环形晶体
Toroidal Crystals
摘要:
在过去的十年里,在各种性质惊人不同的系统中,如病毒衣壳、自组装单分子层和碳纳米材料中,已经发现了由相同的亚单元组装在一起并以环形的形式弹性弯曲的晶体集合体。在这封信中,我们分析了环形晶体的结构特性,我们提供了一个统一的描述弯曲几何缺陷的弹性理论的基础上。我们发现基态的特点是存在5倍的向错的外部的环面和7倍的向错的内部。过量向错的数量主要由环面的纵横比控制,这表明通过缺陷位点的官能化产生具有精确控制的化合价的环形模板的新机制。
英文摘要:
Crystalline assemblages of identical sub-units packed together and elastically bent in the form of a torus have been found in the past ten years in a variety of systems of surprisingly different nature, such as viral capsids, self-assembled monolayers and carbon nanomaterials. In this Letter we analyze the structural properties of toroidal crystals and we provide a unified description based on the elastic theory of defects in curved geometries. We find ground states characterized by the presence of 5-fold disclinations on the exterior of the torus and 7-fold disclinations in the interior. The number of excess disclinations is controlled primarily by the aspect ratio of the torus, suggesting a novel mechanism for creating toroidal templates with precisely controlled valency via functionalization of the defect sites.
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