Experimental evidence for a plethora of low energy spin excitations in the spin-1/2 kagome antiferromagnet ZnCu3(OH)6Cl2 may be understandable in terms of an extended Fermi surface of spinons coupled to a U(1) gauge field. We carry out variational calculations to examine the possibility that such a state may be energetically viable. A Gutzwiller-projected wavefunction reproduces the dimerization of a kagome strip found previously by DMRG. Application to the full kagome lattice shows that the inclusion of a small ferromagnetic next-nearest-neighbor interaction favors a ground state with a spinon Fermi surface.
We deduce a model relevant for the anomalous metallic state of Sr doped manganites at low temperatures within the ferromagnetic phase. It provides a natural explanation to several anomalous features observed experimentally, such as the vanishing Drude contribution in optical conductivity, the pseudo-gap in the density of states, an the unusual dispersion observed in photoemission.
Spin wave excitations were measured in the ferromagnetic phase of Nd$_{1/2}$Sr$_{1/2}$MnO$_{3}$ by neutron scattering. This compound is located in proximity to the A-type antiferromagnetic state, and it shows a clear anisotropy and anomalous softening of the spin wave excitations. The softening in the ferromagnetic phase is induced by the orbital ordering.
We study the renormalization of magnons by charge and coupled orbital-lattice fluctuations in colossal magnetoresistance compounds. The model considered is an orbitally degenerate double-exchange system coupled to Jahn-Teller active phonons. The modulation of ferromagnetic bonds by low-energy orbital fluctuations is identified as the main origin of the unusual softening of the zone-boundary magnons observed experimentally in manganites.
The magnon dispersion of ferromagnetic SrRuO$_3$ was studied by inelastic neutron scattering experiments on single crystals as function of temperature. Even at low temperature the magnon modes exhibit substantial broadening pointing to strong interaction with charge carriers. We find an anomalous temperature dependence of both the magnon gap and the magnon stiffness, which soften upon cooling in the ferromagnetic phase. Both effects trace the temperature dependence of the anomalous Hall effect. We argue that these results show that Weyl points and the anomalous Hall effect can directly influen…
The high temperature paramagnetic state in an antiferromagnetic (AFM) insulator Pr_{1-x}Ca_{x}MnO_{3} is characterized by the ferromagnetic (FM) spin fluctuations with an anomalously small energy scale. The FM fluctuations show a precipitous decrease of the intensity at the charge ordering temperature T_{CO}, but persist below T_{CO}, and vanish at the AFM transition temperature T_{N}. These results demonstrate the importance of the spin ordering for the complete switching of the FM fluctuation in doped manganites.
SrRuO$_3$ heterostructures grown in the (111) direction are a rare example of thin film ferromagnets. By means of density functional theory plus dynamical mean field theory we show that the half-metallic ferromagnetic state with an ordered magnetic moment of 2$μ_{B}$/Ru survives the ultimate dimensional confinement down to a bilayer, even at elevated temperatures of 500$\,$K. In the minority channel, the spin-orbit coupling opens a gap at the linear band crossing corresponding to $\frac34$ filling of the $t_{2g}$ shell. We demonstrate that the respective state is Haldane's quantum anomalous Ha…
We present the first experimental realization of an $S=2$ ferromagnetic-antiferromagnetic (F-AF) alternating chain in a new Mn-verdazyl complex [Mn(hfac)$_2$]$\cdot$($o$-Py-V) [hfac=1,1,1,5,5,5-hexafluoroacetylacetonate; $o$-Py-V=3-(2-pyridyl)-1,5-diphenylverdazyl]. Through the $ab$ $initio$ molecular orbital calculation, magnetization, and ESR measurements, this compound is confirmed to form an $S=2$ F-AF alternating chain with Ising anisotropy below about 100 K. Furthermore, we find an anomalous change in magnetization at 1/4 of the saturation value, which is probably a manifestation of the …
Enhanced Anomalous Nernst Effect in the Ferromagnetic Kondo Lattice CeCo2As2
International Center for Quantum Materials, School of Physics, Peking University（北京大学物理学院量子材料国际中心）；State Key Laboratory of Quantum Functional Materials, Department of Physics, and Guangdong Basic Research Center of Excellence for Quantum Science, Southern University of Science and Technology（南方科技大学物理学院量子功能材料国家重点实验室及广东省量子科学基础研究中心）；Department of Chemistry, Michigan State University（密歇根州立大学化学系）
In metallic manganites with low Curie temperatures, a peculiar softening of the magnon spectrum close to the magnetic zone boundary has experimentally been observed. Here we present a theory of the renormalization of the magnetic excitation spectrum in colossal magnetoresistance compounds. The theory is based on the modulation of magnetic exchange bonds by the orbital degree of freedom of double-degenerate e_g electrons. The model considered is an orbitally degenerate double-exchange system coupled to Jahn-Teller active phonons which we treat in the limit of strong onsite repulsions. Charge an…
We discuss the role of orbital degeneracy in the transport properties of perovskite manganites, focusing in particular on the optical conductivity in the metallic ferromagnetic phase at low temperatures. Orbital degeneracy and strong correlations are described by an orbital t-J model which we treat in a slave-boson approach. Employing the memory-function formalism we calculate the optical conductivity, which is found to exhibit a broad incoherent component extending up to bare bandwidth accompanied by a strong suppression of the Drude weight. Further, we calculate the constant of T-linear spec…
The anomalous Hall effect in a multiband tight-binding model is numerically studied taking into account both elastic scattering by disorder and inelastic scattering by the electron-phonon interaction. The Hall conductivity is obtained as a function of temperature $T$, inelastic scattering rate $γ$, chemical potential $μ$, and impurity concentration $x_{\rm imp}$. We find that the new scaling law holds over a wide range of these parameters; $-σ_{xy}= (ασ_{xx0}^{-1} + βσ_{xx0}^{-2}) σ_{xx}^2 + b$, with $σ_{μν}$ ($σ_{μν0}$) being the conductivity tensor (with only elastic scattering), which corre…
The 5d iridium-based transition metal oxides have gained broad interest because of their strong spin-orbit coupling which favors new or exotic quantum electronic states. On the other hand, they rarely exhibit more mainstream orders like ferromagnetism due to generally weak electron-electron correlation strength. Here, we show a proximity-induced ferromagnetic (FM) state with TC = 100 K and strong magnetocrystalline anisotropy in a SrIrO3 (SIO) heterostructure via interfacial charge transfer by using a ferromagnetic insulator in contact with SIO. Electrical transport allows to selectively probe…
We report inelastic neutron scattering measurements of the phonon spectrum of the pressure-induced ferromagnetic superconductor UGe$_{2}$. No changes of the spectrum were found on cooling down to low temperature. The phonon contribution to the specific heat was estimated from a fit to our data. The excess specific heat previously noted at around $T_{x} \approx$ 30 K is not due to phonons but is well described by the temperature dependence of the magnetic order parameter at the molecular field level.
The specific heat and thermal conductivity of the insulating ferrimagnet Y$_3$Fe$_5$O$_{12}$ (Yttrium Iron Garnet, YIG) single crystal were measured down to 50 mK. The ferromagnetic magnon specific heat $C$$_m$ shows a characteristic $T^{1.5}$ dependence down to 0.77 K. Below 0.77 K, a downward deviation is observed, which is attributed to the magnetic dipole-dipole interaction with typical magnitude of 10$^{-4}$ eV. The ferromagnetic magnon thermal conductivity $κ_m$ does not show the characteristic $T^2$ dependence below 0.8 K. To fit the $κ_m$ data, both magnetic defect scattering effect an…
A scaling relation of the anomalous Hall effect recently found in a ferromagnetic semiconductor (Ti,Co)O_2_ is compared with those of various ferromagnetic semiconductors and metals. Many of these compounds with relatively low conductivity sigma_xx_ < 10^4 ohm^-1 cm^-1 are also found to exhibit similar relation: anomalous Hall conductivity sigma_AH_ approximately scales as sigma_AH_ proportional to sigma_xx_^1.6, that is coincident with a recent theory. This relation is valid over five decades of sigma_xx_ irrespective of metallic or hopping conduction.
We investigate the ground-state phase diagram for the ferromagnetic Kondo lattice model on a triangular lattice by a variational calculation for various spin orderings up to a four-site unit cell. We find that a noncoplanar four-sublattice ordering with a finite scalar spin chirality emerges at and around 1/4 filling, in addition to the 3/4-filled case, which was predicted to be induced by the perfect nesting of the Fermi surface [I. Martin and C. D. Batista: Phys. Rev. Lett. {\bf 101} (2008) 156402]. The 1/4-filling phase is stable in a wider range of parameters than the 3/4-filling one, and …
Monoclinic Li$_3$Co$_2$SbO$_6$ has been proposed as a Kitaev spin liquid candidate and investigated intensively, whereas the properties of its polymorph, the orthorhombic phase, is less known. Here we report the magnetic properties of the orthorhombic Li$_3$Co$_2$SbO$_6$ as revealed by dc and ac magnetic susceptibility, muon spin relaxation ($μ$SR) and neutron diffraction measurements. Successive magnetic transitions at (115, 89 and 71) K were observed in the low field dc susceptibility measurements. The transitions below $T_N$ (= 115 K), are suppressed in higher applied fields. However, zero …
The magnetic susceptibility and spin-spin correlation of the double-exchange model for doped manganites are investigated through the Monte Carlo calculations on the three-dimensional lattice model. Deviations of the susceptibility from the Curie-Weiss behavior above the ferromagnetic ordering temperature $T_c$ seem to indicate a formation of local ferromagnetic clusters in the vicinity of $T_c$, which is consistent with recent electron paramagnetic resonance experiments for La$_{2/3}$Ca$_{1/3}$MnO$_3$. A further analysis of the spin-spin correlations show the ferromagnetic cluster size to be t…
The anomalous Hall effect is investigated for ferromagnetic Fe3Sn2 single crystal with geometrically frustrated kagome bilayer of Fe. The scaling behavior between anomalous Hall resistivity rho_{xy}^{A} and longitudinal resistivity rho_{xx} is quadratic and further analysis implies that the AHE in Fe3Sn2 single crystal should be dominated by the intrinsic Karplus-Luttinger mechanism rather than extrinsic skew-scattering or side-jump mechanisms. Moreover, there is a sudden jump of anomalous Hall conductivity sigma_{xy}^{A} appearing at about 100 K where the spin-reorientation transition from th…
We present an new approach for the ferromagnetic, three-dimensional, translational-symmetric Kondo lattice model which allows us to derive both magnon energies and linewidths (lifetimes) and to study the properties of the ferromagnetic phase at finite temperatures. Both "anomalous softening" and "anomalous damping" are obtained and discussed. Our method consists of mapping the Kondo lattice model onto an effective Heisenberg model by means of the "modified RKKY interaction" and the "interpolating self-energy approach". The Heisenberg model is approximatively solved by applying the Dyson-Maleev…
Quantum anomalous Hall (QAH) phases in magnetic topological insulators are characterized by the scattering-free chiral edge currents protected by their nontrivial bulk band topology. To fully explore these intriguing phenomena and application of topological insulators, high temperature material realization of QAH phases is crucial. In this paper, based on extensive first-principles density functional theory calculations, we predict that perovskite bilayers (LaXO$_3$)$_{2}$ (X = Pd, Pt) imbedded in the (111) (LaXO$_3$)$_{2}$/(LaAlO$_3$)$_{10}$ superlattices are high Curie temperature ferromagne…
Low-temperature specific heat of CaRu1-xMnxO3 was measured to clarify the role of d electrons in ferromagnetic and antiferromagnetic orders observed above x=0.2. Specific heat divided by temperature C_p/T is found to roughly follow a T^2 function, and relatively large magnitudes of electronic specific heat coefficient gamma were obtained in wide x range. In particular, gamma is unchanged from the value at x=0 (84 mJ/K^2 mol) in the paramagnetic state for x<=0.1, but linearly reduced with increasing x above x= 0.2. These features of gamma strongly suggest that itinerant d electrons are tightly …
By density functional theory calculations, we predict a stable two-dimensional (2D) ferromagnetic semiconductor Cr$_2$Ge$_2$Se$_6$, where the Curie temperature $T$$_c$ can be dramatically enhanced beyond room temperature by applying a few percent strain. In addition, the anomalous Hall conductivity in 2D Cr$_2$Ge$_2$Se$_6$ and Cr$_2$Ge$_2$Te$_6$ is predicted to be comparable to that in ferromagnetic metals of Fe and Ni, and is an order of magnitude larger than that in diluted magnetic semiconductor Ga(Mn,As). Based on superexchange interactions, the enhanced $T$$_c$ in 2D Cr$_2$Ge$_2$Se$_6$ by…
The intrinsic antiferromagnetic (AFM) interlayer coupling in two-dimensional magnetic topological insulator MnBi$_2$Te$_4$ places a restriction on realizing stable quantum anomalous Hall effect (QAHE) [Y. Deng et al., Science 367, 895 (2020)]. Through density functional theory calculations, we demonstrate the possibility of tuning the AFM coupling to the ferromagnetic coupling in MnBi$_2$Te$_4$ films by alloying about 50% V with Mn. As a result, QAHE can be achieved without alternation with the even or odd septuple layers. This provides a practical strategy to get robust QAHE in ultrathin MnBi…
To elucidate the origin of anomalous Hall effect (AHE) in ferromagnetic transition metals, we study the intrinsic AHE based on a multi-orbital (xz,yz)-tight-binding model. We find that a large anomalous velocity comes from the off-diagonal (inter-orbital) hopping. By this reason, the present model shows a large intrinsic anomalous Hall conductivity (AHC) which is compatible with typical experimental values in ferromagnets [100-1000 [1/Ωcm]], without necessity to assume a special band structure at the Fermi level. In good metals where resistivity ρis small, the intrinsic AHC is constant (dissip…
We present a model compound for the $S$=1/2 ferromagnetic Heisenberg chain composed of the verdazyl-based complex $[$Zn(hfac)$_2]$$[$4-Cl-$o$-Py-V-(4-F)$_2]$. $Ab$ $initio$ MO calculations indicate a predominant ferromagnetic interaction forming an $S$=1/2 ferromagnetic chain. The magnetic susceptibility and specific heat indicate a phase transition to an AF order owing to the finite interchain couplings. We explain the magnetic susceptibility and magnetization curve above the phase transition temperature based on the $S$=1/2 ferromagnetic Heisenberg chain. The magnetization curve in the order…
The present study deals with the anomalous heat capacity peak and thermal conductivity of BaVS$_3$ near the metal-insulator transition present at $69$ K. The transition is related to a structural transition from an orthorhombic to monoclinic phase. Heat capacity measurements at this temperature exhibit a significant and relatively broad peak, which is also sample dependent. The present study calculates the entropy increase during the structural transition and we show that the additional entropy is caused by enhanced electron scattering as a result of the structural reorientation of the nuclei.…
We investigate the pressure evolution of the anomalous Hall effect in magnetic topological semimetal Co3Sn2S2 in diamond anvil cells with pressures up to 44.9-50.9 GPa. No evident trace of structural phase transition is detected through synchrotron x-ray diffraction over the measured pressure range of 0.2-50.9 GPa. We find that the anomalous Hall resistivity and the ferromagnetism are monotonically suppressed as increasing pressure and almost vanish around 22 GPa. The anomalous Hall conductivity varies non-monotonically against pressure at low temperatures, involving competition between origin…
In a ferromagnet, an applied electric field $\bf E$ invariably produces an anomalous Hall current ${\bf J}_H$ that flows perpendicular to the plane defined by $\bf E$ and $\bf M$ (the magnetization). For decades, the question whether ${\bf J}_H$ is dissipationless (independent of the scattering rate), has been keenly debated without experimental resolution. In the ferromagnetic spinel CuCr$_2$Se$_{4-x}$Br$_x$, the resistivity $ρ$ (at low temperature) may be increased 1000 fold by varying $x$(Br), without degrading the $\bf M$. We show that ${\bf J}_H/E$ (normalized per carrier, at 5 K) remains…
The quantum anomalous Hall effect (QAHE) hosts the dissipationless chiral edge states associated with the nonzero Chern number, providing potentially significant applications in future spintronics. The QAHE usually occurs in a two-dimensional (2D) system with time-reversal symmetry breaking. In this work, we propose that the QAHE can exist in three-dimensional (3D) ferromagnetic insulators. By imposing inversion symmetry, we develop the topological constraints dictating the appearance of 3D QAHE based on the parity analysis at the time-reversal invariant points in reciprocal space. Moreover, u…
A ferromagnetic semiconductor, rutile (Ti,Co)O2, exhibits anomalous Hall effect at room temperature. Strong dependence of the anomalous Hall effect, as well as the magneto-optic response, on the carrier concentration suggests carrier induced ferromagnetism in this compound. Both ferromagnetic responses are caused by the charge carriers at the band edge of host semiconductor, indicating possibilities of spintronics devices operable at room temperature.
We have investigated transport properties of CrO2 thin films deposited on TiO2 and sapphire substrates. The films are good metals down to low temperatures. The residual resistivity is of the order of 6 micro-ohhmcm for films deposited on TiO2 and two times higher for films on sapphire substrates. The sign of the magnetoresistance (MR) changes from negative to positive at a temperature around 100 K. This fact, as well as a rapid change in the ordinary and anomalous Hall coefficients suggest a change in the electronic state. At lower temperatures the MR is a linear function of the applied field.…
We discuss the low-temperature behavior of the electronic self-energy in the vicinity of a ferromagnetic instability in two dimensions within the two-particle self-consistent approximation, functional renormalization group and Ward-identity approaches. Although the long-range magnetic order is absent at T>0, the self-energy has a non-Fermi liquid form at low energies w<Δ_0 near the Fermi level, where Delta_0 is the ground-state spin splitting. The spectral function at temperatures T<Delta_0 has a two-peak structure with finite spectral weight at the Fermi level. The simultaneous inclusion of s…
It is shown that anomalous properties of UGe_2 can be understood in a unified way on the basis of a single assumption that the superconductivity is mediated by the coupled SDW and CDW fluctuations induced by the imperfect nesting of the Fermi surface with majority spins at T=T_x(P) deep in the ferromagnetic phase. Excess growth of uniform magnetization is shown to develop in the temperature range T<T_x(P) as a mode-coupling effect of coupled growth of SDW and CDW orderings, which has been observed by two different types of experiments. The coupled CDW and SDW fluctuations are shown to be essen…
The heat-capacity and magnetization measurements under high pressure have been carried out in a ferromagnetic superconductor UGe$_2$. Both measurements were done using a same pressure cell in order to obtain both data for one pressure. Contrary to the heat capacity at ambient pressure, an anomaly is found in the heat capacity at the characteristic temperature $T^{*}$ where the magnetization shows an anomalous enhancement under high pressure where the superconductivity appears. This suggests that a thermodynamic phase transition takes place at $T^{*}$ at least under high pressure slightly below…
Recent reports of a large anomalous Hall effect (AHE) in ferromagnetic Weyl semimetals (FM WSM) have led to a resurgence of interest in this enigmatic phenomenon. However, due to a lack of tunable materials, the interplay between the intrinsic mechanism caused by Berry curvature and extrinsic mechanisms due to scattering remains unclear in FM WSMs. In this contribution, we present a thorough investigation of both the extrinsic and intrinsic AHE in a new family of FM WSMs, PrAlGe$_{1-x}$Si$_x$, where $x$ can be tuned continuously. From DFT calculations, we show that the two end members, PrAlGe …
We report an above-room-temperature ferromagnetic state realized in a proximitized Dirac semimetal, which is fabricated by growing typical Dirac semimetal Cd$_3$As$_2$ films on a ferromagnetic garnet with strong perpendicular magnetization. Observed anomalous Hall conductivity with substantially large Hall angles is found to be almost proportional to magnetization and opposite in sign to it. Theoretical calculations based on first-principles electronic structure also demonstrate that the Fermi-level dependent anomalous Hall conductivity reflects the Berry curvature originating in the split Wey…
Magnetism and spin-orbit coupling (SOC) are two quintessential ingredients underlying novel topological transport phenomena in itinerant ferromagnets. When spin-polarized bands support nodal points/lines with band degeneracy that can be lifted by SOC, the nodal structures become a source of Berry curvature; this leads to a large anomalous Hall effect (AHE). Contrary to three-dimensional systems that naturally host nodal points/lines, two-dimensional (2D) systems can possess stable nodal structures only when proper crystalline symmetry exists. Here we show that 2D spin-polarized band structures…
We report a comprehensive investigation of the structural, magnetic, transport and thermodynamic properties of a single crystal PrAlSi, in comparison to its nonmagnetic analogue LaAlSi. PrAlSi exhibits a ferromagnetic transition at $T_C$ = 17.8 K which, however, is followed by two weak phase transitions at lower temperatures. Based on the combined dc and ac magnetic susceptibility measurements, we propose the two reentrant magnetic phases below $T_C$ to be spin glasses or ferromagnetic cluster glasses. When the magnetic glassy states are suppressed by small field, several remarkable features a…
We revealed the electrical transport through surface ferromagnetic states of a nonmagnetic metal PdCoO2. Electronic reconstruction at the Pd-terminated surface of PdCoO2 induces Stoner-like ferromagnetic states, which could lead to spin-related phenomena among the highly conducting electrons in PdCoO2. Fabricating a series of nanometer-thick PdCoO2 thin films, we detected a surface-magnetization-driven anomalous Hall effect via systematic thickness- and termination-dependent measurements. Besides, we discuss that finite magnetic moments in electron doped CoO2 triangular lattices may have given…
Topological insulators are bulk electronic insulators which possess symmetry protected gapless modes on their surfaces. Breaking the symmetries that underlie the gapless nature of the surface modes is predicted to give rise to exotic new states of matter. In particular, it has recently been predicted and shown that breaking of time reversal symmetry in the form of ferromagnetism can give rise to a gapped state characterized by a zero magnetic field quantized Hall response and dissipationless longitudinal transport known as the Quantum Anomalous Hall (QAH) state. A key question that has thus fa…
The solid-solution SrRu$_{1-x}$Rh$_x$O$_3$ ($0\le x \le1$) is a variable-electron-configuration system forming in the nearly-cubic-perovskite basis, ranging from the ferromagnetic 4$d^4$ to the enhanced paramagnetic 4$d^5$. Polycrystalline single-phase samples were obtained over the whole composition range by a high-pressure-heating technique, followed by measurements of magnetic susceptibility, magnetization, specific heat, thermopower, and electrical resistivity. The ferromagnetic order in long range is gradually suppressed by the Rh substitution and vanishes at $x \sim 0.6$. The electronic …
Low-temperature electronic states in SrRu_{1-x}Mn_xO_3 for x <= 0.6 have been investigated by means of specific-heat C_p measurements. We have found that a jump anomaly observed in C_p at the ferromagnetic (FM) transition temperature for SrRuO_3 changes into a broad peak by only 5% substitution of Mn for Ru. With further doping Mn, the low-temperature electronic specific-heat coefficient gamma is markedly reduced from the value at x=0 (33 mJ/K^2 mol), in connection with the suppression of the FM phase as well as the enhancement of the resistivity. For x >= 0.4, gamma approaches to ~ 5 mJ/K^2 m…
