In perturbative calculations of quantum-statistical zero-temperature path integrals in curvilinear coordinates one encounters Feynman diagrams involving multiple temporal integrals over products of distributions, which are mathematically undefined. In addition, there are terms proportional to powers of Dirac delta-functions at the origin coming from the measure of path integration. We give simple rules for integrating products of distributions in such a way that the results ensure coordinate independence of the path integrals. The rules are derived by using equations of motion and partial integration, while keeping track of certain minimal features originating in the unique definition of all singular integrals in $1 - ε$ dimensions. Our rules yield the same results as the much more cumbersome calculations in 1- epsilon dimensions where the limit epsilon --> 0 is taken at the end. They also agree with the rules found in an independent treatment on a finite time interval.
Studies of integrable quantum many-body systems have a long history with an impressive record of success. However, surprisingly enough, an unambiguous definition of quantum integrability remains a matter of an ongoing debate. We contribute to this debate by dwelling upon an important aspect of quantum integrability -- the notion of independence of quantum integrals of motion (QIMs). We point out that a widely accepted definition of functional independence of QIMs is flawed, and suggest a new definition. Our study is motivated by the PXP model -- a model of $N$ spins $1/2$ possessing an extensi…
The two-center two-electron Coulomb and hybrid integrals arising in relativistic and nonrelativistic ab-initio calculations of molecules are evaluated over the non-integer Slater-type orbitals via ellipsoidal coordinates. These integrals are expressed through new molecular auxiliary functions and calculated with numerical Global-adaptive method according to parameters of non-integer Slatertype orbitals. The convergence properties of new molecular auxiliary functions are investigated and the results obtained are compared with results found in the literature. The comparison for two-center twoele…
We discuss the coherent states for PT-/non-PT-Symmetric and non-Hermitian generalized Morse Potential obtained by using path integral formalism over the holomorphic coordinates. We transform the action of generalized Morse potential into two harmonic oscillators with a new parametric time to establish the parametric time coherent states. We calculate the energy eigenvalues and the corresponding wave functions in parabolic coordinates.
A new definition for the path integral is proposed in terms of Finsler geometry. The conventional Feynman's scheme for quantisation by Lagrangian formalism suffers problems due to the lack of geometrical structure of the configuration space where the path integral is defined. We propose that, by implementing the Feynman's path integral on an extended configuration space endowed with a Finsler structure, the formalism could be justified as a proper scheme for quantisation from Lagrangian only, that is, independent from Hamiltonian formalism. The scheme is coordinate free, and also a covariant f…
We present a new method for the numerical calculation of canonical reaction rate constants in complex molecular systems, which is based on a path integral formulation of the flux-flux correlation function. Central is the partitioning of the total system into a relevant part coupled to a dual bath. The latter consists of two parts: First, a set of strongly coupled harmonic modes, describing, for example, intramolecular degrees of freedom. They are treated on the basis of a reaction surface Hamiltonian approach. Second, a set of bath modes mimicking an unspecific environment modeled by means of …
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