外消旋过氧化氢分子的光致旋光
Photoinduced optical rotation in a racemic mixture of hydrogen peroxide molecules
摘要：
分析了在手性分子的对映异构体的外消旋混合物中诱导所需手性符号的问题。例如，考虑过氧化氢（H2 O2）分子的左旋和右旋对映异构体的外消旋混合物（蒸气）。结果表明，双谐波拉曼激发分裂由于左-右转换内旋转水平可以有效地用于诱导光学活性在最初的外消旋蒸汽的H2 O2分子。讨论了研究这种光致旋光的实验。
英文摘要：
A problem of inducing a required sign of chirality in a racemic mixture of enantiomers of a chiral molecule is analyzed. As an example, a racemic mixture (vapor) of left- and right-handed enantiomers of hydrogen peroxide (H2O2) molecule is considered. It is shown that biharmonic Raman excitation of the splitted due to the left-right conversion internal rotation levels can be effectively used for inducing optical activity in the initially racemic vapor of H2O2 molecules. An experiment to study this photoinduced optical rotation is discussed.
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