MgO中Ni2 +的双光子吸收跃迁强度
Intensity of Two-Photon Absorption Transitions for Ni2+ in MgO
摘要:
通过一个简单的模型,得到了立方对称组态3d8的基态3A2(T2)与该组态的激发态之间的宇称允许双光子跃迁.该模型是在一个对称性适应的框架下,通过使用二阶机制和离子波函数。它适用于最近的实验结果McClure和同事获得的Ni 2+在MgO中。
英文摘要:
The parity-allowed two-photon transitions between the ground state 3A2(T2) of the configuration 3d8 in cubical symmetry and the excited states of the same configuration are obtained via a simple model. This model is developed in a symmetry adapted framework by using second-order mechanisms and ionic wave-functions. It is applied to the recent experimental results obtained by McClure and co-workers for Ni2+ in MgO.
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