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arXiv physics/0701228physics.optics
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基于黄色咔唑发光体到蓝色发光基质中的掺杂和非掺杂有机发光二极管

Doped and non-doped organic light-emitting diodes based on a yellow carbazole emitter into a blue-emitting matrix

Hakim Choukri, Alexis Fischer, Sebastien Forget, Sebastien Chenais, Marie-Claude Castex, Bernard Geffroy, Dominique Ades, Alain Siove

摘要:

通过羰基-亚甲基Knovenagel缩合反应,合成了一种新型咔唑衍生物(OcCz 2CN)2,该化合物以3,3 '-联咔唑为核,经6,6'-二氰基乙烯基(6,6 '-bis(1-(2,2'-dicyano)vinyl)-N,N '-dioctyl-3,3'-bicarbazyl)取代,并对其进行了表征。由于其-供体-受体型结构,发现(OcCz 2CN)2在max=590 nm(CIE坐标x=0.51; y = 0.47)处发射黄光,并且在4,4 '-双(2,2'-二苯基乙烯基)-1,1 '-联苯(DPVBi)的蓝色发射基质中用作掺杂剂或用作超薄层。掺杂DPVBi(OcCz 2CN)2的结构在掺杂率为1.5重量%时表现出CIE坐标(x = 0.31; y = 0.51)的黄绿色光,电致发光效率EL=1.3 cd/A,外量子效率ext= 0.4%和亮度L= 127 cd/m2(在10 mA/cm 2下),而对于利用咔唑荧光团作为薄的纯层的非掺杂器件,获得了具有CIE坐标(x = 0.40; y= 0.43)、EL= 2.0 cd/A、ext= 0.7%、L = 197 cd/m2(在10 mA/cm 2下)和74的显色指数(CRI)的暖白色。以5,6,11,12-四苯基萘(rubrene)作为高效黄光发光体的参比物,比较了掺杂和未掺杂器件的电致发光性能。

英文摘要:

A new carbazole derivative with a 3,3'-bicarbazyl core 6,6'-substituted by dicyanovinylene groups (6,6'-bis(1-(2,2'-dicyano)vinyl)-N,N'-dioctyl-3,3'-bicarbazyl; named (OcCz2CN)2, was synthesized by carbonyl-methylene Knovenagel condensation, characterized and used as a component of multilayer organic light-emitting diodes (OLEDs). Due to its -donor-acceptor type structure, (OcCz2CN)2 was found to emit a yellow light at max=590 nm (with the CIE coordinates x=0.51; y = 0.47) and was used either as a dopant or as an ultra-thin layer in a blue-emitting matrix of 4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl (DPVBi). DPVBi (OcCz2CN)2-doped structure exhibited, at doping ratio of 1.5 weight %, a yellowish-green light with the CIE coordinates (x = 0.31; y = 0.51), an electroluminescence efficiency EL=1.3 cd/A, an external quantum efficiency ext= 0.4 % and a luminance L= 127 cd/m2 (at 10 mA/cm2) whereas for non-doped devices utilizing the carbazolic fluorophore as a thin neat layer, a warm white with CIE coordinates (x = 0.40; y= 0.43), EL= 2.0 cd/A, ext= 0.7 %, L = 197 cd/m2 (at 10 mA/cm2) and a color rendering index (CRI) of 74, were obtained. Electroluminescence performances of both the doped and non-doped devices were compared with those obtained with 5,6,11,12-tetraphenylnaphtacene (rubrene) taken as a reference of highly efficient yellow emitter.

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