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arXiv physics/0612195physics.atom-ph
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多电子系统中的关联:理论与应用

Correlations in Many Electron Systems: Theory and Applications

M. Tomaselli, T. Kuehl, D. Ursescu, S. Fritzsche

摘要:

在这方面的贡献,我们提出了计算相互作用的电子系统内的非微扰制定的集群理论。外推模型来描述相互作用系统的时间依赖性是可行的和有计划的。该理论是基于酉算子$e^{iS}$({ \it S}是相关算子)的形式主义,在本文中,处理非微扰内的多粒子相关。推导出的方程的应用程序实现的广义线性化近似(GLA)和通过集群因子分解理论(CFT)的少体系统。为了检查模型的可靠性,我们提出了两个不同的应用程序。在第一部分中,我们计算了氦氧、锂氧、铍氧和硼氧的跃迁能。计算的目的是精确地确定卫星跃迁,这在等离子体诊断中起着重要作用。第二部分研究了用同位素位移理论计算氦和锂同位素电荷半径的非微扰方法。我们发现,我们的模型在氦同位素的二电子波函数和锂同位素的三电子波函数中自然地导出了$e^--e^+$对的分量。这些条款的QED领导图的可能连接被假定。

英文摘要:

In this contribution we present calculations performed for interacting electron systems within a non-perturbative formulation of the cluster theory. Extrapolation of the model to describe the time dependence of the interacting systems is feasible and planed. The theory is based on the unitary operator $e^{iS}$ ({\it S} is the correlation operator) formalism which, in this paper, is treated non perturbatively within many-particle correlations. The application of the derived equations to few-body systems is realized in terms of Generalized Linearization Approximations (GLA) and via the Cluster Factorization Theory (CFT). To check the reliability of the model we present two different applications. In the first we evaluate the transitions energies in Helium-, Lithium-, Beryllium-, and Boron-like Oxygen. The calculation aims to a precise determination of the satellite transitions which play an important role in plasma diagnostics. In a second we investigate a non-perturbative method to evaluate the charge radii of the Helium and Lithium isotopes by using the Isotopic Shift theory. We have found that our model leads naturally to components of $e^--e^+$ pair in the two-electron wave functions of the Helium isotopes and three-electron wave functions of the Lithium isotopes. The possible connection of these terms to the QED leading diagrams is postulated.

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