19 F核的化学诱导动态核极化
Chemically Induced Dynamic Nuclear Polarization of 19F Nuclei
摘要:
本研究从理论和实验两方面探讨了19 F核的光化学诱导动态核极化(photo-CIDNP),相关的自旋弛豫,交叉弛豫和交叉相关效应,以及19 F CIDNP在蛋白质结构和折叠问题中的潜在应用。关键词:CIDNP,弛豫,氟,NMR,NOE,TR-CIDNP,tc 5 b,Trp-笼,GFP
英文摘要:
This study explores, both theoretically and experimentally, the photochemically induced dynamic nuclear polarization (photo-CIDNP) of 19F nuclei, the associated spin relaxation, cross-relaxation and cross-correlation effects, as well as potential applications of 19F CIDNP to protein structure and folding problems. Keywords: CIDNP, relaxation, fluorine, NMR, NOE, TR-CIDNP, tc5b, Trp-cage, GFP
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