类氢HH +和反氢antiHH +阳离子的反对称性:经典和从头算量子力学计算
Antisymmetry in hydrogenic HH+ and antihydrogenic antiHH+ cations: classical and ab initio quantum mechanical calculations
摘要:
从头算量子化学揭示了电荷反对称反氢反HH+态是如何隐藏在分子氢阳离子的PEC(势能曲线)中的。只有通过内部电荷反转和库仑定律,才能理解位置坐标产生的反对称性,但这种解决方案一直被忽视。稳定的物质-反物质相互作用不仅存在于自然界中,而且是用库仑模型解释稳定复合物质的一个基本要素,即使在波动力学中也是如此。
英文摘要:
Ab initio quantum chemistry reveals how the charge-antisymmetric antihydrogenic antiHH+ state, deriving from conventional positional antisymmetry of a 3-unit charge system, is hidden in the PEC (potential energy curve) of the molecular hydrogen cation. Only with internal charge inversion and Coulomb's law, the anti-symmetry generated by positional coordinates can be understood but this solution was persistently overlooked. Stabilizing matter-antimatter interactions not only exist in nature, they are an essential element, even in wave mechanics, for explaining stable composite matter with a Coulomb model.
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