We discuss consequences of Fermi exchange symmetry on collisions of polar molecules at low temperatures (below 1 K), considering the OD radical as a prototype. At low fields and low temperatures, Fermi statistics can stabilize a gas of OD molecules against state-changing collisions. We find, however, that this stability does not extend to temperatures high enough to assist with evaporative cooling. In addition, we establish that a novel ``field-linked'' resonance state of OD dimers exists, in analogy with the similar states predicted for bosonic OH.
Charge exchange collisions between ultracold fermionic 6Li atoms and 40Ca+ ions are observed in the mK temperature range. The reaction product of the charge exchange collision is identified via mass spectrometry during which the motion of the ions is excited parametrically. The cross-sections of the charge exchange collisions between 6Li atoms in the ground state and 40Ca+ ions in the ground and metastable excited states are determined. Investigation of the inelastic collision characteristics in the atom-ion mixture is an important step toward ultracold chemistry based on ultracold atoms and i…
Three-body recombination of identical, spin-polarized fermionic atoms in the ultracold limit is investigated. The mechanisms for recombination are described in terms of the ``scattering volume'' $V_p$ in the framework of the adiabatic hyperspherical representation. We have calculated numerically the recombination rate $K_3$ as a function of $V_p$ and have found that $K_3$ scales as $|V_p|^{8/3}$ for small $|V_p|$. A comparison with experimental data is also presented.
We investigate the ultracold reaction dynamics of magnetically trapped NH($X ^3Σ^-$) radicals using rigorous quantum scattering calculations involving three coupled potential energy surfaces. We find that the reactive NH + NH cross section is driven by a short-ranged collisional mechanism, and its magnitude is only weakly dependent on magnetic field strength. Unlike most ultracold reactions observed so far, the NH + NH scattering dynamics is non-universal. Our results indicate that chemical reactions can cause more trap loss than spin-inelastic NH + NH collisions, making molecular evaporative …
Ultracold collisions of LiO molecules in the $^{2}Π_{3/2}$ ground state are considered, under the influence of either an external magnetic or electric field. Inelastic collisions are shown to be suppressed in the presence of modest laboratory strength magnetic and electric fields. The rate of elastic collisions that rethermalize the thermal distribution, and the corresponding low rate of heating state-changing collisions, suggest that quantum degeneracy or even molecular Bose-Einstein condensation of LiO gas may be attainable, provided that the initial temperatures in the milliKelvin range are…
Elastic and inelastic properties of weakly bound s- and p-wave molecules of fermionic atoms that collide with a third atom are investigated. Analysis of calculated collisional properties of s-wave dimers of fermions in different spin states permit us to compare and highlight the physical mechanisms that determine the stability of s-wave and p-wave molecules. In contrast to s-wave molecules, the collisional properties of p-wave molecules are found to be largely insensitive to variations of the p-wave scattering length and that these collisions will usually result in short molecular lifetimes. W…
We describe the formation of fermionic NaLi Feshbach molecules from an ultracold mixture of bosonic 23Na and fermionic 6Li. Precise magnetic field sweeps across a narrow Feshbach resonance at 745 G result in a molecule conversion fraction of 5% for our experimental densities and temperatures, corresponding to a molecule number of 5*10^4. The observed molecular decay ifetime is 1.3 ms after removing free Li and Na atoms from the trap.
We report on the formation of ultracold fermionic Feshbach molecules of $^{23}$Na$^{40}$K, the first fermionic molecule that is chemically stable in its ground state. The lifetime of the nearly degenerate molecular gas exceeds 100 ms in the vicinity of the Feshbach resonance. The measured dependence of the molecular binding energy on the magnetic field demonstrates the open-channel character of the molecules over a wide field range and implies significant singlet admixture. This will enable efficient transfer into the singlet vibrational ground state, resulting in a stable molecular Fermi gas …
We investigate the Bose-Einstein condensation (BEC, superfluidity) of particle-hole pairs in ultracold Fermionic atoms with repulsive interactionsand arbitrary polarization, which are trapped within optical lattices. Near a Feshbach resonance, the dynamics of particle-hole pairs can be described by a hard-core Bose-Hubbard model. The insulator - superfluid and charge-density-wave (CDW) - superfluid phase transitions can be induced by decreasing and increasing the potential depths with controlling the trapping laser intensity, respectively. The parameter and polarization dependence of the criti…
We predict a nonequilibrium critical phenomenon in the space-time density evolution of a fermionic gas above the temperature of transition into the superfluid phase. On the BCS side of the BEC-BCS crossover, the evolution of a localized density disturbance exhibits a negative echo at the point of the initial inhomogeneity. Approaching the BEC side, this effect competes with the slow spreading of the density of bosonic molecules. However, even here the echo dominates for large enough times. This effect may be used as an experimental tool to locate the position of the transition.
We have computed ab inito cross sections for cold collisions of Rb atoms with OH radicals. We predict collision rate constants of order 10^{-11} cm^3/s at temperatures in the range 10-100 mK at which molecules have already been produced experimentally. However, we also find that in these collisions the molecules have a strong propensity for changing their internal state, which could make sympathetic cooling of OH in a Rb buffer gas problematic in magnetostatic or electrostatic traps.
We present our experimental setup to produce ultracold strongly correlated fermionic superfluids made of a two-component spin-mixture of $^6$Li atoms. Employing standard cooling techniques, we achieve quantum degeneracy in a single-beam optical dipole trap. Our setup is capable of generating spin-balanced samples at temperatures as low as $T/T_F = 0.1$ containing up to $5 \times 10^4$ atomic pairs. We can access different superfluid regimes by tuning the interparticle interactions close to a broad magnetic Feshbach resonance. In particular, we are able to explore the crossover from the molecul…
Elastic scattering resonances occurring in ultracold collisions of either bosonic or fermionic polar molecules are investigated. The Born-Oppenheimer adiabatic representation of the two-bodydynamics provides both a qualitative classification scheme and a quantitative WKB quantization condition that predicts several sequences of resonant states. It is found that the near-threshold energy dependence of ultracold collision cross sections varies significantly with the particle exchange symmetry, with bosonic systems showing much smoother energy variations than their fermionic counterparts. Resonan…
We develop a collisional formalism adapted for the dynamics of ultracold dipolar particles in a confined geometry and in fields tilted relative to the confinement axis. Using tesseral harmonics instead of the usual spherical harmonics to expand the scattering wavefunction, we recover a good quantum number $ξ= \pm 1$ which is conserved during the collision. We derive the general expression of the dipole-dipole interaction in this convenient basis set as a function of the polar and azimuthal angles of the fields. We apply the formalism to the collision of fermionic and bosonic polar KRb molecule…
We report on the creation of an ultracold dipolar gas of fermionic $^{23}$Na$^{40}$K molecules in their absolute rovibrational and hyperfine ground state. Starting from weakly bound Feshbach molecules, we demonstrate hyperfine resolved two-photon transfer into the singlet ${\rm X}^1Σ^+ |v{=}0,J{=}0\rangle$ ground state, coherently bridging a binding energy difference of 0.65 eV via stimulated rapid adiabatic passage. The spin-polarized, nearly quantum degenerate molecular gas displays a lifetime longer than 2.5 s, highlighting NaK's stability against two-body chemical reactions. A homogeneous …
We consider collisions of electric and magnetic polar molecules, taking the OH radical as an example, subject to combined electric and magnetic static fields. We show that the relative orientation of the fields has an important effect on the collision processes for different fields magnitude at different collision energies. This is due to the way the molecules polarize in the combined electric and magnetic fields and hence the way the electric dipole-dipole interaction rises. If OH molecules are confined in magnetic quadrupole traps and if an electric field is applied, molecular collisions wil…
At ultracold temperatures, the Pauli exclusion principle suppresses collisions between identical fermions. This has motivated the development of atomic clocks using fermionic isotopes. However, by probing an optical clock transition with thousands of lattice-confined, ultracold fermionic Sr atoms, we have observed density-dependent collisional frequency shifts. These collision effects have been measured systematically and are supported by a theoretical description attributing them to inhomogeneities in the probe excitation process that render the atoms distinguishable. This work has also yield…
We study inelastic processes for ultracold three-body systems in which only one interaction is resonant. We have found that the decay rates for weakly bound molecules due to collisions with other atoms can be suppressed not only without fermionic statistics but also when bosonic statistics applies. In addition, we show that at ultracold temperatures three-body recombination involving a single resonant pair of atoms leads mainly to formation of weakly bound molecules which, in turn, are stable against decay. These results indicate that recombination in three-component atomic gases can be used a…
We show that atomic Fermi mixtures with density and mass imbalance exhibit a rich diversity of scaling laws for the quasiparticle decay rate beyond the quadratic energy and temperature dependence of conventional Fermi liquids. For certain densities and mass ratios, the decay rate is linear whereas in other cases it exhibits a plateau. Remarkably, this plateau extends from the deeply degenerate to the high temperature classical regime of the light species. Many of these scaling laws are analogous to what is found in very different systems including dirty metals, liquid metals, and high temperat…
We investigate magnetically tunable Feshbach resonances in ultracold collisions between ground-state Yb and Cs atoms, using coupled-channel calculations based on an interaction potential recently determined from photoassociation spectroscopy. We predict resonance positions and widths for all stable isotopes of Yb, together with resonance decay parameters where appropriate. The resonance patterns are richer and more complicated for fermionic Yb than for spin-zero isotopes, because there are additional level splittings and couplings due to scalar and tensorial Yb hyperfine interactions. We exami…
We extent the recently developed Multi-Layer Multi-Configuration Time-Dependent Hartree method for Bosons (ML-MCTDHB) for simulating the correlated quantum dynamics of bosonic mixtures to the fermionic sector and establish a unifying approach for the investigation of the correlated quantum dynamics of mixture of indistinguishable particles, be it fermions or bosons. Relying on a multi-layer wave-function expansion, the resulting Multi-Layer Multi-Configuration Time-Dependent Hartree method for Mixtures (ML-MCTDHX) can be adapted to efficiently resolve system-specific intra- and inter-species c…
We determine trapping conditions for ultracold polar molecules, where pairs of internal states experience identical trapping potentials. Such conditions could ensure that detrimental effects of inevitable inhomogeneities across an ultracold sample are significantly reduced. In particular, we investigate the internal rovibronic and hyperfine quantum states of ultracold fermionic ground-state $^{40}$K$^{87}$Rb polar molecules, when static magnetic, static electric, and trapping laser fields are simultaneously applied. Understanding the effect of changing the relative orientation or polarization …
We investigate ultracold collisions in a novel mixture of $^6$Li and $^{53}$Cr fermionic atoms, discovering more than 50 interspecies Feshbach resonances via loss spectroscopy. Building a full coupled-channel model, we unambiguously characterize the $^{6}$Li-$^{53}$Cr scattering properties and yield predictions for other isotopic pairs. In particular, we identify various Feshbach resonances that enable the controlled tuning of elastic $s$- and $p$-wave $^{6}$Li-$^{53}$Cr interactions. Our studies thus make lithium-chromium mixtures emerge as optimally-suited platforms for the experimental sear…
We use the quantum threshold laws combined with a classical capture model to provide an analytical estimate of the chemical quenching cross sections and rate coefficients of two colliding particles at ultralow temperatures. We apply this quantum threshold model (QT model) to indistinguishable fermionic polar molecules in an electric field. At ultracold temperatures and in weak electric fields, the cross sections and rate coefficients depend only weakly on the electric dipole moment d induced by the electric field. In stronger electric fields, the quenching processes scale as d^{4(L+1/2)} where…
We report the observation of resonance-like loss in the trap population of ultracold dysprosium as a function of magnetic field, which we attribute to anisotropy-induced Fano-Feshbach resonances arising from Dy's large magnetic dipole moment and nonzero electronic orbital angular momentum. We recorded these resonances for four different isotopes, three bosonic and one fermionic, over a field range of 0-6 G and show that the number of resonances changes significantly as a function of temperature, even in the nK regime. Most of the observed resonances are of very narrow width. The fermionic isot…
Atomic physics was revolutionized by the development of forced evaporative cooling: it led directly to the observation of Bose-Einstein condensation, quantum-degenerate Fermi gases, and ultracold optical lattice simulations of condensed matter phenomena. More recently, great progress has been made in the production of cold molecular gases, whose permanent electric dipole moment is expected to generate rich, novel, and controllable phases, dynamics, and chemistry in these ultracold systems. However, while many strides have been made in both direct cooling and cold-association techniques, evapor…
Trapping ultracold atoms in optical lattices enabled numerous breakthroughs uniting several disciplines. Coupling these systems to quantized light leads to a plethora of new phenomena and has opened up a new field of study. Here we introduce a physically novel source of competition in a many-body strongly correlated system: We prove that quantum backaction of global measurement is able to efficiently compete with intrinsic short-range dynamics of an atomic system. The competition becomes possible due to the ability to change the spatial profile of a global measurement at a microscopic scale co…
We present investigations of the formation rate and collisional stability of lithium Feshbach molecules in an ultracold three-component mixture composed of two resonantly interacting fermionic 6-Li spin states and bosonic 174-Yb. We observe long molecule lifetimes (> 100 ms) even in the presence of a large ytterbium bath and extract reaction rate coefficients of the system. We find good collisional stability of the mixture in the unitary regime, opening new possibilities for studies and probes of strongly interacting quantum gases in contact with a bath species.
We report the creation of ultracold bosonic dipolar $^{23}\textrm{Na}^{39}\textrm{K}$ molecules in their absolute rovibrational ground state. Starting from weakly bound molecules immersed in an ultracold atomic mixture, we coherently transfer the dimers to the rovibrational ground state using an adiabatic Raman passage. We analyze the two-body decay in a pure molecular sample and in molecule-atom mixtures and find an unexpectedly low two-body decay coefficient for collisions between molecules and $^{39}\textrm{K}$ atoms in a selected hyperfine state. The preparation of bosonic $^{23}\textrm{Na…
We demonstrate a one-dimensional optical lattice clock with ultracold 171Yb atoms, which is free from the linear Zeeman effect. The absolute frequency of the 1S0(F = 1/2) - 3P0(F = 1/2) clock transition in 171Yb is determined to be 518 295 836 590 864(28) Hz with respect to the SI second.
The spectrum of two bosons and two fermions in a trap is calculated using a correlated-Gaussian basis throughout the range of a broad Fano-Feshbach resonance. The calculations provide a few-body solution to the magneto-association of fermionic Feshbach molecules. This solution is used to study the time evolution of the system as the scattering length changes, mimicking experiments with Bose-Fermi mixtures near Fano-Feshbach resonances. The structure of avoided crossings in the few-body spectrum enables an interpretation of the dynamics of the system as a sequence of Landau-Zener transitions. T…
We study the three-body problem for both fermionic and bosonic cold atom gases in a parabolic transverse trap of lengthscale $a_\perp$. For this quasi-one-dimensional (1D) problem, there is a two-body bound state (dimer) for any sign of the 3D scattering length $a$, and a confinement-induced scattering resonance. The fermionic three-body problem is universal and characterized by two atom-dimer scattering lengths, $a_{ad}$ and $b_{ad}$. In the tightly bound `dimer limit', $a_\perp/a\to\infty$, we find $b_{ad}=0$, and $a_{ad}$ is linked to the 3D atom-dimer scattering length. In the weakly bound…
Heteronuclear alkali-metal dimers represent the class of molecules of choice for creating samples of ultracold molecules exhibiting an intrinsic large permanent electric dipole moment. Among them, the KCs molecule, with a permanent dipole moment of 1.92~Debye still remains to be observed in ultracold conditions. Based on spectroscopic studies available in the literature completed by accurate quantum chemistry calculations, we propose several optical coherent schemes to create ultracold bosonic and fermionic KCs molecules in their absolute rovibrational ground level, starting from a weakly boun…
We create fermionic dipolar $^{23}$Na$^6$Li molecules in their triplet ground state from an ultracold mixture of $^{23}$Na and $^6$Li. Using magneto-association across a narrow Feshbach resonance followed by a two-photon STIRAP transfer to the triplet ground state, we produce $3\,{\times}\,10^4$ ground state molecules in a spin-polarized state. We observe a lifetime of $4.6\,\text{s}$ in an isolated molecular sample, approaching the $p$-wave universal rate limit. Electron spin resonance spectroscopy of the triplet state was used to determine the hyperfine structure of this previously unobserve…
The calcium monohydroxide radical (CaOH) is an important astrophysical molecule relevant to cool stars and rocky exoplanets, amongst other astronomical environments. Here, we present a consistent set of highly accurate rovibronic (rotation-vibration-electronic) energy levels for the five lowest electronic states ($\tilde{X}\,^2Σ^+$, $\tilde{A}\,^2Π$, $\tilde{B}\,^2Σ^+$, $\tilde{C}\,^2Δ$, $\tilde{D}\,^2Σ^+$) of CaOH. A comprehensive analysis of the published spectroscopic literature on this system has allowed 1955 energy levels to be determined from 3204 rovibronic experimental transitions, all…
