沿反应坐标存在不等间距吸引子时的弛豫动力学
Relaxation dynamics in the presence of unequally spaced attractors along the reaction coordinate
摘要:
我们展示了反应配位路径长度如何影响一个复杂系统的弛豫效率。为了这个目的,我们考虑度量的贡献的过渡率。这些度量贡献保存了关于系统在障碍交叉处的几何变化的信息,因此与路径长度直接相关。目前的工作的输出可以导致确定一种方法来丰富我们的知识的能力的复杂系统放松只优先结构。
英文摘要:
We show how reaction coordinate path lengths affect the relaxation efficiency of a complex system. To this purpose, we consider the metric contributions to the transition rates. These metric contributions preserve informations about the geometry change of the system at the barrier crossing and, therefore, are directly related to the path lengths. The output of the present work can lead to identify a way to enrich our knowledge about the ability of the complex systems to relax only to preferential structures.
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