Localization transition for a copolymer in an emulsion
英文摘要:
In this paper we study a two-dimensional directed self-avoiding walk model of a random copolymer in a random emulsion.
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F den Hollander, S G Whittington
In this paper we study a two-dimensional directed self-avoiding walk model of a random copolymer in a random emulsion.
机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。
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In this paper we review some recent results, obtained jointly with Stu Whittington, for a mathematical model describing a copolymer in an emulsion. The copolymer consists of hydrophobic and hydrophilic monomers, concatenated randomly with equal density. The emulsion consists of large blocks of oil and water, arranged in a percolation-type fashion. To make the model mathematically tractable, the copolymer is allowed to enter and exit a neighboring pair of blocks only at diagonally opposite corners. The energy of the copolymer in the emulsion is minus $α$ times the number of hydrophobic monomers…
In this paper we consider a two-dimensional model of a copolymer consisting of a random concatenation of hydrophilic and hydrophobic monomers, immersed in a micro-emulsion of random droplets of oil and water. The copolymer interacts with the micro-emulsion through an interaction Hamiltonian that favors matches and disfavors mismatches between the monomers and the solvents, in such a way that the interaction with the oil is stronger than with the water. The configurations of the copolymers are directed self-avoiding paths in which only steps up, down and right are allowed. The configurations of…
The present paper is a continuation of \cite{dHP07b}. The object of interest is a two-dimensional model of a directed copolymer, consisting of a random concatenation of hydrophobic and hydrophilic monomers, immersed in an emulsion, consisting of large blocks of oil and water arranged in a percolation-type fashion. The copolymer interacts with the emulsion through an interaction Hamiltonian that favors matches and disfavors mismatches between the monomers and the solvents, in such a way that the interaction with the oil is stronger than with the water. The model has two regimes, supercritical a…
In this paper we study a two-dimensional directed self-avoiding walk model of a random copolymer in a random emulsion. The copolymer is a random concatenation of monomers of two types, $A$ and $B$, each occurring with density 1/2. The emulsion is a random mixture of liquids of two types, $A$ and $B$, organised in large square blocks occurring with density $p$ and $1-p$, respectively, where $p \in (0,1)$. The copolymer in the emulsion has an energy that is minus $α$ times the number of $AA$-matches minus $β$ times the number of $BB$-matches, where without loss of generality the interaction para…
In this paper we study a model describing a copolymer in a micro-emulsion. The copolymer consists of a random concatenation of hydrophobic and hydrophilic monomers, the micro-emulsion consists of large blocks of oil and water arranged in a percolation-type fashion. The interaction Hamiltonian assigns energy $-α$ to hydrophobic monomers in oil and energy $-β$ to hydrophilic monomers in water, where $α,β$ are parameters that without loss of generality are taken to lie in the cone $\{(α,β) \in\mathbb{R}^2\colon\,α\geq |β|\}$. Depending on the values of these parameters, the copolymer either stays…
We review the literature on the localization transition for the class of polymers with random potentials that goes under the name of copolymers near selective interfaces. We outline the results, sketch some of the proofs and point out the open problems in the field. We also present in detail some alternative proofs that simplify what one can find in the literature.
A copolymer is a chain of repetitive units (monomers) that are almost identical, but they differ in their degree of affinity for certain solvents. This difference leads to striking phenomena when the polymer fluctuates in a nonhomogeneous medium, for example, made of two solvents separated by an interface. One may observe, for instance, the localization of the polymer at the interface between the two solvents. A discrete model of such system, based on the simple symmetric random walk on $\mathbb {Z}$, has been investigated in [Bolthausen and den Hollander, Ann. Probab. 25 (1997), 1334-1366], n…
The generalized copolymer model is a disordered system built on a discrete renewal process with inter-arrival distribution that decays in a regularly varying fashion with exponent $1+ α\geq 1$. It exhibits a localization transition which can be characterized in terms of the free energy of the model: the free energy is zero in the delocalized phase and it is positive in the localized phase. This transition, which is observed when tuning the mean $h$ of the disorder variable, has been tackled in the physics literature notably via a renormalization group procedure that goes under the name of \emp…
We consider a directed random walk model of a random heterogeneous polymer in the proximity of an interface separating two selective solvents. This model exhibits a localization/delocalization transition. A positive value of the free energy corresponds to the localized regime and strong results on the polymer path behavior are known in this case. We focus on the interior of the delocalized phase, which is characterized by the free energy equal to zero, and we show in particular that in this regime there are O(log N) monomers in the unfavorable solvent (N is the length of the polymer). The prev…
We consider a general model of a heterogeneous polymer chain fluctuating in the proximity of an interface between two selective solvents. The heterogeneous character of the model comes from the fact that the monomer units interact with the solvents and with the interface according to some charges that they carry. The charges repeat themselves along the chain in a periodic fashion. The main question concerning this model is whether the polymer remains tightly close to the interface, a phenomenon called localization, or whether there is a marked preference for one of the two solvents, thus yield…
We consider a model of a random copolymer at a selective interface which undergoes a localization/delocalization transition. In spite of the several rigorous results available for this model, the theoretical characterization of the phase transition has remained elusive and there is still no agreement about several important issues, for example the behavior of the polymer near the phase transition line. From a rigorous viewpoint non coinciding upper and lower bounds on the critical line are known. In this paper we combine numerical computations with rigorous arguments to get to a better underst…
We study a random walk pinning model, where conditioned on a simple random walk Y on Z^d acting as a random medium, the path measure of a second independent simple random walk X up to time t is Gibbs transformed with Hamiltonian -L_t(X,Y), where L_t(X,Y) is the collision local time between X and Y up to time t. This model arises naturally in various contexts, including the study of the parabolic Anderson model with moving catalysts, the parabolic Anderson model with Brownian noise, and the directed polymer model. It falls in the same framework as the pinning and copolymer models, and exhibits …
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