In these lectures I will study some properties that are shared by many glassy systems. I will shown how some of these properties can be understood in the framework of the mean field approach based on the replica method and I will discuss which are the difficulties which we have to face when we apply the replica method to realistic short range models. We finally present a partially successfully application of the replica method to soft sphere glasses.
This is a short review on the compatibility between (a) mean-field, mode-coupling theories of the glass transition, where potential energy landscape ideas are natural, and (b) the necessity of describing the slowing down of glassy materials in terms of a growing cooperative length, absent from mean-field descriptions. We summarize some of the outstanding questions that remain before we can say we understand why glasses do not flow.
In these lectures I will present an introduction to the modern way of studying the properties of glassy systems. I will start from soluble models of increasing complications, the Random Energy Model, the $p$-spins interacting model and I will show how these models can be solved due their mean field properties. Finally, in the last section, I will discuss the difficulties in the generalization of these findings to short range models.
The emergence of glassy behavior of the random field Ising model (RFIM) is investigated using an extended mean-field theory approach. Using this formulation, systematic corrections to the standard Bragg-Williams theory can be incorporated, leading to the appearance of a glassy phase, in agreement with the results of the self-consistent screening theory of Mezard and Young. Our approach makes it also possible to obtain information about the low temperature behavior of this glassy phase. We present results showing that within our mean-field framework, the hysteresis and avalanche behavior of the…
In this talk I review some recent developments which shed light on the main connections between structural glasses and mean-field spin glass models with a discontinuous transition. I also discuss the role of quantum fluctuations on the dynamical instability found in mean-field spin glasses with a discontinuous transition. In mean-field models with pairwise interactions in a transverse field it is shown, in the framework of the static approximation, that such instability is suppressed at zero temperature.
In this work we discuss a short range version of the $p$-spin model. The model is provided with a parameter that allows to control the crossover with the mean field behaviour. We detect a discrepancy between the perturbative approach and numerical simulation. We attribute it to non-perturbative effects due to the finite probability that each particular realization of the disorder allows for the formation of regions where the system is less frustrated and locally freezes at a higher temperature.
We investigate analytically the low temperature behavior of the specific heat $C_v(T)$ for a large class of quantum disordered models within Mean Field approximation. This includes the vibrational modes of a lattice pinned by impurity disorder in the quantum regime, the quantum spherical $p$-spin-glass and a quantum Heisenberg spin glass. We exhibit a general mechanism, common to all these models, arising from the so-called marginality condition, responsible for the cancellation of the linear and quadratic contributions in $T$ in the specific heat. We thus find for all these models the Mean Fi…
We introduce a generalization of the cavity, or Bethe-Peierls, method that allows to follow Gibbs states when an external parameter, e.g. the temperature, is adiabatically changed. This allows to obtain new quantitative results on the static and dynamic behavior of mean field disordered systems such as models of glassy and amorphous materials or random constraint satisfaction problems. As a first application, we discuss the residual energy after a very slow annealing, the behavior of out-of-equilibrium states, and demonstrate the presence of temperature chaos in equilibrium. We also explore th…
We study statistical properties of peculiar responses in glassy systems at mesoscopic scales based on a class of mean-field spin-glass models which exhibit 1 step replica symmetry breaking. Under variation of a generic external field, a finite-sized sample of such a system exhibits a series of step wise responses which can be regarded as a finger print of the sample. We study in detail the statistical properties of the step structures based on a low temperature expansion approach and a replica approach. The spacings between the steps vanish in the thermodynamic limit so that arbitrary small bu…
In this paper we expose the results of our recent work on the dynamical TAP approach to mean field glassy systems. Our aim is to clarify the connection between free energy landscape and out of equilibrium dynamics in solvable models. Frequently qualitative explanations of glassy behaviour are based on the ``Free Energy Landscape Paradigm''. If its relevance for equilibrium properties is clear, the relationship between free energy landscape and out of equilibrium dynamics is not well understood yet. In this paper we clarify this relationship for the class of spin glass models which reproduce ph…
The Thouless, Anderson, Palmer (TAP) approach to thermodynamics of mean field spin-glasses is generalised to dynamics. A method to compute the dynamical TAP equations is developed and applied to the p-spin spherical model. In this context we show to what extent the dynamics can be represented as an evolution in the free energy landscape. In particular the relationship between the long-time dynamics and the local properties of the free energy landscape shows up explicitly within this approach. Conversely, by an instantaneous normal modes analysis we show that the local properties of the energy …
The reorientation of one small paramagnetic molecule (spin probe) in glassy polystyrene (PS) is studied by high-field Electron Spin Resonance spectroscopy at two different Larmor frequencies (190 and 285 GHz). The exponential distribution of the energy-barriers for the rotational motion of the spin probe is unambigously evidenced at both 240K and 270K. The same shape for the distribution of the energy-barriers of PS was evidenced by the master curves provided by previous mechanical and light scattering studies. The breadth of the energy-barriers distribution of the spin probe is in the range o…
We study thermally activated, low temperature equilibrium dynamics of elastic systems pinned by disorder using one loop functional renormalization group (FRG). Through a series of increasingly complete approximations, we investigate how the field theory reveals the glassy nature of the dynamics, in particular divergent barriers and barrier distributions controling the spectrum of relaxation times. A naive single relaxation time approximation for each wavevector is found to be unsatisfactory. A second approximation based on a random friction model, yields a size (L) dependent log-normal distrib…
We study the mean-field phase diagram of glassy systems in a field pointing in the direction of a metastable state. We find competition among a ``magnetized'' and a ``disordered'' phase, that are separated by a coexistence line as in ordinary first order phase transitions. The coexistence line terminates in a critical point, which in principle can be observed in numerical simulations of glassy models.
The critical behaviour of the dynamical transition of glassy system is controlled by a Replica Symmetric action with n=1 replicas. The most divergent diagrams in the loop expansion correspond at all orders to the solutions of a stochastic equation leading to perturbative dimensional reduction. The theory describe accurately numerical simulations of mean-field models.
We review recent theoretical progress on glassy dynamics, with special emphasis on the importance and universality of the ``aging regime'', which is relevant to many experimental situations. The three main subjects which we address are: (i) Phenomenological models of aging (coarsening, trap models), (ii) Analytical results for the low-temperature dynamics of mean-field models (corresponding to the mode-coupling equations); and (iii) Simple non-disordered models with glassy dynamics. We discuss the interrelation between these approaches, and also with previous work in the field. Several open pr…
We analyze the energy barriers that allow escapes from a given local minimum in a mean-field model of glasses. We perform this study by using the Kac-Rice method and computing the typical number of critical points of the energy function at a given distance from the minimum. We analyze their Hessian in terms of random matrix theory and show that for a certain regime of energies and distances critical points are index-one saddles and are associated to barriers. We find that the lowest barrier, important for activated dynamics at low temperature, is strictly lower than the "threshold" level above…
Monte Carlo studies of the 3D random field $XY$ model on simple cubic lattices of size $64^3$, using two different isotropic random-field probability distributions of moderate strength, show a glassy freezing behavior above $T_c$, and long-range order below $T_c$, consistent with our earlier results for weaker and stronger random fields. This model should describe random pinning in vortex lattices in type-II superconducting alloys, charge-density wave materials, and decagonal quasicrystals.
We study the interplay of superfluidity and glassy ordering of hard core bosons with random, frustrating interactions. This is motivated by bosonic systems such as amorphous supersolid, disordered superconductors with preformed pairs, and helium in porous media. We analyze the fully connected mean field version of this problem, which exhibits three low-temperature phases, separated by two continuous phase transitions: an insulating, glassy phase with an amorphous frozen density pattern, a nonglassy superfluid phase, and an intermediate phase, in which both types of order coexist. We elucidate …
The complex dynamics of an increasing number of systems is attributed to the emergence of a rugged energy landscape with an exponential number of metastable states. To develop this picture into a predictive dynamical theory I discuss how to compute the exponentially small probability of a jump from one metastable state to another. This is expressed as a path integral that can be evaluated by saddle-point methods in mean-field models, leading to a boundary value problem. The resulting dynamical equations are solved numerically by means of a Newton-Krylov algorithm in the paradigmatic spherical …
We consider the random field Ising model and show rigorously that the spin glass susceptibility at equilibrium is always bounded by the ferromagnetic susceptibility, and therefore that no spin glass phase can be present at equilibrium out of the ferromagnet critical line. When the magnetization is, however, fixed to values smaller than the equilibrium one, a glassy phase can exist, as we show explicitly on the Bethe lattice.
For the dynamical glassy transition in the $p$-spin mean field spin glass model a thermodynamic description is given. The often considered marginal states are not the relevant ones for this purpose. This leads to consider a cooling experiment on exponential timescales, where lower states are accessed. The very slow configurational modes are at quasi-equilibrium at an effective temperature. A system independent law is derived that expresses their contribution to the specific heat. $t/t_w$-scaling in the aging regime of two-time quantities is explained.
We show that facilitated spin models of cooperative dynamics introduced by Fredrickson and Andersen display on Bethe lattices a glassy behaviour similar to the one predicted by the mode-coupling theory of supercooled liquids and the dynamical theory of mean-field disordered systems. At low temperature such cooperative models show a two-step relaxation and their equilibration time diverges at a finite temperature according to a power-law. The geometric nature of the dynamical arrest corresponds to a bootstrap percolation process which leads to a phase space organization similar to the one of me…
The field-cooled magnetization (FCM) processes of Ising spin glasses under relatively small fields are investigated by experiment on Fe_{0.55}Mn_{0.45}TiO_3 and by numerical simulation on the three-dimensional Edwards-Anderson model. Both results are explained in a unified manner by means of the droplet picture. In particular, the cusp-like behavior of the FCM is interpreted as evidence, not for an equilibrium phase transition under a finite magnetic field, but for a dynamical (`blocking') transition frequently observed in glassy systems.
A method is presented for measuring the integrated response in Ising spin system without applying any perturbing field. Large-scale simulations are performed in order to show how the method works. Very precise measurements of the fluctuation-dissipation ratio are presented for 3 different Ising models: the 2-dimensional ferromagnetic model, the mean-field diluted 3-spin model, and the 3-dimensional Edwards-Anderson model.
We discuss the slow relaxation phenomenon in glassy systems by means of replicas by constructing a static field theory approach to the problem. At the mean field level we study how criticality in the four point correlation functions arises because of the presence of soft modes and we derive an effective replica field theory for these critical fluctuations. By using this at the Gaussian level we obtain many physical quantities: the correlation length, the exponent parameter that controls the Mode-Coupling dynamical exponents for the two-point correlation functions, and the prefactor of the crit…
We review the field of the glass transition, glassy dynamics and aging from a statistical mechanics perspective. We give a brief introduction to the subject and explain the main phenomenology encountered in glassy systems, with a particular emphasis on spatially heterogeneous dynamics. We review the main theoretical approaches currently available to account for these glassy phenomena, including recent developments regarding mean-field theory of liquids and glasses, novel computational tools, and connections to the jamming transition. Finally, the physics of aging and off-equilibrium dynamics e…
The field-cooled (FC) process on an Ising spin-glass model is investigated by a standard Monte Calro (MC) method on one hand, and the equilibrium magnetization of the same system is evaluated by the exchang MC method on the other hand. The two types of simulation reveal intriguing glassy (nonequilibrium) dynamic properties of the FC magnetization (FCM) of the system. Particularly, the FCM decrease is observed when the FC process is halted at a low temperater, although its value is smaller than the corresponding equilibrium value. We present a comprehensive interpretation of such peculiar pheno…
We present a detailed study of the electronic transport properties on a single crystalline specimen of the moderately disordered heavy fermion system URh$_2$Ge$_2$. For this material, we find glassy electronic transport in a single crystalline compound. We derive the temperature dependence of the electrical conductivity and establish metallicity by means of optical conductivity and Hall effect measurements. The overall behavior of the electronic transport properties closely resembles that of metallic glasses, with at low temperatures an additional minor spin disorder contribution. We argue tha…
We investigate the critical properties of the four-state commutative random permutation glassy Potts model in three and four dimensions by means of Monte Carlo simulation and of a finite size scaling analysis. Thanks to the use of a field programmable gate array we have been able to thermalize a large number of samples of systems with large volume. This has allowed us to observe a spin-glass ordered phase in d=4 and to study the critical properties of the transition. In d=3, our results are consistent with the presence of a Kosterlitz-Thouless transition, but we cannot exclude transient effect…
By making use of the Langevin dynamics and its generating functional (GF) formulation the influence of the long-range nature of the interaction on the tendency of the glass formation is systematically investigated. In doing so two types of models is considered: (i) the non-disordered model with a pure repulsive type of interaction and (ii) the model with a randomly distributed strength of interaction (a quenched disordered model). The long-ranged potential of interaction is scaled with a number of particles $N$ in such a way as to enable for GF the saddle-point treatment as well as the systema…
We present new results obtained by field effect measurements on insulating granular Al thin films. First, reproducible and stable conductance fluctuations are seen in micron size samples as a function of gate voltage. The anomalous field effect and its slow relaxation already known to exist in macroscopic samples are shown to still exist in small samples and to have no influence on the fluctuations pattern. Secondly, "true" aging is demonstrated, i.e. the anomalous field effect relaxation depends on the time elapsed since the cooling, the longer this time the longer it takes for the system to …
Replica Field Theory for a Generalized Franz--Parisi Potential of Inhomogeneous Glassy Systems: New Closure and the Associated Self-Consistent Equation
We present a study of non-equilibrium phenomena observed in the electrical conductance of insulating granular aluminium thin films. An anomalous field effect and its slow relaxation are studied in some detail. The phenomenology is very similar to the one already observed in indium oxide. The origin of the phenomena is discussed. In granular systems, the present experiments can naturally be interpreted along two different lines. One relies on a slow polarisation in the dielectric surrounding the metallic islands. The other one relies on a purely electronic mechanism: the formation of an electro…
The spherical p-spin model is not only a fundamental model in statistical mechanics of disordered system, but has recently gained popularity since many hard problems in machine learning can be mapped on it. Thus the study of the out of equilibrium dynamics in this model is interesting both for the glass physics and for its implications on algorithms solving NP-hard problems. We revisit the long-time limit of the out of equilibrium dynamics of mean-field spherical mixed p-spin models. We consider quenches (gradient descent dynamics) starting from initial conditions thermalized at some temperatu…
The theory of glassy fluctuations can be formulated in terms of disordered effective potentials. While the properties of the average potentials are well understood, the study of the fluctuations has been so far quite limited. Close to the MCT transition, fluctuations induced by the dynamical heterogeneities in supercooled liquids can be described by a cubic field theory in presence of a random field term. In this paper we set up the general problem of the large deviations going beyond the assumption of the vicinity to $T_{MCT}$ and analyze it in the paradigmatic case of spherical ($p$-spin) gl…
We consider an invariant random matrix model where the standard Gaussian potential is distorted by an additional single pole of order $m$. We compute the average or macroscopic spectral density in the limit of large matrix size, solving the loop equation with the additional constraint of vanishing trace on average. The density is generally supported on two disconnected intervals lying on the two sides of the pole. In the limit of having no pole, we recover the standard semicircle. Obtained in the planar limit, our results apply to matrices with orthogonal, unitary or symplectic symmetry alike.…
We revisit the field effect procedure used to characterise the slow dynamics of glassy Anderson insulators. It is shown that in the slowest systems the procedure fails and the "characteristic" time values extracted are not intrinsic but determined by the experimental procedure itself. In other cases (like lightly doped indium oxide) qualitative indications about the dynamics might be obtained, however the times extracted cannot be seen as characteristic relaxation times of the system in any simple manner, and more complete experiments are necessary. Implications regarding the effect of carrier…
We consider the critical properties of points of continuous glass transition as one can find in liquids in presence of constraints or in liquids in porous media. Through a one loop analysis we show that the critical Replica Field Theory describing these points can be mapped in the $ϕ^4$-Random Field Ising Model. We confirm our analysis studying the finite size scaling of the $p$-spin model defined on sparse random graph, where a fraction of variables is frozen such that the phase transition is of a continuous kind.
We investigate the replica symmetry broken (RSB) phase of spin glass (SG) models in a random field defined on Bethe lattices at zero temperature. From the properties of the RSB solution we deduce a closed equation for the extreme values of the cavity fields. This equation turns out not to depend on the parameters defining the RSB, and it predicts that the spontaneous RSB does not take place homogeneously on the whole system. Indeed, there exist spins having the same effective local field in all local ground states, exactly as in the replica symmetric (RS) phase, while the spontaneous RSB manif…
The spherical mean field approximation of a spin-1 model with p-body quenched disordered interaction is investigated. Depending on temperature and chemical potential the system is found in a paramagnetic or in a glassy phase and the transition between these phases can be of different nature. In given conditions inverse freezing occurs. As $p=2$ the glassy phase is replica symmetric and the transition is always continuous in the phase diagram. For $p>2$ the exact solution for the glassy phase is obtained by the one step replica symmetry breaking Ansatz. Different scenarios arise for both the dy…
We study both analytically, using the renormalization group (RG) to two loop order, and numerically, using an exact polynomial algorithm, the disorder-induced glass phase of the two-dimensional XY model with quenched random symmetry-breaking fields and without vortices. In the super-rough glassy phase, i.e. below the critical temperature $T_c$, the disorder and thermally averaged correlation function $B(r)$ of the phase field $θ(x)$, $B(r) = \bar{<[θ(x) - θ(x+ r) ]^2>}$ behaves, for $r \gg a$, as $B(r) \simeq A(τ) \ln^2 (r/a)$ where $r = |r|$ and $a$ is a microscopic length scale. We derive th…
We investigate the conditions required for general spin systems with frustration and disorder to display self-organized criticality, a property which so far has been established only for the fully-connected infinite-range Sherrington-Kirkpatrick Ising spin-glass model [Phys. Rev. Lett. 83, 1034 (1999)]. Here we study both avalanche and magnetization jump distributions triggered by an external magnetic field, as well as internal field distributions in the short-range Edwards-Anderson Ising spin glass for various space dimensions between 2 and 8, as well as the fixed-connectivity mean-field Vian…
We search for a Gardner transition in glassy glycerol, a standard molecular glass, measuring the third harmonics cubic susceptibility $χ_3^{(3)}$ from slightly below the usual glass transition temperature down to $10K$. According to the mean field picture, if local motion within the glass were becoming highly correlated due to the emergence of a Gardner phase then $χ_3^{(3)}$, which is analogous to the dynamical spin-glass susceptibility, should increase and diverge at the Gardner transition temperature $T_G$. We find instead that upon cooling $| χ_3^{(3)} |$ decreases by several orders of mag…
The following properties are in the present literature associated with the behavior of super-cooled glass-forming liquids: faster than exponential growth of the relaxation time, dynamical heterogeneities, growing point-to-set correlation length, crossover from mean field behavior to activated dynamics. In this paper we argue that these properties are also present in a much simpler situation, namely the melting of the bulk of an ordered phase beyond a first order phase transition point. This is a promising path towards a better theoretical, numerical and experimental understanding of the above …
A theoretical analysis [Angelani et al., Phys. Rev. Lett. 96, 065702 (2006)] predicts glassy behaviour of light in a nonlinear random medium. This implies slow dynamics related to the presence of many metastable states. We consider very general equations (that also apply to other systems, like Bose-Condensed gases) describing light in a disordered non-linear medium and through some approximations we relate them to a mean-field spin-glass-like model. The model is solved by the replica method, and replica-symmetry breaking phase transition is predicted. The transition describes a mode-locking pr…
In this thesis we investigate the Renormalization Group (RG) approach in finite-dimensional glassy systems, whose critical features are still not well-established, or simply unknown. We focus on spin and structural-glass models built on hierarchical lattices, which are the simplest non-mean-field systems where the RG framework emerges in a natural way. The resulting critical properties shed light on the critical behavior of spin and structural glasses beyond mean field, and suggest future directions for understanding the criticality of more realistic glassy systems.
Glassy systems are disordered systems characterized by extremely slow dynamics. Examples are supercooled liquids, whose dynamics slow down under cooling. The specific pattern of slowing-down depends on the material considered. This dependence is poorly understood, in particular, it remains generally unclear which aspects of the microscopic structures control the dynamics and other macroscopic properties. Attacking this question is one of the two main aspects of this dissertation. We have introduced a new class of models of supercooled liquids, which captures the central aspects of the correspo…
In order to study analytically the nature of the jamming transition in granular material, we have considered a cavity method mean field theory, in the framework of a statistical mechanics approach, based on Edwards' original idea. For simplicity we have applied the theory to a lattice model and a transition with exactly the same nature of the glass transition in mean field models for usual glass formers is found. The model is also simulated in three dimensions under tap dynamics and a jamming transition with glassy features is observed. In particular two step decays appear in the relaxation fu…
We study rough high-dimensional landscapes in which an increasingly stronger preference for a given configuration emerges. Such energy landscapes arise in glass physics and inference. In particular we focus on random Gaussian functions, and on the spiked-tensor model and generalizations. We thoroughly analyze the statistical properties of the corresponding landscapes and characterize the associated geometrical phase transitions. In order to perform our study, we develop a framework based on the Kac-Rice method that allows to compute the complexity of the landscape, i.e. the logarithm of the ty…
