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无扫描量子傅里叶变换中红外光谱法用于固体与表面分析

Scanless quantum Fourier-transform mid-infrared spectroscopy for solids and surface analysis

Paul Gattinger, Michela Conti, Franziska Dietz, Andrei N. Halangescu Moldovan, Andreas W. Schell, Markus Brandstetter, Ivan Zorin

arXiv 2609.37281首次发表:更新:

发表机构

Research Center for Non-Destructive Testing; Johannes Kepler University(无损检测研究中心; 约翰内斯·开普勒大学)

机构由 AI 辅助整理,请以论文原文为准。

AI 中文总结

本文实现了一种无扫描量子傅里叶变换中红外显微光谱仪,无需扫描延迟即可在100毫秒内获取光谱,并展示了其在固体、表面及浑浊介质中的高光谱成像能力。

AI 中文摘要

量子红外(IR)光谱是一种基于非线性干涉测量和未探测光子量子传感的新技术。在该方法中,光谱上远分离的关联光子对分别用于探测和传感。因此,探测波长域(中红外)与检测光谱范围(近红外)显著不同,这实现了散粒噪声限制且成本有效的传感方案,对应用计量学具有吸引力。在本文中,我们实现并采用了一台定制的无扫描量子傅里叶变换中红外(sQFTIR)显微光谱仪,用于固体和界面的化学表征与分析。sQFTIR系统采用光谱域采集,无需扫描光学延迟。这导致增强的灵敏度和短测量时间,因此能够在100毫秒内快速获取光谱,覆盖从3000 cm$^{-1}$到2400 cm$^{-1}$的光谱带。我们方法的能力通过干燥药物(金表面上的胰岛素)的高光谱中红外成像以及对钞票上安全特征的调查得到展示。此外,我们展示了通过浑浊陶瓷介质的高光谱成像和光谱分析。

英文摘要

Quantum infrared (IR) spectroscopy is a novel technique based on nonlinear interferometry and quantum sensing with undetected photons. In this approach, spectrally far-separated correlated photon pairs are used for detection and probing, respectively. Hence, the probing wavelength domain (mid-IR) is substantially different from the detection spectral range (near-IR), which enables shot-noise-limited and cost-effective sensing schemes attractive for applied metrology. In this paper, we implement and employ a custom-built scanless quantum Fourier-transform mid-IR (sQFTIR) microspectrometer for chemical characterization and analysis of solids and interfaces. The sQFTIR system employs spectral-domain acquisition, without the need to scan the optical delay. This results in enhanced sensitivity and short measurement times and therefore enables rapid spectral acquisitions in 100~ms spanning a spectral band from 3000 cm$^{-1}$ - 2400 cm$^{-1}$. The capabilities of our approach are demonstrated for hyperspectral mid-IR imaging of dried pharmaceuticals (insulin on a gold surface) and investigation of a security feature on a banknote. Furthermore, we demonstrate hyperspectral imaging and spectroscopy through a turbid ceramic medium.

Comments8 pages, 4 figures

论文原文

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