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arXiv 2607.15332cond-mat.mtrl-sci

通过氧化固相外延生长的SiGe层中的自发纳米图案化和应变弛豫

Spontaneous Nanopatterning and Strain Relaxation in SiGe Layers Grown by Oxidative Solid Phase Epitaxy

Sophie E. Bierer, Trevor R. Smith, Arezoo Mafi, Sunzhuoran Wang, Chengqian Liao, Vatsalkumar Patel, Andrew P. Knights, Ryan B. Lewis

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中文总结 AI 辅助

研究硅上III-V族材料异质外延问题,通过氧化固相外延生长SiGe层形成超薄应变弛豫缓冲层,利用该过程中Ge浓度变化的纳米图案化及位错网络,分析图案间距获取局部应变状态,为III-V光电子异质外延设计缓冲层提供重要方法。

中文摘要 AI 辅助

硅上III-V族材料的晶圆级单片集成将带来用于数据、计算和其他应用的革命性光电子硬件。然而,III-V族在硅上的异质外延需要克服材料之间的大晶格和热失配,并降低位错密度。在这项工作中,我们探索了Ge+注入的Si(111)的氧化固相外延(SPE),以形成用于在硅上异质外延的超薄应变弛豫SiGe变质缓冲层。SPE过程导致样品表面Ge浓度变化的纳米图案化,通过扫描和透射电子显微镜(SEM和TEM)可见。浓度图案化是SiGe/Si界面处肖克利部分位错的六边形网络的结果。分析SEM观察到的图案间距被证明是一种获取SiGe层局部应变状态的简单、无损方法。这项工作对于在硅平台上为III-V光电子异质外延设计超薄SiGe变质缓冲层很重要。

英文摘要

The wafer-scale monolithic integration of III-V materials on Si would lead to revolutionary optoelectronic hardware for data, computing and other applications. However, heteroepitaxy of III-Vs on Si requires overcoming the large lattice and thermal mismatches between the materials and reducing threading dislocations densities. In this work, we explore the oxidative solid phase epitaxy (SPE) of Ge+ implanted Si(111) to form ultra-thin strain-relieving SiGe metamorphic buffer layers for heteroepitaxy on Si. The SPE process is shown to result in a nanopatterning of the Ge concentration variation across the sample surface, visible by scanning and transmission electron microscopy (SEM and TEM). The concentration patterning is the result of a hexagonal network of Shockley partial dislocations at the SiGe/Si interface. Analyzing the pattern spacing observed by SEM is demonstrated as an easy, non-destructive method for obtaining the local strain state of SiGe layers. This work is important for engineering ultra-thin SiGe metamorphic buffer layers for III-V optoelectronics heteroepitaxy on the silicon platform.

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