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arXiv 2603.21765cond-mat.stat-mech
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克劳修斯熵在孤立系统中能量形式转换下的严格熵减:理论证明、数值示例与关键审查

Strict Entropy Decrease of Clausius Entropy in an Isolated System with Energy-Form Conversion: Theoretical Proof, Numerical Illustration, and Critical Examination

Key Laboratory for Special Area Highway Engineering of Ministry of Education(教育部特殊地区公路工程重点实验室);Chang’an University(长安大学)

Ting Peng

AI总结:

本文通过理论证明和数值示例,探讨了克劳修斯熵在孤立系统中能量形式转换时的严格熵减现象,分析了不同公理集间的兼容性问题。

摘要:

本文仅基于明确陈述的物理假设和严格逻辑推导,旨在对克劳修斯框架内的第二定律主张进行严格压力测试。我们直接使用克劳修斯熵定义处理具有能量形式转换的孤立复合系统。从低温释放子系统抽取热量,转换为电能,再作为热量传递给高温子系统。在理想极限下,电学部分对克劳修斯熵会计贡献可忽略,因此建模的热库克劳修斯总和为$$ ΔS_{\mathrm{Cl}} = Q\!\left(\frac{1}{T_B}-\frac{1}{T_A}\right) < 0 $$。本文提供了推导、数值示例和范围分析;任何声称的矛盾应被解释为不同公理集之间的兼容性问题,而不是克劳修斯会计中的代数错误。

英文摘要:

This paper is accountable only to explicitly stated physical assumptions and strict logical inference. Its goal is to run a rigorous stress test of second-law claims within the Clausius framework. We work directly with \textbf{Clausius's entropy definition} for an isolated composite with energy-form conversion. Heat is withdrawn from a cold releasing subsystem with relatively small heat capacity, converted to electrical energy, and then delivered as heat to a hotter subsystem. In the ideal limit, the electrical leg contributes negligibly to Clausius entropy accounting, so the modeled reservoir Clausius sum is \[ ΔS_{\mathrm{Cl}} = Q\!\left(\frac{1}{T_B}-\frac{1}{T_A}\right) < 0. \] The paper provides a derivation, numerical illustrations, and a scope analysis; any claimed contradiction should be interpreted as a compatibility issue between different axiom sets, not as an algebraic error in the Clausius bookkeeping above.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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