受限原始模型的电双层电容:介观理论与缔合平均球近似之间的联系
On the electrical double layer capacitance of the restricted primitive model: a link between the mesoscopic theory and the associative mean spherical approximation
AI总结:
本文比较了介观理论与缔合平均球近似在电双层电容和自由离子密度上的结果,发现两者在高密度低温下吻合良好。
摘要:
将介观理论得到的电双层电容和“自由离子”密度结果与缔合平均球近似的相应结果进行了比较。第一种理论考虑了电荷密度的涨落,而第二种理论假设自由离子和离子对根据质量作用定律处于化学平衡。我们的结果表明,在高密度和低温下,两种理论之间具有相当好的一致性。
英文摘要:
The results for the electrical double layer capacitance and the density of ``free ions'' obtained from the mesoscopic theory are compared with the corresponding results of the associative mean spherical approximation. While the first theory takes into account the fluctuations of the charge density, the second theory assumes that the free ions and ion pairs are in chemical equilibrium according to the mass action law. Our results demonstrate a fairly good agreement between the two theories at high densities and low temperatures.
机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。