Relaxation rates provide important characteristics both for classical and quantum processes. Essentially they control how fast the system thermalizes, equilibrates, {decoheres, and/or dissipates}. Moreover, very often they are directly accessible to be measured in the laboratory and hence they define key physical properties of the system. Experimentally measured relaxation rates can be used to test validity of a particular theoretical model. Here we analyze a fundamental question: {\em does quantum mechanics provide any nontrivial constraint for relaxation rates?} We prove the conjecture formulated a few years ago that any quantum channel implies that a maximal rate is bounded from above by the sum of all the relaxation rates divided by the dimension of the Hilbert space. It should be stressed that this constraint is universal (it is valid for all quantum systems with finite number of energy levels) and it is tight (cannot be improved). In addition, the constraint plays an analogous role to the seminal Bell inequalities and the well known Leggett-Garg inequalities (sometimes called temporal Bell inequalities). Violations of Bell inequalities rule out local hidden variable models, and violations of Leggett-Garg inequalities rule out macrorealism. Similarly, violations of the bound rule out completely positive-divisible evolution.
Dissipation- versus Chaos-Induced Relaxation in Non-Markovian Quantum Many-Body Systems
Universidade de Lisboa（里斯本大学）；Beijing Computational Science Research Center（北京计算科学研究中心）；Technische Universität Dresden（德累斯顿工业大学）；University of Cambridge（剑桥大学）
Recently remarkable progress in quantum technology has been witnessed. In view of this it is important to investigate an open quantum system as a model of such quantum devices. Quantum devices often require extreme conditions such as very low temperature for the devices to operate. Dynamics can be non-Markovian in such a situation in contrast with Markovian dynamics in high temperature regime. This observation necessitates us to investigate a non-Markovian open quantum system, both theoretically and experimentally. In this paper, we report two important results: 1) Exact solution of a simple b…
The non-Markovian dynamics of a three-level quantum system coupled to a bosonic environment is a difficult problem due to the lack of an exact dynamic equation such as a master equation. We present for the first time an exact quantum trajectory approach to a dissipative three-level model. We have established a convolutionless stochastic Schrödinger equation called time-local quantum state diffusion (QSD) equation without any approximations, in particular, without Markov approximation. Our exact time-local QSD equation opens a new avenue for exploring quantum dynamics for a higher dimensional q…
It is shown that by fitting a Markovian quantum master equation to the numerical solution of the time-dependent Schrödinger equation of a system of two spin-1/2 particles interacting with a bath of up to 34 spin-1/2 particles, the former can describe the dynamics of the two-spin system rather well. The fitting procedure that yields this Markovian quantum master equation accounts for all non-Markovian effects in as much the general structure of this equation allows and yields a description that is incompatible with the Lindblad equation.
We characterize to what extent it is possible to modify the stationary states of a quantum dynamical semigroup, that describes the irreversible evolution of a two-level system, by means of an auxiliary two-level system. We consider systems that can be initially entangled or uncorrelated. We find that the indirect control of the stationary states is possible, even if there are not initial correlations, under suitable conditions on the dynamical parameters characterizing the evolution of the joint system.
A key feature of non-equilibrium thermodynamics is the Markovian, deterministic relaxation of coarse observables such as, for example, the temperature difference between two macroscopic objects which evolves independently of almost all details of the initial state. We demonstrate that the unitary dynamics for moderately sized spin-1/2 systems may yield the same type of relaxation dynamics for a given magnetization difference. This observation might contribute to the understanding of the emergence of thermodynamics within closed quantum systems.
Asymptotic relaxation in quantum Markovian dynamics
Universität Ulm（乌尔姆大学）；Center for Integrated Quantum Science and Technology (IQST), Ulm University（乌尔姆大学集成量子科学与技术中心）；Nicolaus Copernicus University（尼古拉·哥白尼大学）
Quantum stochastic methods based on effective wave functions form a framework for investigating the generally non-Markovian dynamics of a quantum-mechanical system coupled to a bath. They promise to be computationally superior to the master-equation approach, which is numerically expensive for large dimensions of the Hilbert space. Here, we numerically investigate the suitability of a known stochastic Schrödinger equation that is local in time to give a description of thermal relaxation and energy transport. This stochastic Schrödinger equation can be solved with a moderate numerical cost, ind…
The recently developed formalism of Markovian master equations for quantum open systems with external periodic driving is applied to the theory of dynamical decoupling by periodic control. This new approach provides a more detailed quantitative picture of this phenomenon applicable both to traditional NMR spectroscopy and to recent attempts of decoherence reduction in quantum devices. For popular choices of bath spectral densities and a two-level system, exact formulas for the relaxation rates are available. In the context of NMR imaging, the obtained formulas allow the extraction of a new par…
We consider the problem of constructing a "universal set" of Markovian processes, such that any Markovian open quantum system, described by a one-parameter semigroup of quantum channels, can be simulated through sequential simulations of processes from the universal set. In particular, for quantum systems of dimension $d$, we explicitly construct a universal set of semigroup generators, parametrized by $d^2-3$ continuous parameters, and prove that a necessary and sufficient condition for the dynamical simulation of a $d$ dimensional Markovian quantum system is the ability to implement a) quant…
For sufficiently low reservoir temperatures, it is known that open quantum systems subject to decoherent interactions with the reservoir relax towards their ground state in the weak coupling limit. Within the framework of quantum master equations, this is formalized by the Born-Markov-secular (BMS) approximation, where one obtains the system Gibbs state with the reservoir temperature as a stationary state. When the solution to some problem is encoded in the (isolated) ground state of a system Hamiltonian, decoherence can therefore be exploited for computation. The computational complexity is t…
A universal characterization of non-Markovianity for any open hybrid quantum systems is presented. This formulation is based on the negativity volume of the generalized Wigner function, which serves as an indicator of the quantum correlations in any composite quantum systems. It is shown, that the proposed measure can be utilized for any single or multi-partite quantum system, containing any discrete or continuous variables. To demonstrate its power in revealing non-Markovianity in such quantum systems, we additionally consider a few illustrative examples.
Energy transfer (relaxation) phenomena are ubiquitous in nature. At a macroscopic level, the phenomenological theory of heat (Fourier law) successfully describes heat transfer and energy flow. However, its microscopic origin is still under debate. This is because the phenomena can contain many-body, multi-scale, nonequilibrium, and even quantum mechanical aspects, which present significant challenges to theories addressing energy transfer phenomena in physics, chemistry and biology. In this paper, we describe our recent theoretical attempts to treat vibrational energy relaxation (VER) in biomo…
To understand typical dynamics of an open quantum system in continuous time, we introduce an ensemble of random Lindblad operators, which generate Markovian completely positive evolution in the space of density matrices. Spectral properties of these operators, including the shape of the spectrum in the complex plane, are evaluated by using methods of free probabilities and explained with non-Hermitian random matrix models. We also demonstrate universality of the spectral features. The notion of ensemble of random generators of Markovian qauntum evolution constitutes a step towards categorizati…
In order to engineer an open quantum system and its evolution, it is essential to identify and control the memory effects. These are formally attributed to the non-Markovianity of dynamics that manifests itself by the evolution being indivisible in time, a property which can be witnessed by a non-monotonic behavior of contractive functions or correlation measures. We show that by monitoring directly the entanglement behavior of a system in a tripartite setting it is possible to witness all invertible non-Markovian dynamics, as well as all (also non-invertible) qubit evolutions. This is achieve…
Although the conditions for performing arbitrary unitary operations to simulate the dynamics of a closed quantum system are well understood, the same is not true of the more general class of quantum operations (also known as superoperators) corresponding to the dynamics of open quantum systems. We propose a framework for the generation of Markovian quantum dynamics and study the resources needed for universality. For the case of a single qubit, we show that a single nonunitary process is necessary and sufficient to generate all unital Markovian quantum dynamics, whereas a set of processes para…
Physicists are attracted to open-system dynamics, how quantum systems evolve, and how they can protected from unnecessary environmental noise, especially environmental memory effects are not negligible, as with non-Markovian approximations. There are several methods to solve master equation of non-Markovian cases, we obtain the solutions of quantum-state-diffusion equation for a two qubit system using perturbation method, which under influence of various types of environmental noises, i.e., relaxation, dephasing and mix of them. We found that mixing these two types of noises benefit the quantu…
We perform a first- principles derivation of the general master equation to study the non-Markovian dynamics of a two-level atom (2LA) interacting with an electromagnetic field (EMF). We use the influence functional method which can incorporate the full backreaction of the field on the atom, while adopting Grassmannian variables for the 2LA and the coherent state representation for the EMF. We find exact master equations for the cases of a free quantum field and a cavity field in the vacuum. In response to the search for mechanisms to preserve maximal coherence in quantum computations in ion t…
We study the non-Markovian dynamics of a qubit made up of a two-level atom interacting with an electromagnetic field (EMF) initially at finite temperature. Unlike most earlier studies where the bath is assumed to be fixed, we study the coherent evolution of the combined qubit-EMF system, thus allowing for the back-action from the bath on the qubit and the qubit on the bath in a self-consistent manner. In this way we can see the development of quantum correlations and entanglement between the system and its environment, and how that affects the decoherence and relaxation of the system. We find …
We exploit the properties of chain mapping transformations of bosonic environments to identify a finite collection of modes able to capture the characteristic features, or fingerprint, of the environment. Moreover we show that the countable infinity of residual bath modes can be replaced by a universal Markovian closure, namely a small collection of damped modes undergoing a Lindblad-type dynamics whose parametrization is independent of the spectral density under consideration. We show that the Markovian closure provides a quadratic speed-up with respect to standard chain mapping techniques an…
Continuous-time Markovian evolution appears to be manifestly different in classical and quantum worlds. We consider ensembles of random generators of $N$-dimensional Markovian evolution, quantum and classical ones, and evaluate their universal spectral properties. We then show how the two types of generators can be related by superdecoherence. In analogy with the mechanism of decoherence, which transforms a quantum state into a classical one, superdecoherence can be used to transform a Lindblad operator (generator of quantum evolution) into a Kolmogorov operator (generator of classical evoluti…
The collective and purely relaxational dynamics of quantum many-body systems after a quench at temperature $T=0$, from a disordered state to various phases is studied through the exact solution of the quantum Langevin equation of the spherical and the $O(n)$-model in the limit $n\to\infty$. The stationary state of the quantum dynamics is shown to be a non-equilibrium state. The quantum spherical and the quantum $O(n)$-model for $n\to\infty$ are in the same dynamical universality class. The long-time behaviour of single-time and two-time correlation and response functions is analysed and the un…
Operation Mpemba effect: Breakdown of resource-Markovianity of free dynamics
Institute of Physics, Chinese Academy of Sciences（中国科学院物理研究所）；School of Physical Sciences, University of Chinese Academy of Sciences（中国科学院大学物理科学学院）；School of Physics and Optoelectronics, South China University of Technology（华南理工大学物理与光电学院）；Beijing Academy of Quantum Information Sciences（北京量子信息科学研究院）；Hefei National Laboratory（合肥国家实验室）
Non-Markovian processes can often be turned Markovian by enlarging the set of variables. Here we show, by an explicit construction, how this can be done for the dynamics of a Brownian particle obeying the generalized Langevin equation. Given an arbitrary bath spectral density $J_{0}$, we introduce an orthogonal transformation of the bath variables into effective modes, leading stepwise to a semi-infinite chain with nearest-neighbor interactions. The transformation is uniquely determined by $J_{0}$ and defines a sequence $\{J_{n}\}_{n\in\mathbb{N}}$ of residual spectral densities describing the…
In 1976, Gorini, Kossakowski, Sudarshan and Lindblad independently discovered a general form of master equations for an open quantum Markovian dynamics. In honor of all the authors, the equation is nowadays called the GKLS master equation. In this paper, we show universal constraints on the relaxation times valid for any d-level GKLS master equations, which is a generalization of the well-known constraints for 2-level systems. Specifically, we show that any relaxation rate, the inverse-relaxation time, is not greater than half of the sum of all relaxation rates. Since the relaxation times are …
We are interested in dynamics of a system in an environment, or an open system. Such phenomena like {\it crossover} from Markovian to non-Markovian relaxation and {\it thermal equilibration} are of our interest. Open systems have experimentally been studied with ultra cold atoms, ions in traps, optics, and cold electric circuits because well isolated systems can be prepared here and thus the effects of environments can be controlled. We point out that some molecules solved in isotropic liquid are well isolated and thus they can also be employed for studying open systems in Nuclear Magnetic Res…
Ergodicity-breaking and slow relaxation are intriguing aspects of nonequilibrium dynamics both in classical and in quantum settings. These phenomena are typically associated with phase transitions, e.g. the emergence of metastable regimes near a first-order transition or scaling dynamics in the vicinity of critical points. Despite being of fundamental interest the associated divergent time scales are a hindrance when trying to explore steady-state properties. Here we show that the relaxation dynamics of Markovian open quantum systems can be accelerated exponentially by devising an optimal unit…
We investigate the non-Markovian dynamics of an open Ising model simulated by a superconducting circuit. The quantum many-body system is weakly coupled to a white, pink- or blue-colored environment. The relaxation of the system in the strong inter-qubit interaction regime shows a metastable behaviour. In comparison with the dissipative system in the Markovian limit, the negative memory of the blue-colored noise weakens the system's relaxation. However, for the pink-colored noise the relaxation rate of the system is enhanced due to the positive memory effect. The understanding of quantum many-b…
The Lieb-Robinson bound shows the existence of a maximum speed of signal propagation in discrete quantum mechanical systems with local interactions. This generalizes the concept of relativistic causality beyond field theory, and provides a powerful tool in theoretical condensed matter physics and quantum information science. Here, we extend the scope of this seminal result by considering general Markovian quantum evolution, where we prove that an equivalent bound holds. In addition, we use the generalized bound to demonstrate that correlations in the stationary state of a Markov process decay …
Dynamical decoupling as a quantum control strategy aims at suppressing quantum decoherence adopting the popular philosophy that the disorder in the unitary evolution of the open quantum system caused by environmental noises should be neutralized by a sequence of ordered or well-designed external operations acting on the system. This work studies the solution of quantum-state-diffusion equations by mixing two channels of environmental noises, i.e., relaxation (dissipation) and dephasing. It is interesting to find in two-level and three-level atomic systems that a non-Markovian relaxation or dis…
By using the effective non-Markovian measure [H.P. Breuer, E.M. Laine, J. Piilo, Phys. Rev. Lett. 103, 210401 (2009)], we investigate non-Markovian dynamics of a pair of two-level atoms (TLAs) system, each of which interacting with a local reservoir. We show that subsystem dynamics can be controlled by manipulating the coupling between TLAs, temperature and relaxation rate of the atoms. Moreover, the correlation between non-Markovianity of subsystem and entanglement between the subsystem and the structured bath is investigated, the results show that the emergence of non-Markovianity has a nega…
The large deviation theory has recently been applied to open quantum systems to uncover dynamical crossovers in the space of quantum trajectories associated to Markovian evolutions. Such dynamical crossovers are characterized by qualitative changes in the fluctuations of rare quantum jump trajectories, and have been observed in the statistics of coherently driven quantum systems. In this article we investigate the counting statistics of rare quantum trajectories of an undriven system undergoing a pure relaxation process, namely, Markovian exciton transport. We find that dynamical crossovers oc…
We study a driven two-state system interacting with a structured environment. We introduce the non-Markovian master equation ruling the system dynamics, and we derive its analytic solution for general reservoir spectra. We compare the non-Markovian dynamics of the Bloch vector for two classes of reservoir spectra: the Ohmic and the Lorentzian reservoir. Finally, we derive the analytic conditions for complete positivity with and without the secular approximation. Interestingly, the complete positivity conditions have a transparent physical interpretation in terms of the characteristic timescale…
Quantum computing has the potential to revolutionize computing for certain classes of problems with exponential scaling, and yet this potential is accompanied by significant sensitivity to noise, requiring sophisticated error correction and mitigation strategies. Here we simulate the relaxations of stationary states at different frequencies on several quantum computers to obtain unique spectroscopic fingerprints of their noise. Response functions generated from the data reveal a clear signature of non-Markovian dynamics, demonstrating that each of the quantum computers acts as a non-Markovian …
Strongly coupled organic systems are characterized by unusually large Rabi splittings, even in the vacuum state. They show the counter-intuitive feature of a lifetime of the lower polariton state longer than for all other excited states. Here we build up a new theoretical framework to understand the dynamics of such coupled system. In particular, we show that the non-Markovian character of the relaxation of the dressed organic system explains the long lifetime of the lower polariton state.
Universal Precision Limits in General Open Quantum Systems
Center for Gravitational Physics and Quantum Information, Yukawa Institute for Theoretical Physics, Kyoto University（京都大学汤川理论物理研究所引力物理与量子信息中心）；Department of Physics, Kyoto University（京都大学物理学系）
Markov length can diverge in systems whose universal physics is spatially Markovian
University of California at San Diego（加利福尼亚大学圣地亚哥分校）；Kavli Institute for Theoretical Physics, University of California, Santa Barbara（加州大学圣塔芭芭拉分校卡弗里理论物理研究所）
A maximal steady-state fermionic entanglement of a nanoelectronic system is generated in finite temperature non-Markovian environments. The fermionic entanglement dynamics is presented by connecting the exact solution of the system with an appropriate definition of fermionic entanglement. We prove that the two understandings of the dissipationless non-Markovian dynamics, namely the bound state and the modified Laplace transformation are completely equivalent. For comparison, the steady-state entanglement is also studied in the wide-band limit and Born-Markovian approximation. When the environm…
Open quantum systems exhibit a range of novel out-of-equilibrium behavior due to the interplay between coherent quantum dynamics and dissipation. Of particular interest in these systems are driven, dissipative transitions, the emergence of dynamical phases with novel broken symmetries, and critical behavior that lies beyond the conventional paradigms of Landau-Ginzburg phenomenology. Here, we consider a parametrically driven two-mode system in the presence of non-Markovian system-reservoir interactions. We show that non-Markovianity modifies the phase diagram of this system resulting in the em…
From information theory and thermodynamic considerations a universal bound on the relaxation time $τ$ of a perturbed system is inferred, $τ\geq \hbar/πT$, where $T$ is the system's temperature. We prove that black holes comply with the bound; in fact they actually {\it saturate} it. Thus, when judged by their relaxation properties, black holes are the most extreme objects in nature, having the maximum relaxation rate which is allowed by quantum theory.
