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arXiv 2404.02012cond-mat.mtrl-sciphysics.chem-ph
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通过磁化率测量确定抗磁性混合固体的化学成分

Determining the chemical composition of diamagnetic mixed solids via measurements of the magnetic susceptibility

Miao Miao Zhao, Yang Yang, Na Du, Yu Ying Zhu, Peng Ren, Fei Yen

AI总结:

本文提出通过测量粉末状抗磁性混合固体的质量磁化强度,利用摩尔磁化率与摩尔质量的加和性质同时求解掺杂浓度δ和摩尔磁化率,并以八个实例验证了该方法在约1.2%误差下的广泛适用性。

摘要:

混合固体化合物被广泛应用于众多领域,因此准确测定其化学成分至关重要。目前所有的表征方法都需要经过特殊处理的样品,因此若能提供一种具有相似精度且更实用的方法,将有助于简化定量过程。在本工作中,我们展示了如何通过测量质量磁化强度来获得粉末状混合固体化合物的掺杂浓度δ(或同位素浓度),其中两种母体化合物均为抗磁性物质。我们利用摩尔磁化率χ_Mol与摩尔质量的加和性质,在χ_Mol对δ的空间中构造两个含有相同两个未知量的方程,从而同时求解混合固体的χ_Mol和δ。文中给出了八个例子以展示该方法的广泛适用性:NH₄₍₁₋δ₎D₄δBr(其中D = ²H)、NH₄I₁₋δBrδ、(NH₄H₂)₁₋δ(ND₄D₂)δPO₄、C₄₈H₂₂₊₆δBr₆₍₁₋δ₎O₃₂Zr₆、[肌酸]₁₋δ[_D-葡萄糖]δ、[_L-谷氨酸]₁₋δ[_L-亮氨酸]δ、[对苯二甲酸]₁₋δ[均苯三甲酸]δ和[对三联苯]₁₋δ[三苯基膦]δ。对于平均质量为16.6 mg的粉末样品,δ的实验误差约为1.2%,这使得所提出的方法成为表征混合固体比例的一种有吸引力的选择。

英文摘要:

Mixed solid compounds are employed in a vast array of applications so an accurate determination of their chemical compositions is of crucial importance. All current characterization methods require specially-treated samples so the availability of a more practical method with similar accuracy should alleviate the quantification process. In this work, we show how the doping concentration $δ$ (or isotope concentration) of a mixed solid compound in powdered form, where both parent compounds are diamagnetic, can be obtained from the measurement of the mass magnetization. We exploit the additive nature of the molar magnetic susceptibility $χ_{Mol}$ and molar mass to construct two equations with the same two unknowns in the $χ_{Mol}$ vs. $δ$ space to simultaneously solve $χ_{Mol}$ and $δ$ of a mixed solid. Eight examples are provided to show the wide applicability of this method: NH$_{4(1-δ)}$D$_{4δ}$Br (where D = $^2$H), NH$_4$I$_{1-δ}$Br$_δ$, (NH$_4$H$_2$)$_{1-δ}$(ND$_4$D$_2$)$_δ$PO$_4$, C$_{48}$H$_{22+6δ}$Br$_{6(1-δ)}$O$_{32}$Zr$_6$, [creatine]$_{1-δ}$[$_D$-glucose]$_δ$, [$_L$-glutamic acid]$_{1-δ}$[$_L$-leucine]$_δ$, [terephthalic acid]$_{1-δ}$[trimesic acid]$_δ$ and [p-terphenyl]$_{1-δ}$[triphenylphosphine]$_δ$. Experimental errors of ~1.2% were obtained for $δ$ from average sample masses of 16.6 mg in powdered form rendering the presented approach an attractive choice for characterizing the ratios of mixed solids.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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