Exhaustive study of topological semimetal phases of matter in equilibriated electonic systems and myriad extensions has built upon the foundations laid by earlier introduction and study of the Weyl semimetal, with broad applications in topologically-protected quantum computing, spintronics, and optical devices. We extend recent introduction of multiplicative topological phases to find previously-overlooked topological semimetal phases of electronic systems in equilibrium, with minimal symmetry-protection. We show these multiplicative topological semimetal phases exhibit rich and distinctive bulk-boundary correspondence and response signatures that greatly expand understanding of consequences of topology in condensed matter settings, such as the limits on Fermi arc connectivity and structure, and transport signatures such as the chiral anomaly. Our work therefore lays the foundation for extensive future study of multiplicative topological semimetal phases.
Topological semimetals: surface transport and spin effects
Institute of Solid State Physics of the Russian Academy of Sciences（俄罗斯科学院固体物理研究所）；V.L. Ginzburg Research Centre for High-Temperature Superconductivity and Quantum Materials, P.N. Lebedev Physical Institute of RAS（俄罗斯科学院列别杰夫物理研究所V.L.金兹堡高温超导与量子材料研究中心）
We discuss the possibility of realizing Weyl semimetal phase in the magnetically doped topological band insulators. When the magnetic moments are ferromagnetically polarized, we show that there are three phases in the system upon the competition between topological mass and magnetic mass: topological band insulator phase, Weyl semimetal phase, and trivial phase. We explicitly derive the low energy theory of Weyl points from the general continuum Hamiltonian of topological insulators near the Dirac point, e.g. ${\bf k} \cdot {\bf p}$ theory near $Γ$ point for Bi_{2}Se_{3}. Furthermore, we intro…
Dirac semimetals host bulk band-touching Dirac points and a surface Fermi loop. We develop a theory of superconducting Dirac semimetals. Establishing a relation between the Dirac points and the surface Fermi loop, we clarify how the nontrivial topology of Dirac semimetals affects their superconducting state. We note that the unique orbital texture of Dirac points and a structural phase transition of the crystal favor symmetry-protected topological superconductivity with a quartet of surface Majorana fermions. We suggest possible application of our theory to recently discovered superconducting …
We find that the vortex bound states in superconducting topological semimetals are gapless owing to topological massless excitations in their normal states. We demonstrate this universal result in a variety of semimetals including Dirac and Weyl semimetals, threefold degenerate spin-1 fermions, spin-3/2 Rarita-Schwinger-Weyl fermion semimetals and other exotic fermion semimetals. The formation of these gapless bound states are closely related to their Andreev specular reflection and propagating Andreev modes in $π$ phase superconductor-normal metal-superconductor (SNS) junctions. We further de…
We study the stability of gap-closing (Weyl or Dirac) points in the three-dimensional Brillouin zone of semimetals using Clifford algebras and their representation theory. We show that a pair of Weyl points with $\mathbb{Z}_2$ topological charge are stable in a semimetal with time-reversal and reflection symmetries when the square of the product of the two symmetry transformations equals minus identity. We present toy models of $\mathbb{Z}_2$ Weyl semimetals which have surface modes forming helical Fermi arcs. We also show that Dirac points with $\mathbb{Z}_2$ topological charge are stable in …
This chapter describes topological (Dirac and Weyl) semimetals from the viewpoint of their observable electromagnetic response. We argue that this response may be represented by topological terms with unquantized (non-integer) coefficients and make a connection with the Luttinger's theorem, which relates the size of the Fermi surface of an ordinary metal to the number of electrons per unit cell. We discuss observable transport phenomena, associated with this topological response.
Dirac semimetal is a class of semi-metallic phase protected by certain types of crystalline symmetries, and its low-energy effective Hamiltonian is described by Dirac equations in three dimensions (3D). Despite of various theoretical studies, theories that describe the topological nature of Dirac semimetals have not been well established. In this work, we define a topological invariant for 3D Dirac semimetals by establishing a mapping between a 3D Dirac semimetal and a topological crystalline insulator in four dimension (4D). We demonstrate this scheme by constructing a tight-binding model for…
Topological semimetals are a new class of metallic materials, which exist at band fillings that ordinarily correspond to insulators or compensated accidental semimetals with zero Luttinger volume. Their metallicity is a result of nontrivial topology in momentum space and crystal symmetry, wherein topological charges may be assigned to point band-touching nodes, preventing gap opening, unless protecting crystal symmetries are violated. These topological charges, however, are defined from noninteracting band eigenstates, which raises the possibility that the physics of topological semimetals may…
Recent experimental breakthrough in magnetic Weyl semimetals have inspired exploration on the novel effects of various magnetic structures in these materials. Here we focus on a domain wall structure which connects two uniform domains with different magnetization directions. We study the topological superconducting state in presence of an s-wave superconducting pairing potential. By tuning the chemical potential, we can reach a topological state, where a chiral Majorana mode or zero-energy Majorana bound state is localized at the edges of the domain walls. This property allows a convenient bra…
We study dynamical mass generation and the resultant helical spin orders in topological Dirac and Weyl semimetals, including the edge states of quantum spin Hall insulators, the surface states of weak topological insulators, and the bulk materials of Weyl semimetals. In particular, the helical spin textures of Weyl semimetals manifest the spin-momentum locking of Weyl fermions in a visible manner. The spin-wave fluctuations of the helical order carry electric charge density; therefore, the spin textures can be electrically controlled in a simple and predictable manner.
Electronic structures of Ge$_{1-x}$Sn$_{x}$ alloys (0 $\leq$ $x$ $\leq$ 1) are theoretically studied by nonlocal empirical pseudopotential method. For relaxed Ge$_{1-x}$Sn$_{x}$, a topological semimetal is found for $\textit x$ $>$ 41$\%$ with gapless and band inversion at $Γ$ point, while there is an indirect-direct bandgap transition at $x$ = 8.5$\%$. For strained Ge$_{1-x}$Sn$_{x}$ on a Ge substrate, semimetals with a negative indirect bandgap appear for $x$ $>$ 43$\%$, and the strained Ge$_{1-x}$Sn$_{x}$ on Ge is always an indirect bandgap semiconductor for $x$ $<$ 43$\%$. With appropriate…
Topological phases can not only be protected by internal symmetries (e.g., time-reversal symmetry), but also by crystalline symmetries, such as reflection or rotation symmetry. Recently a complete topological classification of reflection symmetric insulators, superconductors, nodal semimetals, and nodal superconductors has been established. In this article, after a brief review of the classification of reflection-symmetry-protected semimetals and nodal superconductors, we discuss an example of a three-dimensional topological Dirac semimetal, which exhibits time-reversal symmetry as well as ref…
Topological semimetals, such as Dirac, Weyl, or line-node semimetals, are gapless states of matter characterized by their nodal band structures and surface states. In this work, we consider layered (topologically trivial) insulating systems in $D$ dimensions that are composed of coupled multi-layers of $d$-dimensional topological semimetals. Despite being nominal bulk insulators, we show that crystal defects having co-dimension $(D-d)$ can harbor robust lower dimensional topological semimetals embedded in a trivial insulating background. As an example we show that defect-bound topological semi…
Floquet engineering, the concept of tailoring a system by a periodic drive, is increasingly exploited to design and manipulate topological phases of matter. In this work, we study periodically driven higher-order topological Dirac semimetals associated with a $k$-dependent quantized quadrupole moment by applying circularly polarized light. The undriven Dirac semimetals feature gapless higher-order hinge Fermi arc states which are the consequence of the higher-order topology of the Dirac nodes. Floquet Weyl semimetal phases with hybrid-order topology, characterized by both a $k$-dependent quant…
In this work, we propose a ferromagnetic Bi$_2$Se$_3$ as a candidate to hold the coexistence of Weyl- and nodal-line semimetal phases, which breaks the time reversal symmetry. We demonstrate that the type-I Weyl semimetal phase, type-I-, type-II- and their hybrid nodal-line semimetal phases can arise by tuning the Zeeman exchange field strength and the Fermi velocity. Their topological responses under U(1) gauge field are also discussed. Our results raise a new way for realizing Weyl and nodal-line semimetals and will be helpful in understanding the topological transport phenomena in three-dim…
Topological Weyl semimetals (TWS) can be classified as type-I TWS, in which the density of states vanishes at the Weyl nodes, and type-II TWS where an electron and a hole pocket meet with finite density of states at the nodal energy. The dispersions of type-II Weyl nodes are tilted and break Lorentz invariance, allowing for physical properties distinct from those in a type-I TWS. We present minimal lattice models for both time-reversal-breaking and inversion-breaking type-II Weyl semimetals, and investigate their bulk properties and topological surface states. These lattice models capture the …
We propose topological semimetals generated by the square-root operation for tight-binding models in two and three dimensions, which we call square-root topological semimetals. The square-root topological semimetals host topological band touching at finite energies, whose topological protection is inherited from the squared Hamiltonian. Such a topological character is also reflected in emergence of boundary modes with finite energies. Specifically, focusing on topological properties of squared Hamiltonian in class AIII, we reveal that a decorated honeycomb (decorated diamond) model hosts finit…
While the topological classification of insulators, semimetals, and superconductors in terms of nonspatial symmetries is well understood, less is known about topological states protected by crystalline symmetries, such as mirror reflections and rotations. In this work, we systematically classify topological semimetals and nodal superconductors that are protected, not only by nonspatial (i.e., global) symmetries, but also by a crystal reflection symmetry. We find that the classification crucially depends on (i) the codimension of the Fermi surface (nodal line or point) of the semimetal (superco…
We theoretically study the electric polarization in magnetic topological nodal semimetal thin films. In magnetically doped topological insulators, topological nodal semimetal phases emerge once the exchange coupling overcomes the band gap. Changing the magnetization direction, nodal structure is modulated and the system becomes topological nodal point or line semimetals. We find that nodal line semimetals are characterized by non-linear electric polarization, which is not observed in nodal point semimetals. The non-linear response originates from the existence of the surface states. Screening …
Chiral topological semimetals host multifold degenerate band crossing points under the protection of crystalline symmetries. In this paper, we suggest that the recently discovered chiral topological semimetals in space group 198, parts of which are superconducting upon doping, can be new candidates of time reversal invariant topological superconductors. By investigating the Fermi surfaces around the band crossing points that carry nonzero Chern numbers, we clarify how the nontrivial topology of chiral topological semimetals affects their superconducting state and show the existence of topologi…
We propose the creation of a two-dimensional topological semimetal in a semiconductor artificial lattice with triangular symmetry. An in-plane magnetic field drives a quantum phase transition between the topological insulating and topological semimetal phases. The topological semimetal is characterized by robust band touching points which carry quantized Berry flux and edge states which terminate at the band touching points. The topological phase transition is predicted to occur at magnetic fields $\sim 4\text{T}$ in high mobility GaAs artificial lattices, and can be detected via the anomalous…
Topological semimetals and metals have emerged as a new frontier in the field of quantum materials. Novel macroscopic quantum phenomena they exhibit are not only of fundamental interest, but may hold some potential for technological applications.
We review recent theoretical progress in the understanding and prediction of novel topological semimetals. Topological semimetals define a class of gapless electronic phases exhibiting topologically stable crossings of energy bands. Different types of topological semimetals can be distinguished based on the degeneracy of the band crossings, their codimension (e.g., point or line nodes), as well as the crystal space group symmetries on which the protection of stable band crossings relies. The dispersion near the band crossing is a further discriminating characteristic. These properties give ris…
We study the conductance fluctuation in topological semimetals. Through statistic distribution of energy levels of topological semimetals, we determine the dominant parameters of universal conductance fluctuation (UCF), i.e., the number of uncorrelated bands $k$, the level degeneracy $s$, and the symmetry parameter $β$. These parameters allow us to predict the zero-temperature intrinsic UCF of topological semimetals by the Altshuler-Lee-Stone theory. Then, we obtain numerically the conductance fluctuations for topological semimetals of quasi-1D geometry. We find that for Dirac/Weyl semimetals,…
By first-principles calculations, we find that Ba2X(X=Si, Ge) hosts a topological semimetal phase with one nodal ring in the kx=0 plane, which is protected by the glide mirror symmetry when spin-orbit coupling (SOC) is ignored. The corresponding drumheadlike surface flat band appears on the (100) surface in surface Green function calculation. Furthermore, a topological-semimetal-to-insulator transition (TSMIT) is found. The nodal line semimetal would evolve into topological insulator as SOC is turned on. The topologically protected metallic surface states emerge around the Gamma=0 point, which…
In this work we predict several new types of topological semimetals that exhibit a bulk quadrupole moment. These semimetals are modeled with a 3D extension of the 2D quadrupole topological insulator. One type of semimetal has bulk nodes and gapped, topological surfaces. A second type, which we may call a higher order topological semimetal, has a gapped bulk, but harbors a Dirac semimetal with an even number of nodes on one or more surfaces. The final type has a gapped bulk, but harbors half of a Dirac semimetal on multiple surfaces. Each of these semimetals gives rise to mid-gap hinge states a…
We propose a different route to time-reversal invariant Weyl semimetals employing multilayer heterostructures comprising ordinary "trivial" insulators and nontrivial insulators with \textit{pairs} of protected Dirac cones on the surface. We consider both the case of weak topological insualtors, where surface Dirac cones are pinned to time-reversal invariant momenta, and of topological crystalline insulators with unpinned surface Dirac cones. For both realizations we explain phenomenologically how the proposed construction leads to the emergence of a Weyl semimetal phase. We further formulate e…
The electronic bands are classified according to their topology. We compute the connection and curvature for the electronic bands and show that the physical properties are determined by topological invariants which are equivalent to the existence of the zero modes. We apply this method to the Topological Insulators and Topogical Superconductors.
We study a general phase transition between spinless topological nodal-line semimetal and Weyl semimetal phases. We classify topological nodal lines into two types based on their positions and shapes, and their phase transitions depends on their types. We show that the topological nodal-line semimetal becomes the Weyl semimetal by breaking time-reversal symmetry when the nodal lines enclose time-reversal invariant momenta (type-A nodal lines). We also discuss an effect of crystallographic symmetries determining the band structure of the topological nodal-line semimetals. Thanks to protection b…
Three-dimensional (3D) topological semimetals represent a new class of topological matters. The study of this family of materials has been at the frontiers of condensed matter physics, and many breakthroughs have been made. Several topological semimetal phases, including Dirac semimetals (DSMs), Weyl semimetals (WSMs), nodal-line semimetals (NLSMs), and triple-point semimetals, have been theoretically predicted and experimentally demonstrated. The low-energy excitation around the Dirac/Weyl nodal points, nodal line, or triply degenerated nodal point can be viewed as emergent relativistic fermi…
In this Book Chapter (invited) we briefly review the basic concepts defining topological insulators and focus on elaborating on the key experimental results that revealed and established their symmetry protected (SPT) topological nature. We then present key experimental results that demonstrate magnetism, Kondo insulation, mirror chirality or topological crystalline order and superconductivity in spin-orbit topological insulator settings and how these new (bulk insulating) phases of matter arise through topological quantum phase transitions from Bloch band insulators via topological or Dirac s…
We review the recent, mainly theoretical, progress in the study of topological nodal line semimetals in three dimensions. In these semimetals, the conduction and the valence bands cross each other along a one-dimensional curve in the three-dimensional Brillouin zone, and any perturbation that preserves a certain symmetry group (generated by either spatial symmetries or time-reversal symmetry) cannot remove this crossing line and open a full direct gap between the two bands. The nodal line(s) is hence topologically protected by the symmetry group, and can be associated with a topological invari…
$α$-Sn is well known as a typical Luttinger semimetal with a quadratic band touching at the $Γ$ point. Based on the effective $k\cdot p$ analysis as well as first-principles calculations, we demonstrate that multiple topological phases with a rich diagram, including topological insulator, Dirac semimetal, and Weyl semimetal phases, can be induced and engineered in $α$-Sn by external strains, magnetic fields, and circularly polarized light (CPL). Intriguingly, not only the conventional type-I Weyl nodes, but also type-II Weyl nodes and double-Weyl nodes can be generated directly from the quadra…
Characterized by bulk Dirac or Weyl cones and surface Fermi-arc states, topological semimetals have sparked enormous research interest in recent years. The nanostructures, with large surface-to-volume ratio and easy field-effect gating, provide ideal platforms to detect and manipulate the topological quantum states. Exotic physical properties originating from these topological states endow topological semimetals attractive for future topological electronics (topotronics). For example, the linear energy dispersion relation is promising for broadband infrared photodetectors, the spin-momentum lo…
The recently discovered topological Dirac semimetal represents a new exotic quantum state of matter. Topological Dirac semimetals can be viewed as three dimensional analogues of graphene, in which the Dirac nodes are protected by crystalline symmetry. It has been found that quantum confinement effect can gap out Dirac nodes and convert Dirac semimetal to a band insulator. The band insulator is either normal insulator or quantum spin Hall insulator depending on the thin film thickness. We present the study of disorder effects in thin film of Dirac semimetals. It is found that moderate Anderson …
We theoretically show that IV-VI semiconducting compounds with low-temperature rhombohedral crystal structure represent a new potential platform for topological semimetals. By means of minimal $\mathbf{k}\cdot\mathbf{p}$ models we find that the two-step structural symmetry reduction of the high-temperature rocksalt crystal structure, comprising a rhombohedral distortion along the [111] direction followed by a relative shift of the cation and anion sublattices, gives rise to topologically protected Weyl semimetal and nodal line semimetal phases. We derive general expressions for the nodal featu…
The notion of topological phases has been extended to higher-order and has been generalized to different dimensions. As a paradigm, Cd3As2 is predicted to be a higher-order topological semimetal, possessing three-dimensional (3D) bulk Dirac fermions, two-dimensional (2D) Fermi arcs, and one-dimensional (1D) hinge states. These topological states have different characteristic length scales in electronic transport, allowing to distinguish their properties when changing sample size. Here, we report an anomalous dimensional reduction of supercurrent transport by increasing the size of Dirac semime…
A topological flatband, also known as drumhead states, is an ideal platform to drive new exotic topological quantum phases. Using angle-resolved photoemission spectroscopy experiments, we reveal the emergence of a highly localized possible drumhead surface state in a topological semimetal BaAl4 and provide its full energy and momentum space topology. We find that the observed surface state is highly localized in momentum, inside a square-shaped bulk Dirac nodal loop, and in energy, leading to a flat band and a peak in the density of state. These results establish this class of materials as a p…
The notion of higher-order topological insulators has endowed materials with topological states beyond the first order. Particularly, a three-dimensional (3D) higher-order topological insulator can host topologically protected 1D hinge states, referred to as the second-order topological insulator, or 0D corner states, referred to as the third-order topological insulator. Similarly, a 3D higher-order topological semimetal can be envisaged if it hosts states on the 1D hinges. Here we report the realization of a second-order topological Weyl semimetal in a 3D-printed acoustic crystal, which posse…
We propose an unconventional type of Hall effect in a topological Dirac semimetal with ferromagnetic electrodes. The topological Dirac semimetal itself has time-reversal symmetry, whereas attached ferromagnetic electrodes break it, causing the large Hall response. This induced Hall effect is a characteristic of the helical surface/edge states that arise in topological materials, such as topological Dirac semimetals or quantum spin Hall insulators. We compute the Hall conductance/resistance and the Hall angle by using a lattice model with four-terminal geometry. For topological Dirac semimetals…
We study two Weyl semimetal generalizations in five dimensions (5d) which have Yang monopoles and linked Weyl surfaces in the Brillouin zone, respectively, and carry the second Chern number as a topological number. In particular, we show a Yang monopole naturally reduces to a Hopf link of two Weyl surfaces when the $\mathbf{TP}$ (time-reversal combined with space-inversion) symmetry is broken. We then examine the phase transition between insulators with different topological numbers in 5d. In analogy to the 3d case, 5d Weyl semimetals emerge as intermediate phases during the topological phase …
Classification of topological insulators and superconductors is manifested in terms of spin cobordism groups for lower dimensions. It is discussed that the periodic table of topological insulators is a result of the possible choices of spin structures on Brillouin zones of relevant topological materials. This framework is extended to the case of Weyl semimetals. It is shown that the classification of Weyl semimetals can be managed in terms of spin$^c$ cobordism groups via the extension of spin structures to spin$^c$ structures. Topological invariants of Weyl semimetals are connected to the top…
We develop a topological theory for disordered Weyl semimetals in the framework of gauge invariance of replica formalism and boundary-bulk correspondence of Chern insulators. An anisotropic topological $θ$-term is analytically derived for the effective non-linear sigma model. It is this nontrivial topological term that ensures the bulk transverse transport of Weyl semimetals to be robust against disorders. Moreover, we establish a general diagram that reveals the intrinsic relations among topological terms in the non-linear sigma models and gauge response theories respectively for $(2n + 2)$-d…
For first-order topological semimetals, non-Hermitian perturbations can drive the Weyl nodes into Weyl exceptional rings having multiple topological structures and no Hermitian counterparts. Recently, it was discovered that higher-order Weyl semimetals, as a novel class of higher-order topological phases, can uniquely exhibit coexisting surface and hinge Fermi arcs. However, non-Hermitian higher-order topological semimetals have not yet been explored. Here, we identify a new type of topological semimetals, i.e, a higher-order topological semimetal with Weyl exceptional rings. In such a semimet…
We demonstrate that topological transport phenomena, characteristic of Weyl semimetals, namely the semi-quantized anomalous Hall effect and the chiral magnetic effect (equilibrium magnetic-field-driven current), may be thought of as two distinct manifestations of the same underlying phenomenon, the chiral anomaly. We show that the topological response in Weyl semimetals is fully described by a $θ$-term in the action for the electromagnetic field, where $θ$ is not a constant parameter, like e.g. in topological insulators, but is a field, which has a linear dependence on the space-time coordinat…
The Fermi arcs of topological surface states in the three-dimensional multi-Weyl semimetals on surfaces by a continuum model are investigated systematically. We calculated analytically the energy spectra and wave function for bulk quadratic- and cubic-Weyl semimetal with a single Weyl point. The Fermi arcs of topological surface states in Weyl semimetals with single- and double-pair Weyl points are investigated systematically. The evolution of the Fermi arcs of surface states variating with the boundary parameter is investigated and the topological Lifshitz phase transition of the Fermi arc co…
A three-dimensional (3D) nodal-loop semimetal phase is exploited to engineer a number of intriguing phases featuring different peculiar topological surface states. In particular, by introducing various two-dimensional gap terms to a 3D tight-binding model of a nodal-loop semimetal, we obtain a rich variety of topological phases of great interest to ongoing theoretical and experimental studies, including chiral insulator, degenerate-surface-loop insulator, second-order topological insulator, as well as Weyl semimetal with tunable Fermi arc profiles. The unique concept underlying our approach is…
Searching for the signature of the violation of chiral charge conservation in solids has inspired a growing passion on the magneto-transport in topological semimetals. One of the open questions is how the conductivity depends on magnetic fields in a semimetal phase when the Fermi energy crosses the Weyl nodes. Here, we study both the longitudinal and transverse magnetoconductivity of a topological Weyl semimetal near the Weyl nodes with the help of a two-node model that includes all the topological semimetal properties. In the semimetal phase, the Fermi energy crosses only the 0th Landau bands…
We study a topological phase diagram of a ferromagnetic topological nodal semimetal. We consider a lattice model for three-dimensional topological insulators with ferromagnetic ordering. The exchange coupling between the magnetization and the electron spin leads to the nodal band structure. The topology of the nodal band structure depends on the direction of the magnetization and both the Weyl points and the nodal line emerge. We find that the nodal line structure is stable under an easy-plane magnetization in appropriate model parameters. In this case, the nodal line phase emerges as a phase …
The concepts of Weyl fermions and topological semimetals emerging in three-dimensional momentum space are extensively explored owing to the vast variety of exotic properties that they give rise to. On the other hand, very little is known about semimetallic states emerging in two-dimensional magnetic materials, which present the foundation for both present and future information technology. Here, we demonstrate that including the magnetization direction into the topological analysis allows for a natural classification of topological semimetallic states that manifest in two-dimensional ferromagn…
We investigate the chiral electronic modes at the interface between two regions of a threefold topological semimetal, which is illuminated by left and right handed elliptically polarized waves. The radiation effects on the band structure of semimetal is analyzed by using Floquet theory. Two distinct solutions of the interface modes are found with the chirality depending on the phase of the irradiation. We also consider the anomalous Hall response which is attributed to the transition between dispersionless flat band and conic bands.
We study the time-development processes of spin and charge transport phenomena in a topological Dirac semimetal attached to a ferromagnetic insulator with a precessing magnetization. Compared to conventional normal metals, topological Dirac semimetals manifest a large inverse spin Hall effect when a spin current is pumped from the attached ferromagnetic insulator. It is shown that the induced charge current is semi-quantized, i.e., it depends only on the distance between the two Dirac points in momentum space and hardly depends on the disorder strength when the system remains in the topologica…
