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arXiv 2211.09255physics.flu-dyn

任意形状轴对称通道中的Taylor扩散

Taylor dispersion in arbitrarily shaped axisymmetric channels

Ray Chang, Juan G. Santiago

AI总结:

研究分析了任意形状轴对称通道中的Taylor-Aris扩散,推导出两个耦合常微分方程预测溶质区域演化,并通过模拟验证,提出通道几何设计方法以实现特定溶质宽度分布。

摘要:

溶质在细长轴对称通道中的平流扩散对于包括化学分离系统和微流控芯片在内的多种设备的分析与设计至关重要。尽管对各种场景下的Taylor扩散进行了广泛分析,但大多数研究集中于长期扩散行为,无法捕捉溶质区域在通道空间变化中的瞬态演化。在本研究中,我们分析了任意形状轴对称通道的Taylor-Aris扩散。我们推导出了一个由两个耦合常微分方程(ODEs)表示的溶质动力学表达式。这两个ODEs允许预测溶质区域的平均位置和轴向(标准差)宽度随时间的演化,作为通道几何形状的函数。我们将预测结果与布朗动力学模拟进行了比较和基准测试,涵盖了包括线性扩张/收缩通道和周期性通道在内的多种情况。我们还对溶质宽度的瞬态正向与负向轴向增长的物理区域进行了分析描述。最后,为了进一步展示该分析的实用性,我们展示了一种设计通道几何形状的方法,以实现所需的溶质宽度在空间和时间上的分布。我们将后一种分析应用于生成一种产生恒定轴向宽度的几何形状,以及第二种在空间中产生正弦轴向方差的几何形状。

英文摘要:

Advective dispersion of solutes in long thin axisymmetric channels is important to the analysis and design of a wide range of devices, including chemical separation systems and microfluidic chips. Despite extensive analysis of Taylor dispersion in various scenarios, most studies focused on long-term dispersion behavior and cannot capture the transient evolution of solute zone across the spatial variations in the channel. In the current study, we analyze the Taylor-Aris dispersion for arbitrarily shaped axisymmetric channels. We derive an expression for solute dynamics in terms of two coupled ordinary differential equations (ODEs). These two ODEs allow prediction of the time evolution of the mean location and axial (standard deviation) width of the solute zone as a function of the channel geometry. We compare and benchmark our predictions with Brownian dynamics simulations for a variety of cases including linearly expanding/converging channels and periodic channels. We also present an analytical description of the physical regimes of transient positive versus negative axial growth of solute width. Finally, to further demonstrate the utility of the analysis, we demonstrate a method to engineer channel geometries to achieve desired solute width distributions over space and time. We apply the latter analysis to generate a geometry that results in a constant axial width and a second geometry that results in a sinusoidal axial variance in space.

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