The gas giant HD 80606 b has a highly eccentric orbit (e $\sim$ 0.93). The variation due to the rapid shift of stellar irradiation provides a unique opportunity to probe the physical and chemical timescales and to study the interplay between climate dynamics and atmospheric chemistry. In this work, we present integrated models to study the atmospheric responses and the underlying physical and chemical mechanisms of HD 80606 b. We first run three-dimensional general circulation models (GCMs) to establish the atmospheric thermal and dynamical structures for different atmospheric metallicities and internal heat. Based on the GCM output, we then adopted a 1D time-dependent photochemical model to investigate the compositional variation along the eccentric orbit. The transition of the circulation patterns of HD 80606 b matched the dynamics regimes in previous works. Our photochemical models show that efficient vertical mixing leads to deep quench levels of the major carbon and nitrogen species and the quenching behavior does not change throughout the eccentric orbit. Instead, photolysis is the main driver of the time-dependent chemistry. While CH$_4$ dominates over CO through most of the orbits, a transient state of [CO]/[CH$_4$}] $>$ 1 after periastron is confirmed for all metallicity and internal heat cases. The upcoming JWST Cycle 1 GO program will be able to track this real-time CH$_4$--CO conversion and infer the chemical timescale. Furthermore, sulfur species initiated by sudden heating and photochemical forcing exhibit both short-term and long-term cycles, opening an interesting avenue for detecting sulfur on exoplanets.
The space and ground-based observations have shown a lot of activities and instabilities in the atmosphere of the giant ice planet Neptune. Using the archival data of high resolution Atacama Large Millimeter/Submillimeter Array (ALMA) with band 7 observation, we present the spectroscopic detection of the rotational emission line of sulfur dioxide (SO$_{2}$) at frequency $ν$ = 343.476 GHz with transition J=57$_{15,43}$$-$58$_{14,44}$. We also re-detect the emission line of carbon monoxide (CO) at frequency $ν$ = 345.795 GHz with transition J=3$-$2. The molecular lines of SO$_{2}$ and CO in the …
The extremely thin atmosphere of Jupiter's volcanic moon Io primarily consists of sulfur (S), sodium (Na), and oxygen (O) molecules that are controlled by the combination of the sublimation and volcanic outgasses. We present the first spectroscopic detection of the two rotational emission lines of acetone (CH$_{3}$COCH$_{3}$) and a single emission line of disulfur monoxide (S$_{2}$O), and carbon monoxide (CO) at frequency $ν$ = 346.539, 346.667, 346.543, and 345.795 GHz respectively using the archival data of high-resolution Atacama Large Millimeter/Submillimeter Array (ALMA) interferometer wi…
Sulfur-bearing molecules play an important role in prebiotic chemistry and planet habitability. They are also proposed probes of chemical ages, elemental C/O ratio, and grain chemistry processing. Commonly detected in diverse astrophysical objects, including the Solar System, their distribution and chemistry remain, however, largely unknown in planet-forming disks. We present CS ($2-1$) observations at $\sim0."3$ resolution performed within the ALMA-MAPS Large Program toward the five disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. CS is detected in all five disks, displaying a var…
The Role of Formation Location in Shaping Sulfur-, Nitrogen-, and Carbon-Bearing Species in Super-Earth and Sub-Neptune Atmospheres
Institute for Particle Physics and Astrophysics, ETH Zurich（苏黎世联邦理工学院粒子物理与天体物理研究所）；Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles（加州大学洛杉矶分校地球、行星与空间科学系）；Observatoire de la Côte d’Azur, Université Cote d’Azur, Laboratoire Lagrange（蔚蓝海岸天文台，尼斯大学，拉格朗日实验室）；Department of Space Research and Technology, Technical University of Denmark（丹麦技术大学太空研究与技术系）
The Isotopic and Elemental Abundances of Planet-Host Star TRAPPIST-1
Leiden Observatory, Leiden University（莱顿天文台，莱顿大学）；Department of Physics and Astronomy, University of Kansas（堪萨斯大学物理与天文学系）；Department of Physics and Astronomy, University of New Mexico（新墨西哥大学物理与天文学系）；Space Telescope Science Institute（太空望远镜科学研究所）；Department of Earth Sciences, University of Hawai’i at Mānoa（夏威夷大学马诺阿分校地球科学系）；INAF-Osservatorio di Astrofisica e Scienza dello Spazio（意大利国家天体物理研究所空间科学与天体物理观测台）
JWST Exoplanetary Worlds and Elemental Survey (JEWELS) II: Condensation Temperature Trends and Galactic Chemical Evolution in JWST Planet-Hosting Stars
Tsung-Dao Lee Institute, School of Physics and Astronomy, & State Key Laboratory of Dark Matter Physics, Shanghai Jiao Tong University（上海交通大学物理与天文学院、汤川研究所、暗物质物理国家重点实验室）；Department of Physics, King’s College London（伦敦国王学院物理系）；Department of Astronomy, Tsinghua University（清华大学天文系）；National Astronomical Observatories, Chinese Academy of Sciences（中国科学院国家天文台）
Unveiling the Chemical Complexity and C/O Ratio of the HD 163296 Protoplanetary Disk: Constraints from Multi-line ALMA Observations of Organics, Nitriles, Sulfur-bearing, and Deuterated Molecules
The atmospheric C/O ratio of exoplanets is widely used to constrain their formation. To guarantee that the C/O ratio provides robust information, we need to accurately quantify the amount of C and O in exoplanetary atmospheres. In the case of O, water and carbon monoxide are generally studied as the two key carriers. However, oxygen is a very reactive element and does not bind with carbon; depending on the temperature, it also binds to refractory elements. Estimating the amount of oxygen bound to refractory elements is therefore critical for unbiased estimates of the C/O ratio. In this work, w…
We investigate the dependence of elemental abundances on physical constants, and the implications this has for the distribution of complex life for various proposed habitability criteria. We consider three main sources of abundance variation: differing supernova rates, alpha burning in massive stars, and isotopic stability, and how each affects the metal-to-rock ratio and the abundances of carbon, oxygen, nitrogen, phosphorus, sulfur, silicon, magnesium, and iron. Our analysis leads to several predictions for which habitability criteria are correct by determining which ones make our observatio…
