Using the QUIJOTE line survey in the 32.0-50.4 GHz range, we report the discovery of the molecule CH2CCHC4H towards the prestellar cold core TMC-1 in the Taurus region. We also present a rigorous detection of CH2CCHC3N, along with its detailed analysis. We identified a total of twenty rotational transitions for each one of these molecules. The rotational quantum numbers range from Ju=17 up to 24 and Ka<=3. The column density for CH2CCHC4H is N=(2.2+/-0.2)x 1E12 cm-2, while for CH2CCHC3N, we derived N=(1.2+/-0.15) x 1E11 cm-2. The rotational temperature is 9.0+/-0.5 K for both species. The abundance ratio between CH2CCHC4H and CH2CCHC3N is 18+/-4. We also compared the column densities of these species with those of their isomers CH3C6H and CH3C5N, derived from their J=20-19 up to J=30-29 rotational transitions observed with the QUIJOTE line survey. The observed abundances for all these species are reasonably well explained by state-of-the-art chemical models of TMC-1. The observed astronomical frequencies were merged with laboratory frequencies from the literature to derive improved spectroscopic parameters.
Discovery of fulvenallene in TMC-1 with the QUIJOTE line survey
我们报告了利用QUIJOTE线调查在TMC-1方向检测到富烯丙二烯($c$ -C $_5$ H $_4$ CCH $_2$)。共检测到30个旋转跃迁,跃迁频率分别为$K_a$ = 0,1,2,3和$J$ =9-15。数据的最佳旋转温度拟合值为9 ° K,导出的柱密度为(2.7 $\pm$ 0.3)$\times$ 10 $^{12}$ cm $^{-2}$,仅比其潜在的前体环戊二烯($c$-C $_5$ H $_6$)低4.4倍,比环戊二烯的乙炔基衍生物高1.4--1.9倍.我们寻找富烯($c$-C $_5$ H $_4$ CH $_2$),一种环戊二烯的CH $_2$衍生物,我们推导出其柱密度的3 $σ$上限为(3.5 $\pm$ 0.5)$\times$ 10 $^{12}$ cm $^{-2}$ .还获得了甲苯(C $_6$ H $_5$ CH $_3$)和苯乙烯(C $_6$ H $_5$ C $_2$ H $_3$)(苯的甲基和乙烯基衍生物)的上限。环戊二烯($c$-C $_5$ H $_6$)和乙炔基(CCH)之间的反应可能形成富烯并二烯和乙炔基环戊二烯.然而,TMC-1中自下而上的气相合成循环将环戊二烯的丰度低估了两个数量级,这加强了研究TMC-1等冷暗云环境中环化的所有可能化学途径的必要性。然而,纳入C $_3$ H $_3^+$和C $_2$ H $_4$之间的反…
Discovery of linear propadienone: Study of the chemistry of linear and cyclic H$_2$C$_3$O and H$_2$C$_3$S in TMC-1
Institut des Sciences Moléculaires ISM, CNRS UMR 5255, Univ. Bordeaux(波尔多大学分子科学研究所);Instituto de Física Fundamental, CSIC(西班牙国家科学研究委员会基础物理研究所);Observatorio de Yebes, IGN(耶贝斯天文台)
Doubly substituted isotopologues of HCCCN in TMC-1: Detection of D13CCCN, DC13CCN, DCC13CN, DCCC15N, H13C13CCN, H13CC13CN, HC13C13CN, HCC13C15N, and HC13CC15N