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arXiv 2201.08615astro-ph.EPphysics.geo-ph
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Oldhamite:地幔中C-O-S-Ca循环的新环节与行星宜居性的指示器

Oldhamite: a new link in mantle for C-O-S-Ca cycles and an indicator for planetary habitability

Yuegao Liu

AI总结:

本研究首次报道了地幔条件下oldhamite的形成机制,发现其氧逸度比太阳星云机制高6个数量级,并指出oldhamite的广泛存在可作为行星缺氧不宜居的指示器。

摘要:

在太阳系中,oldhamite(CaS)通常被认为是由太阳星云气体凝结形成的。Enstatite chondrites是oldhamite最重要的储库之一,被认为是形成地球物质的代表。因此,oldhamite的形成机制和演化过程对于深入理解太阳星云、陨石、地球起源以及地球的C-O-S-Ca循环具有重要意义。迄今为止,尚无关于地幔中oldhamite的报道。然而,我们在此展示了在1.5 GPa/1510 K和0.5 GPa/1320 K条件下,通过含硫化物orthopyroxenite与熔融方解石之间的反应形成oldhamite的过程。令人惊讶的是,我们实验中的氧逸度处于地幔条件范围内,比太阳星云机制的氧逸度高6个数量级。Oldhamite很容易被氧化成硫酸钙。岩浆的低氧逸度和大气极低氧含量是行星表面存在oldhamite的必要条件;否则,硬石膏或石膏将大量存在。行星表面oldhamite的广泛存在表明该行星绝对不宜居,因为缺乏氧气。Oldhamite的形成和氧化伴随着二氧化碳的产生和氧气的消耗,这可能对大氧化事件之前和二叠纪-三叠纪界线期间的地球大气产生了影响。

英文摘要:

In the solar system, oldhamite (CaS) is generally considered to be formed by the condensation of solar nebula gas. Enstatite chondrites, one of the most important repositories of oldhamite, are believed to be the representative of the material which formed Earth. Thus, the formation mechanism and the evolution process of oldhamite are of great significance to the deeply understanding about the solar nebula, meteorites, the origin of Earth, and the C-O-S-Ca cycles of Earth. To date, no report about the oldhamite in the mantle exists. However, here we show the formation of oldhamite through the reaction between sulfide-bearing orthopyroxenite and molten calcite at 1.5 GPa/1510 K and 0.5 GPa/1320 K. Surprisingly the oxygen fugacities in our experiments are within the range of mantle conditions, which is 6 orders of magnitude higher than that of the solar nebula mechanism. Oldhamite is easily oxidized to calcium sulfate. Both low oxygen fugacity of magma and extreme low oxygen content of atmosphere are necessary for existence of oldhamite on the surface of a planet; otherwise, anhydrite or gypsum will exist in large quantities. The widespread existence of oldhamite on the planet surface indicates the planet is definitely not habitable because of the scarcity of oxygen. The formation and oxidation of oldhamite are accompanied by the production of carbon dioxide and the consumption of oxygen, which may have an impact on the Earth atmosphere before the Great Oxidation Event and during the Permian-Triassic Boundary.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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