We propose a new, more efficient, and potentially cost effective, solid-state nuclear spin hyperpolarization method combining the Cross Effect mechanism and electron spin optical hyperpolarization in rotating solids. We first demonstrate optical hyperpolarization in the solid state at low temperature and low field, and then investigate its field dependence to obtain the optimal condition for high-field electron spin hyperpolarization. The results are then incorporated into advanced Magic Angle Spinning Dynamic Nuclear Polarization (MAS-DNP) numerical simulations that show that optically pumped MAS-DNP could yield breakthrough enhancements at very high magnetic fields. Based on these investigations, enhancements greater than the ratio of electron to nucleus magnetic moments (>658 for 1H) are possible without microwave irradiation. This could solve at once the MAS-DNP performance decrease with increasing field and the high cost of MAS-DNP instruments at very high fields.
We report a versatile method to efficiently polarize single nuclear spins in diamond, which is based on optical pumping of a single NV color center and mediated by a level-anti crossing in its excited state. A nuclear spin polarization higher than 98% is achieved at room temperature for the 15N nuclear spin associated to the NV center, corresponding to $μ$K effective nuclear spin temperature. We then show simultaneous deterministic initialization of two nuclear spins (13C and 15N) in close vicinity to a NV defect. Such robust control of nuclear spin states is a key ingredient for further scali…
One of the most remarkable properties of the nitrogen-vacancy (NV) center in diamond is that optical illumination initializes its electronic spin almost completely, a feature that can be exploited to polarize other spin species in their proximity. Here we use field-cycled nuclear magnetic resonance (NMR) to investigate the mechanisms of spin polarization transfer from NVs to 13C spins in diamond at room temperature. We focus on the dynamics near 51 mT, where a fortuitous combination of energy matching conditions between electron and nuclear spin levels gives rise to alternative polarization tr…
Bulk 13C polarization can be strongly enhanced in diamond at room-temperature based on the optical pumping of nitrogen-vacancy color centers. This effect was confirmed by irradiating suitably aligned single-crystals at a ~50 mT field promoting anti-crossings between electronic excited-state levels, followed by shuttling of the sample into a custom-built NMR setup and by subsequent 13C detection. A nuclear polarization of ~0.5% - equivalent to the 13C polarization achievable by thermal polarization at room temperature at fields of ~2000 T - was measured, and its bulk nature determined based on …
Polarized atomic ensembles play a crucial role in precision measurements. We demonstrate a novel method of creating atomic polarization in an alkali vapor in a continuous-wave regime. The method relies on a combination of optical pumping by a laser beam and microwave transitions due to a cavity-enhanced magnetic field. With this approach, atomic internal angular momentum can be oriented along a static magnetic field at an arbitrary angle with respect to the laser beam. Furthermore, the atomic polarization depends on the microwave parameters, which can be used for microwave-to-optical transduct…
Optical pumping is an efficient method for initializing and maintaining atomic spin ensembles in a well-defined quantum spin state. Standard optical-pumping methods orient the spins by transferring photonic angular momentum to spin polarization. Generally the spins are oriented along the propagation direction of the light due to selection rules of the dipole interaction. Here we present and experimentally demonstrate that by modulating the light polarization, angular momentum perpendicular to the optical axis can be transferred efficiently to cesium vapor. The transverse pumping scheme employs…
Vacuum polarization of a massive scalar field in the background of a two-dimensional version of a spinning cosmic string is investigated. It is shown that when the `radius of the universe' is such that spacetime is globally hyperbolic the vacuum fluctuations are well behaved, diverging though on the `chronology horizon'. Naive use of the formulae when spacetime is nonglobally hyperbolic leads to unphysical results. It is also pointed out that the set of normal modes used previously in the literature to address the problem gives rise to two-point functions which do not have a Hadamard form, and…
The phenomenon of charge pumping and the modern theory of electric polarization are reconsidered by analytically taking into account emergent non-Hermitian contributions. These are accounted for through the use of an extended definition of the velocity operator and are determined by means of a dynamic Hellmann-Feynman theorem (DHFT) that we derive here for the first time. The DHFT introduces generalized Berry curvatures and it is valid for calculating observables nonperturbatively, hence with results valid to all orders of the external fields. By using the extended velocity operator we rigorou…
Sharp threshold-like transitions between two stable nuclear spin polarizations are observed in optically pumped individual InGaAs self-assembled quantum dots embedded in a Schottky diode when the bias applied to the diode is tuned. The abrupt transitions lead to the switching of the Overhauser field in the dot by up to 3 Tesla. The bias-dependent photoluminescence measurements reveal the importance of the electron-tunneling-assisted nuclear spin pumping. We also find evidence for the resonant LO-phonon-mediated electron co-tunneling, the effect controlled by the applied bias and leading to the…
Erbium doped solids are potential candidates for the realization of a quantum memory for photons at telecommunication wavelengths. The implementation of quantum memory proposals in rare earth ion doped solids require spectral tailoring of the inhomogeneous absorption profile by efficient population transfer between ground state levels (spin polarization) using optical pumping. In this article we investigate the limiting factors of efficient optical pumping between ground state Zeeman levels in an erbium doped Y2SiO5 crystal. We introduce two methods to overcome these limiting factors: stimulat…
Understanding the joint dynamics of electron and nuclear spins is central to core concepts in solid-state magnetic resonance - such as spin-lattice relaxation and dynamic nuclear polarization - but a generalization that capitalizes on competing polarization loss and gain channels is still lacking. Here, we theoretically study the non-Hermitian dynamics of hybrid electron/nuclear spin systems in the simultaneous presence of electron spin pumping and spin-lattice relaxation. Focusing on periodic, one-dimensional chains, we find that by adjusting the electron spin pumping to a critical level, it …
Two dimensional heterostructures are likely to provide new avenues for the manipulation of magnetization that is crucial for spintronics or magnetoelectronics. Here, we demonstrate that optical spin pumping can generate a large effective magnetic field in two dimensional MoSe2/WSe2 heterostructures. We determine the strength of the generated field by polarization-resolved measurement of the interlayer exciton photoluminescence spectrum: the measured splitting exceeding 10 milli-electron volts (meV) between the emission originating from the two valleys corresponds to an effective magnetic field…
We study the photon emission from a quantum dot embedded in a microcavity. Incoherent pumping of its excitons and biexciton provokes the emission of leaky and cavity modes. By solving a master equation we obtain the correlation functions required to compute the spectrum and the relative efficiency among the emission of pairs and single photons. A quantum regime appears for low pumping and large rate of emission. By means of a post-selection process, a two beams experiment with different linear polarizations could be performed producing a large polarization entanglement visibility precisely in …
Initializing a set of qubits to a given quantum state is a basic prerequisite for the physical implementation of quantum-information protocols. Here, we discuss the polarization of the electronic and nuclear spin in a single nitrogen vacancy center in diamond. Our initialization scheme uses a sequence of laser, microwave and radio-frequency pulses, and we optimize the pumping parameters of the laser pulse. A rate equation model is formulated that explains the effect of the laser pulse on the spin system. We have experimentally determined the population of the relevant spin states as a function…
We introduce a classification scheme for symmetry protected topological phases applicable to stationary states of open systems based on a generalization of the many-body polarization. The polarization can be used to probe the topological properties of non-interacting and interacting closed and open systems as well and remains a meaningful quantity even in the presence of moderate particle-number fluctuations. As examples, we discuss two open-system versions of a topological Thouless pump in the steady state of one-dimensional lattices driven by Markovian reservoirs. In the analogous unitary sy…
Analytical model for polarization transfer during gas-phase collision events in spin-exchange optical pumping: Spin-$\frac{1}{2}$ $^{129}$Xe versus spin-$\frac{3}{2}$ $^{131}$Xe
Exciton spin and related optical polarization in self-assembled InAs/In$_{0.53}$Ga$_{0.23}$Al$_{0.24}$As/InP(001) quantum dashes emitting at 1.55 μm are investigated by means of polarization- and time-resolved photoluminescence, as well as photoluminescence excitation spectroscopy, at cryogenic temperature. We investigate the influence of highly non-resonant and quasi-resonant optical spin pumping conditions on spin polarization and spin memory of the quantum dash ground state. We show that a spin pumping scheme, utilizing the longitudinal-optical-phonon-mediated coherent scattering process, c…
Coherent dark states in atoms, created by simultaneous interaction of two coherent light fields with a 3-level system, are of prime importance in quantum state manipulation. They are used extensively in quantum sensing and quantum information applications to build atomic clocks, magnetometers, atomic interferometers and more. Here we study the formation and decay of coherent dark-states in an ensemble of laser-cooled free-falling atoms. We measure the optical-pumping rate into the dark-state in the $σ^+-σ^-$ polarization configuration. We find that the pumping rate is linear with the optical f…
