We present out-of-plane dielectric and magnetodielectric measurements of single crystallines $α$-RuCl$_3$ with various degrees of stack faults. A frequency dependent, but field independent, dielectric anomaly appears at $T_{A}\:(f=100\:\mathrm{kHz})\sim$ 4 K once both magnetic transitions at $T_{N1}\sim$ 7 K and $T_{N2}\sim$ 14 K set in. The observed dielectric anomaly is attributed to the emergency of possible local electric polarizations whose inversion symmetry is broken by inhomogeneously distributed stacking faults. A field-induced intermediate phase is only observed when a magnetic field is applied perpendicular to the Ru-Ru bonds for samples with minimal stacking faults. Less pronounced in-plane anisotropy is found in samples with sizable contribution from stacking imperfections. Our findings suggest that dielectric measurement is a sensitive probe in detecting the structural and magnetic properties, which may be a promising tool especially in studying $α$-RuCl$_3$ thin film devices. Moreover, the stacking details of RuCl$_3$ layers strongly affect the ground state both in the magnetic and electric channels. Such a fragile ground state against stacking faults needs to be overcome for realistic applications utilizing the magnetic and/or electric properties of Kitaev based physics in $α$-RuCl$_3$.
The layered honeycomb magnet alpha-RuCl3 has been proposed as a candidate to realize a Kitaev spin model with strongly frustrated, bond-dependent, anisotropic interactions between spin-orbit entangled jeff=1/2 Ru4+ magnetic moments. Here we report a detailed study of the three-dimensional crystal structure using x-ray diffraction on untwinned crystals combined with structural relaxation calculations. We consider several models for the stacking of honeycomb layers and find evidence for a crystal structure with a monoclinic unit cell corresponding to a stacking of layers with a unidirectional in…
We report a muon spin rotation/relaxation ($μ$SR) study of single-crystalline samples of the $α$-RuCl$_3$ honeycomb magnet, which is presumed to be a model compound for the Kitaev-Heisenberg interaction. It is inferred from magnetic susceptibility and specific-heat measurements that the present samples exhibit successive magnetic transitions at different critical temperatures $T_{\rm N}$ with decreasing temperature, eventually falling into the $T_{\rm N}=7$ K antiferromagnetic (7 K) phase that has been observed in only single-crystalline specimens with the least stacking fault. Via $μ$SR measu…
$α$-RuCl$_3$ intercalated into graphite: a new three-dimensional platform for exotic quantum phases
Goethe-Universität（歌德大学）；The University of Tennessee（田纳西大学）；Clemson University（克莱姆森大学）；National Institute of Physics, University of the Philippines Diliman（菲律宾大学迪利曼国立物理研究所）；Oak Ridge National Laboratory（橡树岭国家实验室）；Duke University（杜克大学）
Spin $\frac{1}{2}$ honeycomb materials have gained substantial interest due to their exotic magnetism and possible application in quantum computing. However, in all current materials out-of-plane interactions are interfering with the in-plane order, hence a true 2D magnetic honeycomb system is still of demand. Here, we report the exfoliation of the magnetic semiconductor $α$-RuCl$_3$ into the first halide monolayers and the magnetic characterization of the spin $\frac{1}{2}$ honeycomb arrangement of turbostratically stacked RuCl$_3$ monolayers. The exfoliation is based on a reductive lithiatio…
In $α$-RuCl$_3$, an external magnetic field applied within the honeycomb plane can induce a transition from a magnetically ordered state to a disordered state that is potentially related to the Kitaev quantum spin liquid. In zero field, single crystals with minimal stacking faults display a low-temperature state with in-plane zigzag antiferromagnetic order and a three-layer periodicity in the direction perpendicular to the honeycomb planes. Here, we present angle-dependent magnetization, ac susceptibility, and thermal transport data that demonstrate the presence of an additional intermediate-f…
We report a detailed experimental and theoretical study on the effect of hydrostatic pressure on the structural and magnetic aspects of the layered honeycomb antiferromagent $α$-RuCl$_{3}$. Magnetic susceptibility measurements performed under almost ideal hydrostatic-pressure conditions yield that the phase transition to zigzag-type antiferromagnetic order at $T_N$ = 7.3 K can be rapidly suppressed to about 6.1 K. A further suppression with increasing pressure is impeded due to the occurrence of a pressure-induced structural transition at $p \geq$ 104 MPa, accompanied by a strong dimerization …
Magnetic dilution of a well-established Kitaev candidate system is realized in the substitutional Ru$_{1-x}$Rh$_x$Cl$_3$ series ($x = 0.02-0.6$). Optimized syntheses protocols yield uniformly-doped single crystals and polycrystalline powders that are isostructural to the parental $α$-RuCl$_3$ as per X-ray diffraction. The Rh content $x$ is accurately determined by the quantitative energy-dispersive X-ray spectroscopy technique with standards. We determine the magnetic phase diagram of Ru$_{1-x}$Rh$_x$Cl$_3$ for in-plane magnetic fields from magnetization and specific-heat measurements as a fun…
The random spin-orbit coupling in multicomponent superconductors is investigated focusing on the non-centrosymmetric superconductor CePt_3Si and the spin triplet superconductor Sr_2RuO_4. We find novel manifestations of the random spin-orbit coupling in the multicomponent superconductors with directional disorders, such as stacking faults. The presence of stacking faults is indicated for the disordered phase of CePt_3Si and Sr_2RuO_4. It is shown that the d-vector of spin triplet superconductivity is locked to be d = k_y x - k_x y with the anisotropy ΔT_c/T_c0 \sim \barα^2/T_c0 W_z, where \bar…
Spin sensitive transport in RuCl_3/Pt heterostructures: revealing a field-transverse spin anisotropy in a spin liquid candidate
WPI Advanced Institute for Materials Research (AIMR) and Center for Science and Innovation in Spintronics (CSIS), Tohoku University（东北大学材料高等研究所（AIMR）与自旋电子学科学与创新中心（CSIS））；Department of Physics and Astronomy and Purdue Quantum Science and Engineering Institute, Purdue University（普渡大学物理与天文学系及普渡量子科学与工程研究所）；Department of Physics, The University of Tokyo（东京大学物理学系）；Institute for Materials Research (IMR), Tohoku University（东北大学材料研究所（IMR））；Materials Science and Technology Division, Oak Ridge National Laboratory（橡树岭国家实验室材料与科技分部）；The Quantum Science Center, Oak Ridge National Laboratory（橡树岭国家实验室量子科学中心）；Computational Sciences and Engineering Division, Oak Ridge National Laboratory（橡树岭国家实验室计算科学与工程分部）；Department of Materials Science and Engineering, University of Tennessee（田纳西大学材料科学与工程系）；Neutron Scattering Division, Oak Ridge National Laboratory（橡树岭国家实验室中子散射分部）；School of Electrical and Computer Engineering and Birck Nanotechnology Center, Purdue University（普渡大学电气与计算机工程学院及Birck纳米技术中心）；Institute of Physics and Astronomy and Villum Centers for Dirac Materials and for Hybrid Quantum Materials and Devices, Aarhus University（奥胡斯大学物理与天文学研究所及Villum狄拉克材料与混合量子材料及器件中心）
We report the nature of magnetic structure, microscopic spin-spin correlations and their dependence on the underlying crystal structure of the geometrically frustrated layered spin-3/2 maple-leaf-lattice (MLL) antiferromagnet Na2Mn3O7 by a comprehensive neutron diffraction study. Crystal structural studies by x-ray and neutron diffractions reveal that the MLL layers (constituted by Mn3O72- units) are well separated by non-magnetic Na layers. The studies also conclude the presence of stacking faults (in-plane sliding of magnetic MLL layers) as well as a distortion in the MLL of Mn4+. Temperatur…
