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arXiv 2103.16868cond-mat.mtrl-sciphysics.chem-ph
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碳氮化物的结构与稳定性:开环诱导的光电化学降解

Structure and stability of carbon nitrides: ring opening induced photoelectrochemical degradation

Florentina Iuliana Maxim, Eugenia Tanasa, Bogdan Mitrea, Cornelia Diac, Tomas Skala, Liviu Cristian Tanase, Adrian Ciocanea, Stefan Antohe, Eugeniu Vasile, Serban N. Stamatin

AI总结:

针对清洁能源领域对稳定光催化材料的需求,本研究制备并表征了三聚氰胺热缩聚得到的聚合碳氮化物,发现其在高过电势下会因开环发生光电化学降解,为该类材料的应用优化提供了依据。

摘要:

清洁能源需求的持续增长要求研究界开展更多创新。能够利用太阳辐射推动各类反应的高活性、稳定材料是新兴技术的基石。可捕获太阳辐射以驱动电化学反应的聚合碳氮化物(polymeric carbon nitrides)被认为是可靠的候选材料。本研究通过三聚氰胺热缩聚法制备了聚合碳氮化物,利用同步辐射和实验室技术对所得材料进行了表征,并结合电化学光电研究完整表征了其电子能带结构。光电化学实验前后的电子显微镜研究显示,材料出现了形貌和结构降解。本研究得出结论:聚合碳氮化物在高过电势下易发生光电化学降解。

英文摘要:

A constant increase in the need of clean energy demands more innovation from the research community. Active and stable materials that can make use of the solar radiation to promote different reactions are the cornerstone of emerging technologies. Polymeric carbon nitrides that harvest solar radiation to drive electrochemical reactions are considered solid candidates. In this respect, polymeric carbon nitrides were prepared by the thermal polycondensation of melamine. As-obtained materials were characterized by synchrotron radiation and lab-based techniques. The electron band structure was fully characterized by a combined electrochemical optoelectronic study. Electron microscopy studies before and after the photoelectrochemical experiments showed morphological and structure degradation. The work at-hand concludes that polymeric carbon nitrides are prone to photoelectrochemical degradation at high overpotentials.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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