The onset of rigidity in interacting liquids, as they undergo a transition to a disordered solid, is associated with a rearrangement of the low-frequency vibrational spectrum. In this letter, we derive scaling forms for the singular dynamical response of disordered viscoelastic networks near both jamming and rigidity percolation. Using effective-medium theory, we extract critical exponents, invariant scaling combinations and analytical formulas for universal scaling functions near these transitions. Our scaling forms describe the behavior in space and time near the various onsets of rigidity, for rigid and floppy phases and the crossover region, including diverging length and time scales at the transitions.
Disordered viscoelastic materials are ubiquitous and exhibit fascinating invariant scaling properties. In a companion article, we have presented comprehensive new results for the critical behavior of the dynamic susceptibility of disordered elastic systems near the onset of rigidity. Here we provide additional details of the derivation of the singular scaling forms of the longitudinal response near both jamming and rigidity percolation. We then discuss global aspects associated with these forms, and make scaling collapse plots for both undamped and overdamped dynamics in both the rigid and flo…
The progressive onset of slip at the wall, which corresponds to a slip length increasing with the solicitation time before reaching a plateau, has been investigated for model viscoelastic polymer solutions, allowing one to vary the longest relaxation time while keeping constant solid - fluid interactions. A hydrodynamic model based on a Maxwell fluid and the classical Navier's hypothesis of a linear response for the friction stress at the interface fully accounts for the data, without any adjustable parameter. No viscoelastic response needs be postulated for the friction, reflecting the local …
Disordered spring networks that are undercoordinated may abruptly rigidify when sufficient strain is applied. Since the deformation in response to applied strain does not change the generic quantifiers of network architecture - the number of nodes and the number of bonds between them - this rigidity transition must have a geometric origin. Naive, degree-of-freedom based mechanical analyses such as the Maxwell-Calladine count or the pebble game algorithm overlook such geometric rigidity transitions and offer no means of predicting or characterizing them. We apply tools that were developed for t…
We analyze transient dynamics during shear start-up in viscoelastic flows between two parallel plates, with a specific focus on the signatures for the onset of transient shear banding using the Johnson-Segalman, non-stretching Rolie-Poly and Giesekus models. We explore the dynamics of shear start-up in monotonic regions of the constitutive curves using two different methodologies: (i) the oft-used `frozen-time' linear stability (eigenvalue) analysis, wherein we examine whether infinitesimal perturbations imposed on instantaneous stress components (treated as quasi steady states) exhibit expone…
Conversion of liquid milk to cheese curds is the first stage in cheese manufacture. Changing the rigidity of cheese curds through heating and pH control is an established method for preparing fresh curds, whereas a similar method to prepare fully coagulated curds is largely unknown. This study elucidated the effect of temperature variation on the viscoelastic moduli of fully coagulated curds under different pH conditions. The results showed that rennet curds treated at pH 4.8 exhibited drastic changes in the viscoelasticity at 43 degrees C, above which the degree of fluidity exceeded the degre…
We present experimental evidence of global viscoelastic flow transitions in 2:1, 8:1 and 32:1 planar contractions under inertia-less conditions. Light sheet visualization and laser Doppler velocimetry techniques are used to probe spatial structure and time scales associated with the onset of these instabilities. The results are reported in terms of critical Weissenberg numbers characterizing the fluid flow rates. For a given contraction ratio and polymer fluid, a two-dimensional, steady flow with converging streamlines transitions to a two-dimensional pattern with diverging streamlines beyond …
We study geometrical clues of a rigidity transition due to the emergence of a system-spanning state of self stress in under-constrained systems of individual polygons and spring networks constructed from such polygons. When a polygon with harmonic bond edges and an area spring constraint is subject to an expansive strain, we observe that convexity of the polygon is a necessary condition for such a self stress. We prove that the cyclic configuration of the polygon is a sufficient condition for the self stress. This correspondence of geometry and rigidity is akin to the straightening of a one di…
Inertial cavitation in soft matter is an important phenomenon featured in a wide array of biological and engineering processes. Recent advances in experimental, theoretical, and numerical techniques have provided access into a world full of nonlinear physics, yet most of our quantitative understanding to date has been centered on a spherically symmetric description of the cavitation process. However, cavitation bubble growth and collapse rarely occur in a perfectly symmetrical fashion, particularly in soft materials. Predicting the onset of dynamically arising, non-spherical instabilities has …
The dynamical properties and mechanical functions of amorphous materials are governed by their microscopic structures, particularly the elasticity of the interaction networks, which is generally complicated by structural heterogeneity. This ubiquitous heterogeneous nature of amorphous materials is intriguingly attributed to a complex role of entropy. Here, we show in disordered networks that the vibrational entropy increases by creating phase-separated structures when the interaction connectivity is close to the onset of network rigidity. The stress-energy, which conversely penalizes the heter…
We present a detailed analysis of the unjamming transition in 2D frictionless disk packings using a static correlation function that has been widely used to study disordered systems. We show that this point-to-set (PTS) correlation function exhibits a dominant length scale that diverges as the unjamming transition is approached through decompression. In addition, we identify deviations from meanfield predictions, and present detailed analysis of the origin of non-meanfield behavior. A mean-field bulk-surface argument is reviewed. Corrections to this argument are identified, which lead to a cha…
We consider a continuum model of active viscoelastic matter, whereby an active nematic liquid-crystal is coupled to a minimal model of polymer dynamics with a viscoelastic relaxation time $τ_C$. To explore the resulting interplay between active and polymeric dynamics, we first generalise a linear stability analysis (from earlier studies without polymer) to derive criteria for the onset of spontaneous heterogeneous flows (strain rate) and/or deformations (strain). We find two modes of instability. The first is a viscous mode, associated with strain rate perturbations. It dominates for relativel…
We investigate the onset of the Faraday instability in a vertically vibrated wormlike micelle solution. In this strongly viscoelastic fluid, the critical acceleration and wavenumber are shown to present oscillations as a function of driving frequency and fluid height. This effect, unseen neither in simple fluids nor in previous experiments on polymeric fluids, is interpreted in terms of standing elastic waves between the disturbed surface and the container bottom. It is shown that the model of S. Kumar [Phys. Rev. E, {\bf 65}, 026305 (2002)] for a viscoelastic fluid accounts qualitatively for …
We study the onset of rigidity near the glass transition (GT) in a short-chain polymer melt modelled by a bead-spring model, where all beads interact with Lennard-Jones potentials. The properties of the system are examined above and below the GT. In order to minimize high cooling-rate effects and computational times, equilibrium configurations are reached via isothermal compression. We monitor quantities such as the heat capacity C_P, the short-time diffusion constants D, the viscosity η, and the shear modulus; the time-dependent shear modulus G(t) is compared with the shear modulus μobtained …
