We discuss theoretically static and dynamical properties of $XY$ and Heisenberg antiferromagnets on triangular lattice with random vacancies and substitutional spins. It is shown that the distortion of $120^\circ$ magnetic order produced by a single defect is described by electrostatic equations for a field of an electrically neutral complex of six charges located around the impurity. The first finite term in the multipole expansion of this field is the octupole moment which decays as $1/r^3$ with the distance $r$. The linearity of equations allows to describe analytically the distortion of the long-range magnetic order at a small concentration $c$ of defects. We obtain analytically renormalization of the elastic neutron scattering cross section and the magnon spectrum $ε_{\bf k}$ in the leading order in $c$. We find that the scattering on impurities renormalizes weakly the bare spectrum $ε_{\bf k}\propto k$ at $k\gg\sqrt c$. However the renormalization is substantial of the long-wavelength magnon spectrum at $k\ll\sqrt c$: $ε_{\bf k}\propto \sqrt{c /\ln(1/k)}$ at $k\to0$ and there is a parametrically large region in which magnons with not too small momenta are overdamped and localized. This strong modification of the long-wavelength spectrum leads to the stabilization of the slightly distorted magnetic long-range order at $T<T_N\sim S^2J/\ln(1/c)$ and to the considerable change in the density of states and in the specific heat. The overdamped modes arise also in quasi-2D spin systems on a stacked triangular lattice.
Electronic structures and magnetic orders of Fe-vacancies ordered ternary iron selenides TlFe$_{1.5}$Se$_2$ and AFe$_{1.5}$Se$_2$ (A=K, Rb, or Cs)
通过第一性原理电子结构计算,我们发现Fe空位有序TlFe $_{1.5}$ Se $_2$的基态是一个准二维共线反铁磁半导体,其能隙为94 meV,与实验测量相一致.这种反铁磁有序是由Fe磁矩之间的Se桥反铁磁超交换相互作用驱动的。同样地,我们发现晶体AFe $_{1.5}$ Se $_2$(A=K,Rb,或Cs)也是反铁磁半导体,但具有零能隙半导体态或与基态近似简并的半金属态。因此,丰富的物理性质和相图的预期。
Effect of iron vacancies on the magnetic order and spin dynamics of the spin ladder BaFe$_{2-δ}$S$_{1.5}$Se$_{1.5}$
准一维铁硫属化物具有不同的磁状态,这取决于晶格畸变、电子相关性和缺陷的存在。本文报道了含$\sim$ 6%铁空位的自旋梯化合物BaFe $_{2-δ}$ S $_{1.5}$ Se $_{1.5}$的中子衍射和非弹性中子散射实验。数据显示,长程磁秩序是不存在的,而对应于条纹和块型反铁磁相关的特征磁激发观察。第一性原理计算支持在实验样品中同时存在条状和块状反铁磁短程有序。长程磁序的消失可能是由于这两种磁序之间的竞争,对于一定浓度的铁空位,这种竞争大大增强,我们计算的铁空位浓度约为6%,与测量的铁空位浓度一致。我们的结果突出了铁基自旋梯系统中的铁空位如何强烈地影响磁性基态。
Intrinsic susceptibility and bond defects in the novel 2D frustrated antiferromagnet Ba$_{2}$Sn$_{2}$ZnCr$_{7p}$Ga$_{10-7p}$O$_{22}$
本文报道了高阻挫反铁磁体Ba $_{2}$ Sn $_{2}$ ZnCr $_{7p}$ Ga $_{10-7p}$ O $_{22}$的微观和宏观磁性,分别用NMR和SQUID实验进行了探测. Cr $^{3+}$受抑kagomé双层的固有磁化率的$T$ -变化,$χ_{kag}$,在45 K附近显示最大值。详细研究了$0.29 \leq p \leq0.97$的磁晶格稀释。新的稀释无关的缺陷,可能与磁键无序,证明和讨论。我们将我们的结果与SrCr $_{9p}$ Ga $_{12-9p}$ O $_{19}$进行比较。键缺陷和自旋空位都不影响kagomé双层膜的平均磁化率。
Order Induced by Dilution in Pyrochlore XY Antiferromagnets
众所周知,XY烧绿石反铁磁体通过量子和热选择表现出有序无序。在本文中,我们考虑的效果替代非磁性离子的磁性网站烧绿石XY模型一般各向异性交换调整的一个单一的参数$J^{\pm\pm}/J^\pm$。物理学由参数$J^{\pm\pm}/J^\pm=\pm 2$的该空间中的两个点控制,在这两个点处,在基态中存在线模式,并且因此存在介于常规磁体和库仑相位之间的$O(L^2)$基态简并度。在这些点中的每一点处,单个空位产生线缺陷对。两个线缺陷携带不兼容的自旋配置从不同的空位可以交叉导致一个有效的一维描述所产生的自旋织构。在有限密度下的热力学极限中,我们发现稀释选择了一个与从单空位极限中理解的热无序和量子无序所选择的状态“相反”的状态。后一发现暗示了Er $_{2-x}$ Y $_x$ Ti $_2$ O $_7$对小$x$表现出热选择$ψ_2$状态到由淬灭无序选择的$ψ_3$状态的第二相变的可能性。
Tuning of the carrier localization, magnetic and thermoelectric properties in ultrathin (LaNiO$_{3-δ}$)$_1$/(LaAlO$_{3}$)$_1$(001) superlattices by oxygen vacancies
Effect of perturbations on the kagome $S=1/2$ antiferromagnet at all temperatures
$S=1/2$可果美海森堡反铁磁体的基态现在被认为是一种自旋液体,但它的确切性质仍然没有确定,即使越来越多的线索指向一种无隙自旋液体。我们使用高温系列展开(HTSE)外推的比热$c_V(T)$和磁化率$χ(T)$在整个温度范围内,使用改进的熵方法与自我确定的基态能量每个网站$e_0$。优化算法给出的HTSE系数达到前所未有的数量级(20 in $1/T$),并作为磁场的精确函数。对于$c_V$的不同低$T$行为,给出了三种外推:指数(对于带隙系统)、线性或二次(对于两种不同类型的无隙自旋液体)。我们研究了各种扰动对海森堡哈密顿量的影响:伊辛各向异性,Dzyaloshinskiii-Moriya相互作用,第二和第三邻居相互作用,以及随机分布的磁空位。我们提出了一个实验测定的$χ(T=0)$,这可能是非零的,从$c_V$测量在不同的磁场。