In this work, we investigate dissipative effects involved during the detachment of a smooth spherical glass probe from a viscoelastic silicone substrate patterned with micro-asperities. As a baseline, the pull-off of a single asperity, millimeter-sized contact between a glass lens and a smooth poly(dimethylsiloxane) (PDMS) rubber is first investigated as a function of the imposed detachment velocity. From a measurement of the contact radius a(t) and normal load during unloading, the dependence of the strain energy relase rate G on the velocity of the contact line vc = da/dt is determined under the assumption that viscoelastic dissipation is localized at the edge of the contact. These data are incorporated into Muller's model (V.M. Muller J Adh Sci Tech (1999) 13 999-1016) in order to predict the time-dependence of the contact size. Similar pull-off experiments are carried out with the same PDMS substrate patterned with spherical micro-asperities with a prescribed height distribution. From in situ optical measurements of the micro-contacts, scaling laws are identified for the contact radius a and the contact line velocity vc. On the basis of the observed similarity between macro and microscale contacts, a numerical solution is developed to predict the reduction of the contact radius during unloading.
Pastewka & Robbins (PNAS, 111(9), 3298-3303, 2014) recently have proposed a criterion to distinguish when two surfaces will stick together or not, and suggested it shows a large conflict with asperity theories. It is found that their criterion corresponds very closely to the Fuller and Tabor asperity model one when bandwidth α is small, but otherwise involves a rms ampliture of roughness reduced by a factor Sqrt(α). Therefore, it implies the stickiness of any rough surface is the same as that of the surface where practically all wavelength components of roughness are removed except the very fi…
We study the influence of the surface energy and contamination films on rubber adhesion and sliding friction. We find that there is a transfer of molecules from the rubber to the substrate which reduces the work of adhesion and makes the rubber friction insensitive to the substrate surface energy. We show that there is no simple relation between adhesion and friction: adhesion is due to (vertical) detachment processes at the edge of the contact regions (opening crack propagation), while friction in many cases is determined mainly by (tangential) stick-slip instabilities of nanosized regions, w…
We report on measurements of the local friction law at a multi-contact interface formed between a smooth rubber and statistically rough glass lenses, under steady state friction. Using contact imaging, surface displacements are measured, and inverted to extract both distributions of frictional shear stress and contact pressure with a spatial resolution of about 10~$μ$m. For a glass surface whose topography is self-affine with a Gaussian height asperity distribution, the local frictional shear stress is found to vary strongly sub-linearly with the local contact pressure over the whole investiga…
We study experimentally and theoretically the equilibrium adhesive contact between a smooth glass lens and a rough rubber surface textured with spherical microasperities with controlled height and spatial distributions. Measurements of the real contact area $A$ versus load $P$ are performed under compression by imaging the light transmitted at the microcontacts. $A(P)$ is found to be non-linear and to strongly depend on the standard deviation of the asperity height distribution. Experimental results are discussed in the light of a discrete version of Fuller and Tabor's (FT) original model (\te…
Recently, there has been some debate over the effect of adhesion on the contact of rough surfaces. Classical asperity theories predict, in agreement with experimental observations, that adhesion is always destroyed by roughness except if the amplitude of the same is extremely small, and the materials are particularly soft. This happens for all fractal dimensions. However, these theories are limited due to the geometrical simplification, which may be particularly strong in conditions near full contact. We introduce therefore a simple model for adhesion, which aims at being rigorous near full co…
Frictional properties of contacts between a smooth viscoelastic rubber and rigid surfaces are investigated using a torsional contact configuration where a glass lens is continuously rotated on the rubber surface. From the inversion of the displacement field measured at the surface of the rubber, spatially resolved values of the steady state frictional shear stress are determined within the non homogeneous pressure and velocity fields of the contact. For contacts with a smooth lens, a velocity dependent but pressure independent local shear stress is retrieved from the inversion. On the other ha…
Adhesive interactions strongly characterize the contact mechanics of soft bodies as they lead to large elastic deformations and contact instabilities. In this paper, we extend the Interacting and Coalescing Hertzian Asperities (ICHA) model to the case of adhesive contact. Adhesion is modeled according to an improved version of the Johnson, Kendall & Roberts (JKR) theory, in which jump-in contact instabilities are conveniently considered as well as the lateral interaction of the asperities and the coalescence of merging contact spots. Results obtained on complex fractal geometries with several …
We present a general theory for the contribution from contact electrification to the work necessary to separate two solid bodies. The theory depends on the surface charge density correlation function, which we deduce from Kelvin Force Microscopy (KFM) maps of the surface electrostatic potential. For silicon rubber (polydimethylsiloxane, PDMS) we discuss in detail the relative importance of the different contributions to the observed work of adhesion.
We report on normal contact and friction measurements of model multicontact interfaces formed between smooth surfaces and substrates textured with a statistical distribution of spherical micro-asperities. Contacts are either formed between a rigid textured lens and a smooth rubber, or a flat textured rubber and a smooth rigid lens. Measurements of the real area of contact $A$ versus normal load $P$ are performed by imaging the light transmitted at the microcontacts. For both interfaces, $A(P)$ is found to be sub-linear with a power law behavior. Comparison to two multi-asperity contact models,…
Surface roughness is known to easily suppress the adhesion of elastic surfaces. Here a simple model for the contact of \emph{viscoelastic} rough surfaces with significant levels of adhesion is presented. This approach is derived from our previous model [E. Barthel and G. Haiat {\em Langmuir}, 18 9362 2002] for the adhesive contact of viscoelastic spheres. For simplicity a simple loading/unloading history (infinitely fast loading and constant pull-out velocity) is assumed. The model provides approximate analytical expressions for the asperity response and exhibits the full viscoelastic adhesive…
Contact analysis without adhesion is still a challenging problem, mainly owing to the multiscale and self-fractal characteristics of rough surfaces. Up to now, theories for analyzing contact behavior of rough surfaces in literature can be generally categorized into two groups: the asperity-based Hertz contact models initiated by Greenwood and Williamson (G-W model), which is shown more accurate under small indentation distance, and the magnification-based pressure diffusion theory initiated by Persson, which is shown to work well under full contact conditions. The aim of this paper is to propo…
The diverse chemical and physical reactions encountered during cooking connect us to science every day. Here, we theoretically and experimentally investigate the swelling and softening of pasta due to liquid imbibition, as well as the elastic deformation and adhesion of pasta due to capillary force. As water diffuses into the pasta during cooking, it softens gradually from the outside inward as starch swells. The softening follows three sequential regimes: Regime I shows a slow decrease of modulus with cooking time; Regime II, the glassy to rubbery transition region, is characterized by very f…
We review a theory of crack propagation in viscoelastic solids. We consider both cracks in infinite systems and in finite sized systems. As applications of the theory we consider two adhesion problems, namely pressure sensitive adhesives and the ball-flat adhesion problem. We also study crack propagation in the pig skin dermis, which is of medical relevance, and rubber wear in the context of tires.
This paper reports on the frictional properties of smooth rubber substrates sliding against rigid surfaces covered with various densities of colloidal nano-particles (average diameter 77 nm). Friction experiments were carried out using a transparent Poly(dimethyl siloxane) (PDMS) rubber contacting a silica lens with silica nano-particles sintered onto its surface. Using a previously described methodology (Nguyen \textit{et al.}, \textit{J. of Adhesion} \textbf{87} (2011) 235-250 ), surface shear stress and contact-pressure distribution within the contact were determined from a measurement of t…
Contact mechanics-based models for the friction of nominally flat rough surfaces have not been able to adequately capture certain key experimentally observed phenomenona, such as the transition from a static friction peak to a lower level of sliding friction and the shear-induced contact area reduction that has been observed in the pre-sliding regime especially for soft materials. Here, we propose a statistical model based on physically-rooted contact mechanics laws describing the micromechanics of individual junctions. The model considers the quasi-static tangential loading, up to full slidin…
In rubber friction studies it is often observed that the kinetic friction coefficient μ depends on the nominal contact pressure p. We discuss several possible origins of the pressure dependency of μ: (a) saturation of the contact area (and friction force) due to high nominal squeezing pressure, (b) non-linear viscoelasticity, (c) non-randomness in the surface topography, in particular the influence of the skewness of the surface roughness profile, (d) adhesion, and (e) frictional heating. We show that in most cases the non-linearity in the μ(p) relation is mainly due to process (e) (frictional…
Adhesive [e.g. van der Waals] forces were not generally taken into account in contact mechanics until 1971, when Johnson, Kendall and Roberts (JKR) generalized Hertz' solution for an elastic sphere using an energetic argument which we now recognize to be analogous to that used in linear elastic fracture mechanics. A significant result is that the load-displacement relation exhibits instabilities in which approaching bodies `jump in' to contact, whereas separated bodies `jump out' at a tensile `pull-off force'. The JKR approach has since been widely used in other geometries, but at small length…
We present contact radius and curvature corrections to the nonlocal contact formulation that take into account multi-particle interactions in elastic confined granular systems. The nonlocal contact formulation removes the classical assumption of independent contacts by taking into account the interplay of deformations due to multiple contact forces acting on a single particle. The contact radius correction considers the components of these deformations that contribute to the inter-particle contact area. The curvature correction improves the description of the contacting surface profiles by inc…
