Describing the comprehensive evolutionary scenario for asteroids is key to explaining the various physical processes of the solar system. Bulk-scale carbonaceous chondrites (CCs) possibly record the primordial information associated with the formation processes of their parent bodies. In this study, we tried to estimate the relative formation region of volatile-rich asteroids by utilizing the nucleosynthetic Cr isotopic variation (54Cr/52Cr) in bulk-scale CCs. Numerical calculations were conducted to track the temporal evolution of isotopically different (solar and presolar) dust and 54Cr/52Cr values for mixed materials with disk radius. First, we found that isotopic heterogeneities in CC formation regions would be preserved with a weak turbulence setting that would increase the timescales of the advection and diffusion in the disk. Second, we assessed the effects of gaps formed by giant planets. Finally, the distance from the injected supernovae and Cr isotopic compositions of the presolar grains were investigated in terms of the estimated formation region of CCs. In our results, a plausible formation region of four types of CCs can be obtained with the supernova from approximately 2 pc and typical Cr isotopic compositions of presolar grains. Among the parent bodies of CCs (i.e., volatile-rich asteroids), B-type asteroids formed in the outermost region, which is inconsistent with the present population, showing that D-type asteroids are generally located beyond most of the C-complex asteroids. Both the initial and present orbits of asteroids might be explained by the scatter attributed to the inward-outward migration of Jupiter and Saturn.
The distribution and isotopic composition of volatile elements in planetary materials holds a key to the characterization of the early solar system and the Moon's formation. The Moon and Earth are chemically and isotopically very similar. However, the Moon is highly depleted in volatile elements and the origin of this depletion is still debated. We present gallium isotopic and elemental measurements in a large set of lunar samples to constrain the origin of this volatile depletion. We show that while Ga has a geochemical behavior different from zinc, both elements show a systematic enrichment …
We report on the results of NanoSIMS isotope imaging of low-density supernova graphite grains from the Orgueil meteorite. 70 nm thick microtomed sections of three supernova graphite grains were deposited on Si wafers and isotopically imaged in the NanoSIMS. These sections contain hotspots of excesses in $^{18}O$ and $^{15}N$ which are spatially well correlated, and are likely carried by internal TiC subgrains. These hotspots are considerably more enriched in $^{18}O$ and $^{15}N$ than the host graphite grain. Correlations between $^{18}O$ and $^{15}N$ excesses indicate that the grains incorpor…
Lunar rocks are severely depleted in moderately volatile elements such as Rb, K, and Zn relative to Earth. Identifying the cause of this depletion is important for understanding how the Earth-Moon system evolved in the aftermath of the Moon-forming giant impact. We measured the Rb isotopic compositions of lunar and terrestrial rocks to understand why moderately volatile elements are depleted in the Moon. Combining our new measurements with previous data reveals that the Moon has an 87Rb/85Rb ratio higher than Earth by +0.16 permil. This isotopic composition is consistent with evaporation of Rb…
Nucleosynthetic isotopic anomalies in meteorites and planetary objects contribute to our understanding of the formation of the solar system. Isotope systematics of chondrites demonstrate the existence of a physical separation between isotopic reservoirs in the solar system. The isotopic composition of atmospheric xenon (Xe) indicates that its progenitor, U-Xe, is depleted in 134Xe and 136Xe isotopes relative to Solar or Chondritic end-members. This deficit supports the view that nucleosynthetic heterogeneities persisted during the Solar System formation. Measurements of xenon emitted from come…
Solar system materials are variably depleted in moderately volatile elements (MVEs) relative to the proto-solar composition. To address the origin of this MVE depletion, we conducted a systematic study of high-precision K isotopic composition on 16 carbonaceous chondrites (CCs) of types CM1-2, CO3, CV3, CR2, CK4-5 and CH3 and 28 ordinary chondrites (OCs) covering petrological types 3 to 6 and chemical groups H, L, and LL. We observed significant overall K isotope (delta41K) variations (-1.54 to 0.70 permil). The K isotope compositions of CCs are largely higher than the Bulk Silicate Earth (BSE…
The isotopic compositions of terrestrial hydrogen and nitrogen are clearly different from those of the nebular gas from which the solar system formed, and also differ from most of cometary values. Terrestrial N and H isotopic compositions are in the range of values characterizing primitive meteorites, which suggests that water, nitrogen, and other volatile elements on Earth originated from a cosmochemical reservoir that also sourced the parent bodies of primitive meteorites. Remnants of the proto-solar nebula (PSN) are still present in the mantle, presumably signing the sequestration of PSN ga…
Martian atmospheric neon (Ne) has been detected by Viking and also found as trapped gas in Martian meteorites, though its abundance and isotopic composition have not been well determined. Because the timescale of Ne loss via atmospheric escape estimated from recent measurements with MAVEN is short (0.6--1 $\times$ 10$^8$ years), the abundance and isotope composition of Martian atmospheric Ne reflect recent atmospheric gas supply mostly from volcanic degassing. Thus, it can serve as a probe for the volatile content of the interior. Here we show that the tentatively-informed atmospheric Ne abund…
Carbonaceous chondrites (CCs) may have been the carriers of water, volatile and moderately volatile elements to Earth. Investigating the abundances of these elements, their relative volatility, and isotopes of state-change tracer elements such as Zn, and linking these observations to water contents, provide vital information on the processes that govern the abundances and isotopic signatures of these species in CCs and other planetary bodies. Here we report Zn isotopic data for 28 CCs (20 CM, 6 CR, 1 C2-ung, and 1 CV3), as well as trace element data for Zn, In, Sn, Tl, Pb, and Bi in 16 samples…
Isotopic ratios are keys to understanding the origin and early evolution of the solar system in the context of Galactic nucleosynthesis. The large range of measured $^{14}$N/$^{15}$N isotopic ratios in the solar system reflects distinct reservoirs of nitrogen whose origins remain to be determined. We have directly measured a C$^{14}$N/C$^{15}$N abundance ratio of 323$\pm$30 in the disk orbiting the nearby young star TW Hya. This value, which is in good agreement with nitrogen isotopic ratios measured for prestellar cores, likely reflects the primary present-day reservoir of nitrogen in the sol…
Understanding the origin of life-essential volatiles like N in the Solar System and beyond is critical to evaluate the potential habitability of rocky planets. Whether the inner Solar System planets accreted these volatiles from their inception or had an exogenous delivery from the outer Solar System is, however, not well understood. Using previously published data of nucleosynthetic anomalies of Ni, Mo, W and Ru in iron meteorites along with their 15N-14N ratios, here we show that the earliest formed protoplanets in the inner and outer protoplanetary disk accreted isotopically distinct N. Whi…
Meteoritic studies of solar system objects show evidence of nucleosynthetic heterogeneities that are inherited from small presolar grains (< 10 $μ$m) formed in stellar environments external to our own. The initial distribution and subsequent evolution of these grains are currently unconstrained. Using 3D, gas-dust simulations, we find that isotopic variations on the order of those observed in the solar system can be generated and maintained by drag and viscosity. Small grains are dragged radially outwards without size/density sorting by viscous expansion and backreaction, enriching the outer d…
Ultrarefractory (UR) phases in CAIs could have formed at higher T compared to common CAI minerals and thus they potentially provide constraints on very high-T processes in the solar nebula. We report a detailed characterization of an UR phase davisite bearing CAI from a reduced type CV chondrite. Absence of secondary iron- and/or alkali-rich phases and occurrence of LIME olivine indicate that primitive chemical and isotopic compositions are preserved in the CAI. Davisite occur only in one lithological unit that consists of three chemically and isotopically distinct parts: i) $^{16}$O-poor regi…
Earth's volatile elements (H, C, and N) are essential to maintaining habitable conditions for metazoans and simpler life forms. However, identifying the sources (comets, meteorites, and trapped nebular gas) that supplied volatiles to Earth is not straightforward because secondary processes like mantle degassing, crustal recycling, and escape to space modified the composition of the atmosphere. Here, we review two complementary approaches to investigate the origin of Earth's atmosphere and oceans. The geochemical approach uses volatile element abundances and isotopic compositions to identify th…
Isotopic ratios provide a powerful tool for understanding the origins of materials, including the volatile and refractory matter within solar system bodies. Recent high sensitivity observations of molecular isotopologues, in particular with ALMA, have brought us new information on isotopic ratios of hydrogen, carbon, nitrogen and oxygen in star and planet forming regions as well as the solar system objects. Solar system exploration missions, such as Rosetta and Cassini, have given us further new insights. Meanwhile, the recent development of sophisticated models for isotope chemistry including…
Pebbles of millimeter sizes are abundant in protoplanetary discs around young stars. Chondrules inside primitive meteorites - formed by melting of dust aggregate pebbles or in impacts between planetesimals - have similar sizes. The role of pebble accretion for terrestrial planet formation is nevertheless unclear. Here we present a model where inwards-drifting pebbles feed the growth of terrestrial planets. The masses and orbits of Venus, Earth, Theia (which later collided with the Earth to form the Moon) and Mars are all consistent with pebble accretion onto protoplanets that formed around Mar…
Oxygen isotope fractionation in the Martian atmosphere induced by CO$_2$ photolysis and O$_3$ formation
Earth-Life Science Institute, Institute of Science Tokyo（地球生命研究所，东京科学大学）；Department of Earth and Space Sciences, University of Washington（华盛顿大学地球与空间科学系）；Department of Geophysics, Graduate School of Science, Tohoku University（东北大学理学研究科地球物理学科）；Department of Complexity Science and Engineering, Graduate School of Frontier Sciences, The University of Tokyo（东京大学前沿科学研究生院复杂科学与工程系）；Instituto de Astrofísica de Andalucía, CSIC（安达卢西亚天体物理研究所，西班牙国家科学研究委员会）；Research Center for Advanced Science and Technology, The University of Tokyo（东京大学先进科学技术研究中心）；Department of Earth and Planetary Sciences, School of Science, Institute of Science Tokyo（东京科学大学理学院地球行星科学系）；Faculty of Environment and Information Studies, Keio University（庆应义塾大学环境信息学部）
[Abridged] We present an extensive suite of terrestrial planet formation simulations that allows quantitative analysis of the stochastic late stages of planet formation. We quantify the feeding zone width, Delta a, as the mass-weighted standard deviation of the initial semi-major axes of the planetary embryos and planetesimals that make up the final planet. The size of a planet's feeding zone in our simulations does not correlate with its final mass or semi-major axis, suggesting there is no systematic trend between a planet's mass and its volatile inventory. Instead, we find that the feeding …
Isotopic Evidence for a Cold and Distant Origin of the Interstellar Object 3I/ATLAS
NASA Goddard Space Flight Center（美国国家航空航天局戈达德太空飞行中心）；Catholic University of America（天主教大学）；American University（美国大学）；European Space Agency（欧洲空间局）；Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）；Observatoire de Paris, Université PSL, CNRS, Sorbonne Université, Université Paris Cité, CY Cergy Paris Université（巴黎天文台，PSL大学，法国国家科学研究中心，索邦大学，巴黎西岱大学，塞吉-蓬图瓦兹大学）
Late infall of molecular cloud material reshaped the outer Solar System
Centre for Star and Planet Formation, Globe Institute, University of Copenhagen（哥本哈根大学环球学院恒星与行星形成中心）；School of Earth Sciences, University of Bristol（布里斯托大学地球科学学院）
Chondrules represent one of the best probes of the physical conditions and processes acting in the early solar nebula. Proposed chondrule formation models are assessed based on their ability to match the meteoritic evidence, especially experimental constraints on their thermal histories. The model most consistent with chondrule thermal histories is passage through shock waves in the solar nebula. Existing models of heating by shocks generally yield a good first-order approximation to inferred chondrule cooling rates. However, they predict prolonged heating in the pre-shock region, which would …
Heating by short-lived radioisotopes (SLRs) such as aluminum-26 and iron-60 fundamentally shaped the thermal history and interior structure of Solar System planetesimals during the early stages of planetary formation. The subsequent thermo-mechanical evolution, such as internal differentiation or rapid volatile degassing, yields important implications for the final structure, composition and evolution of terrestrial planets. SLR-driven heating in the Solar System is sensitive to the absolute abundance and homogeneity of SLRs within the protoplanetary disk present during the condensation of the…
Volatile compositions of asteroids provide information on the Solar System history and the origins of Earth's volatiles. Visible to near-infrared observations at wavelengths of $<2.5\ {\rm μm}$ have suggested a genetic link between outer main belt asteroids located at $2.5$-$4\ {\rm au}$ and carbonaceous chondrite meteorites (CCs) that show isotopic similarities to volatile elements on Earth. However, recent longer wavelength data for large outer main belt asteroids show $3.1\ {\rm μm}$ absorption features of ammoniated phyllosilicates that are absent in CCs and cannot easily form from materia…
We review the state of knowledge on the origin of Earth's water. Empirical constraints come from chemical and isotopic measurements of solar system bodies and of Earth itself. Dynamical models have revealed pathways for water delivery to Earth during its formation; most are anchored to specific models for terrestrial planet formation. Meanwhile, disk chemical models focus on determining how the isotopic ratios of the building blocks of planets varied as a function of radial distance and time, defining markers of material transported along those pathways. Carbonaceous chondrite meteorites -- re…
With approximately one ninth of Earth's mass, Mars is widely considered to be a stranded planetary embryo that never became a fully-grown planet. A currently popular planet formation theory predicts that Mars formed near Earth and Venus and was subsequently scattered outwards to its present location. In such a scenario, the compositions of the three planets are expected to be similar to each other. However, bulk elemental and isotopic data for martian meteorites demonstrate that key aspects of Mars' composition are markedly different from that of Earth. This suggests that Mars formed outside o…
We have conducted a NanoSIMS-based search for presolar material in samples recently returned from C-type asteroid Ryugu as part of JAXA's Hayabusa2 mission. We report the detection of all major presolar grain types with O- and C-anomalous isotopic compositions typically identified in carbonaceous chondrite meteorites: 1 silicate, 1 oxide, 1 O-anomalous supernova grain of ambiguous phase, 38 SiC, and 16 carbonaceous grains. At least two of the carbonaceous grains are presolar graphites, whereas several grains with moderate C isotopic anomalies are probably organics. The presolar silicate was lo…
