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arXiv 2012.01853eess.SYcs.SY
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准二维锂离子电池电化学模型的结构可辨识性

Structural Identifiability of a Pseudo-2D Li-ion Battery Electrochemical Model

Ross Drummond, Stephen R. Duncan

摘要:

对快速充电和优化电池设计的需求不断增长,这引发了人们对锂离子电池电化学模型的极大兴趣。然而,估计这些模型的参数值仍然是一个重大挑战。在本文中,结构可识别性分析被施加到伪二维锂离子电化学电池模型,可以被认为是一个线性化和解耦形式的基准Doyle-Fuller-Newman模型。从阻抗函数的检查,它表明,该模型是唯一的参数化由21个参数,是电化学参数的组合,如电导率和扩散系数。然后建立了这些参数的参数估计问题的适定性。通过识别可以从数据中唯一识别的参数集,该结果可以导致关于电池内部状态的更现实的预测。

英文摘要:

Growing demand for fast charging and optimised battery designs is fuelling significant interest in electrochemical models of Li-ion batteries. However, estimating parameter values for these models remains a major challenge. In this paper, a structural identifiability analysis was applied to a pseudo-2D Li-ion electrochemical battery model that can be considered as a linearised and decoupled form of the benchmark Doyle-Fuller-Newman model. From an inspection of the impedance function, it was shown that this model is uniquely parametrised by 21 parameters, being combinations of the electrochemical parameters like the conductivities and diffusion coefficients. The well-posedness of the parameter estimation problem with these parameters was then established. This result could lead to more realistic predictions about the internal state of the battery by identifying the parameter set that can be uniquely identified from the data.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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