Immiscible fluid-fluid displacement in porous media is of great importance in many engineering applications, such as enhanced oil recovery, agricultural irrigation, and geologic CO2 storage. Fingering phenomena, induced by the interface instability, are commonly encountered during displacement processes and somehow detrimental since such hydrodynamic instabilities can significantly reduce displacement efficiency. In this study, we report a possible adjustment in pore geometry which aims to suppress the capillary fingering in porous media with hierarchical structures. Through pore-scale simulations and theoretical analysis, we demonstrate and quantify combined effects of wettability and hierarchical geometry on displacement patterns, showing a transition from fingering to compact mode. Our results suggest that with a higher porosity of the 2nd-order porous structure, the displacement can keep compact across a wider range of wettability conditions. Combined with our previous work on viscous fingering in such media, we can provide a complete insight into the fluid-fluid displacement control in hierarchical porous media, across a wide range of flow conditions from capillary- to viscous-dominated modes. The conclusions of this work can benefit the design of microfluidic devices, as well as tailoring porous media for better fluid displacement efficiency at the field scale.
The capillary flow of a ferrofluid in a single cylindrical capillary tube and through a sandy porous medium under the action of a non-uniform magnetic field is studied experimentally. The dynamics of the capillary rise and the static case have been considered. It has been shown that the non-uniform magnetic field with upward directed gradient accelerates the capillary rise; contrary, the non-uniform magnetic field with downward directed gradient decelerates the capillary rise. Time dependences of the ferrofluid height and maximum reachable height of ferrofluid have been analyzed. The method of…
Flood front is the jump interface where fluids distribute discontinuously, whose interface condition is the theoretical basis of a mathematical model of the multiphase flow in porous medium. The conventional interface condition at the jump interface is expressed as the continuous Darcy velocity and fluid pressure (named CPVCM). This paper has inspected it via the studying the water-oil displacement in one dimensional reservoir with considering capillary pressure but ignoring the compressibility and gravity. It is proved theoretically that the total Darcy velocity and total pressure (defined by…
Immiscible fluids flowing at high capillary numbers in porous media may be characterized by an effective viscosity. We demonstrate that the effective viscosity is well described by the Lichtenecker-Rother equation. The exponent $α$ in this equation takes either the value 1 or 0.6 in two- and 0.5 in three-dimensional systems depending on the pore geometry. Our arguments are based on analytical and numerical methods.
Hypothesis Control of capillary flow through porous media has broad practical implications. However, achieving accurate and reliable control of such processes by tuning the pore size or by modification of interface wettability remains challenging. Here we propose that the flow of liquid by capillary penetration can be accurately adjusted by tuning the geometry of porous media and develop numerical method to achieve this. Methodologies On the basis of Darcys law, a general framework is proposed to facilitate the control of capillary flow in porous systems by tailoring the geometric shape of por…
Capillary energy barriers have important consequences for immiscible fluid flow in porous media. We derive time-and-space averaging theory to account for non-equilibrium behavior and understand the role of athermal capillary fluctuations in the context of their relationship to larger scale phenomenological equations. The formulation resolves several key challenges associated with two-fluid flow in porous media: (1) geometric and thermodynamic quantities are constructed as smooth functions of time based on time-and space averages; (2) averaged thermodynamics are developed for films; (3) multi-s…
The problem of capillary transport in fibrous porous materials at low levels of liquid saturation has been addressed. It has been demonstrated, that the process of liquid spreading in this type of porous materials at low saturation can be described macroscopically by a similar super-fast, non-linear diffusion model as that, which had been previously identified in experiments and simulations in particulate porous media. The macroscopic diffusion model has been underpinned by simulations using a microscopic network model. The theoretical results have been qualitatively compared with available ex…
Liquids in oil-bearing porous media assume complex shapes that depend on the reservoir characteristics and the wetting properties of the liquid. The wide variation in the geometry of rock formations makes it difficult to accurately predict the capillary pressure of small volumes of liquid and hence the likelihood of being able to move it. Here we consider the situation in which a small volume of liquid surrounds an upright cylinder on a flat substrate and predict the shape that the liquid takes and its capillary pressure. We validate our predictions by comparing with Surface Evolver simulation…
The anomalous dynamics of capillary rise in a porous medium discovered experimentally more than a decade ago (Delker et al., Phys. Rev. Lett. 76 (1996) 2902) is described. The developed theory is based on considering the principal modes of motion of the menisci that collectively form the wetting front on the Darcy scale. These modes, which include (i) dynamic wetting mode, (ii) threshold mode and (iii) interface de-pinning process, are incorporated into the boundary conditions for the bulk equations formulated in the regular framework of continuum mechanics of porous media, thus allowing one t…
We show that during evaporation of a pore network, liquid can refill the gas occupied pores, snapping off a gas bubble, which then moves to a stable configuration. This phenomenon is induced by the capillary instability due to the wettability heterogeneity of the pore network and has a much smaller time scale as compared to the evaporation process. The capillary instability induced liquid refilling and bubble movement are explained in detail based on the analysis of the images obtained from the visualization experiment. The capillary valve effect, which hinders the movement of the gas-liquid i…
Bundle-of-tubes model was previously used to understand the flow behaviour in a porous medium. The interacting nature of the pores within a porous medium can be well depicted by an interacting capillary model. However, the arrangement of pores is crucial in understanding the flow behaviour in an interacting capillary system, which also leads to different governing equations of spontaneous imbibition. To this end, in the present work, we first develop a generalized one-dimensional lubrication approximation model to predict the imbibition behaviour in an interacting multi-capillary system. Using…
The migration of liquids in porous media, such as sand, has been commonly considered at high saturation levels with liquid pathways at pore dimensions. In this letter we reveal a low saturation regime observed in our experiments with droplets of extremely low volatility liquids deposited on sand. In this regime the liquid is mostly found within the grain surface roughness and in the capillary bridges formed at the contacts between the grains. The bridges act as variable-volume reservoirs and the flow is driven by the capillary pressure arising at the wetting front according to the roughness le…
This paper discusses the convective heat transfer enhancement of non-condensing slug flows by using phase separation for local liquid circulations through a porous-tube insert. Numerical simulations were carried out to study the air-water slug flow and heat transfer without phase change (boiling and condensation) in a vertical upward flow. The governing equations of two-phase flow and heat transfer were numerically solved using the Volume of Fluid-Continuum Surface Force (VOF-CSF) method in a two-dimensional axisymmetric computational domain. The rear end (exit) of the porous tube was open to …
We report a local analysis of the flow of foams in two dimensional heterogeneous model porous media. Pressure measurements are combined with direct observation in order to determine simultaneously the effective viscosity and the fraction of trapped gas. Experiments are conducted in the low-quality regime, in a large range of capillary numbers and relative gas flow rates. The effective viscosity is very high (up to a few thousands times that of water) at low capillary numbers and rheology can be described by a decreasing power-law function of the capillary number of exponent ranging from -1 to …
This is a computational study of gravity-driven fingering instabilities in unsaturated porous media. The governing equations and corresponding numerical scheme are based on the work of Nieber et al. [Ch. 23 in Soil Water Repellency, eds. C. J. Ritsema and L. W. Dekker, Elsevier, 2003] in which non-monotonic saturation profiles are obtained by supplementing the Richards equation with a non-equilibrium capillary pressure-saturation relationship, as well as including hysteretic effects. The first part of the study takes an extensive look at the sensitivity of the finger solutions to certain key p…
We present a theoretical and experimental investigation of slow drainage in porous media with a gradient in the grains size (and hence in the typical pores' throats), in an external gravitational field. We mathematically show that such structural gradient and external force have a similar effect on the obtained drainage patterns, when they stabilise the invasion front. With the help of a newly introduced experimental set-up, based on the 3D-print of transparent porous matrices, we illustrate this equivalence, and extend it to the case where the front is unstable. We also present some invasion-…
Liquid bridges are commonly encountered in nature and the liquid transfer induced by their rupture are widely used in various industrial applications. In this work, with the focus on the porous tip, we studied the impacts of capillary effects on the liquid transfer induced by the rupture through numerical simulations. To depict the capillary effects of a porous tip, a time scale ratio, R_T, is proposed to compare the competing mechanisms of spontaneous imbibitiona and external drag. In terms of R_T, we then develop a theoretical model for estimating the liquid retention ratio considering the g…
In this paper we formulate and test numerically a fully-coupled discontinuous Galerkin (DG) method for incompressible two-phase flow with discontinuous capillary pressure. The spatial discretization uses the symmetric interior penalty DG formulation with weighted averages and is based on a wetting-phase potential / capillary potential formulation of the two-phase flow system. After discretizing in time with diagonally implicit Runge-Kutta schemes the resulting systems of nonlinear algebraic equations are solved with Newton's method and the arising systems of linear equations are solved efficie…
We study three different time integration methods for a dynamic pore network model for immiscible two-phase flow in porous media. Considered are two explicit methods, the forward Euler and midpoint methods, and a new semi-implicit method developed herein. The explicit methods are known to suffer from numerical instabilities at low capillary numbers. A new time-step criterion is suggested in order to stabilize them. Numerical experiments, including a Haines jump case, are performed and these demonstrate that stabilization is achieved. Further, the results from the Haines jump case are consisten…
Immiscible two-phase flow in porous media with mixed wet conditions was examined using a capillary fiber bundle model, which is analytically solvable, and a dynamic pore network model. The mixed wettability was implemented in the models by allowing each tube or link to have a different wetting angle chosen randomly from a given distribution. Both models showed that mixed wettability can have significant influence on the rheology in terms of the dependence of the global volumetric flow rate on the global pressure drop. In the capillary fiber bundle model, for small pressure drops when only a sm…
We present pore-scale simulations of two-phase flows in a reconstructed fibrous porous layer. The three dimensional microstructure of the material, a fuel cell gas diffusion layer, is acquired via X-ray computed tomography and used as input for lattice Boltzmann simulations. We perform a quantitative analysis of the multiphase pore-scale dynamics and we identify the dominant fluid structures governing mass transport. The results show the existence of three different regimes of transport: a fast inertial dynamics at short times, characterised by a compact uniform front, a viscous-capillary regi…
We present measurements on the spontaneous imbibition (capillary rise) of water, a linear hydrocarbon (n-C16H34) and a liquid crystal (8OCB) into the pore space of monolithic, nanoporous Vycor glass (mean pore radius 5 nm). Measurements on the mass uptake of the porous hosts as a function of time, m(t), are in good agreement with the Lucas-Washburn square root of time prediction, typical of imbibition of liquids into porous hosts. The relative capillary rise velocities scale as expected from the bulk fluid parameters.
Continuum models of porous media use macroscopic parameters and state variables to capture essential features of pore-scale physics. We propose a macroscopic property "accessivity" ($α$) to characterize the network connectivity of different sized pores in a porous medium, and macroscopic state descriptors "radius-resolved saturations" ($ψ_w(F),ψ_n(F)$) to characterize the distribution of fluid phases within. Small accessivity ($α\to0$) implies serial connections between different sized pores, while large accessivity ($α\to1$) corresponds to more parallel arrangements, as the classical capillar…
Droplet mobility under shear flows is important in a wide range of engineering applications, e.g., fog collection, and self-cleaning surfaces. For structured surfaces to achieve superhydrophobicity, the removal of stains adhered within the microscale surface features strongly determines the functional performance and durability. In this study, we numerically investigate the shear-induced mobility of the droplet trapped within porous surfaces. Through simulations covering a wide range of flow conditions and porous geometries, three droplet mobility modes are identified, i.e., the stick-slip, cr…
We investigate a two-dimensional network simulator capable of modeling different time dependencies in two-phase drainage displacements. In particular, we focus on the temporal evolution of the pressure due to capillary and viscous forces and the time dependence of the interface between the two liquids. The dynamics of the capillary effect are taken into account and we report on high accuracy pressure measurements. Moreover, the simulator includes important features in drainage, like burst dynamics of the invading fluid and simultaneous flow of two liquids in a section of a tube. The validity o…
A simple model of two-phase flow in porous media is presented. A connection is made to statistical mechanics by applying capillary power as a constraint. Stochastic sampling is then used to test the validity of this approach. Good agreement is found between stochastic sampling and time stepping for flow-rates above a transition value.
We have simulated the temporal evolution of pressure due to capillary and viscous forces in two-phase drainage in porous media. We analyze our result in light of macroscopic flow equations for two-phase flow. We also investigate the effect of the trapped clusters on the pressure evolution and on the effective permeability of the system. We find that the capillary forces play an important role during the displacements for both fast and slow injection rates and both when the invading fluid is more or less viscous than the defending fluid. The simulations are based on a network simulator modeling…
In this paper, we consider a non-local (in time) two-phase flow model. The non-locality is introduced through the wettability alteration induced dynamic capillary pressure function. We present a monotone fixed-point iterative linearization scheme for the resulting non-standard model. The scheme treats the dynamic capillary pressure functions semi-implicitly and introduces an $L$-scheme type \cite{List2016, Radu2015} stabilization term in the pressure as well as the transport equations. We prove the convergence of the proposed scheme theoretically under physically acceptable assumptions and ver…
We use confocal microscopy to directly visualize the simultaneous flow of both a wetting and a non-wetting fluid through a model three-dimensional (3D) porous medium. We find that, for small flow rates, both fluids flow through unchanging, distinct, connected 3D pathways; in stark contrast, at sufficiently large flow rates, the non-wetting fluid is broken up into discrete ganglia. By performing experiments over a range of flow rates, using fluids of different viscosities, and with porous media having different geometries, we show that this transition can be characterized by a state diagram tha…
We demonstrate through numerical simulations and a mean field calculation that immiscible two-phase flow in a porous medium behaves effectively as a Bingham viscoplastic fluid. This leads to a generalized Darcy equation where the volumetric flow rate depends quadratically on an excess pressure difference in the range of flow rates where the capillary forces compete with the viscous forces. At higher rates, the flow is Newtonian.
During evaporation in porous media, two types of corner films are distinguished. A continuous corner film is connected to the bulk liquid, while a discontinuous one is not. To disclose their effects on evaporation in porous media, a pore network model with both continuous and discontinuous corner films is developed, which considers the capillary and viscous forces as well as the effects of corner films on the threshold pressures of pores. The capillary valve effect induced by the sudden geometrical expansion between the small and large pores is also taken into account in the model. The develop…
We show that when a non-wetting fluid drains a stratified porous medium at sufficiently small capillary numbers Ca, it flows only through the coarsest stratum of the medium; by contrast, above a threshold Ca, the non-wetting fluid is also forced laterally, into part of the adjacent, finer strata. The spatial extent of this partial invasion increases with Ca. We quantitatively understand this behavior by balancing the stratum-scale viscous pressure driving the flow with the capillary pressure required to invade individual pores. Because geological formations are frequently stratified, we antici…
We use confocal microscopy to directly visualize the formation and complex morphologies of trapped non-wetting fluid ganglia within a model 3D porous medium. The wetting fluid continues to flow around the ganglia after they form; this flow is characterized by a capillary number, Ca. We find that the ganglia configurations do not vary for small Ca; by contrast, as Ca is increased above a threshold value, the largest ganglia start to become mobilized and are ultimately removed from the medium. By combining our 3D visualization with measurements of the bulk transport, we show that this behavior c…
Direct numerical simulations are presented for a porous media model consisting of two immiscible fluids, an invading and defending phase, in a two-dimensional micro-geometry filled with randomly sized and randomly distributed cylinders. First, interface instability and penetration modes are studied when varying the wetting features of a single pore in the porous medium. It is found that the displacement patterns not only change with the capillary number, as previously observed, but also are a function of the contact angle, even for a viscosity ratio of unity. This is an important conclusion su…
We report and discuss, by means of pore-scale numerical simulations, the possibility of achieving a directional-dependent two-phase flow behaviour during the process of invasion of a viscous fluid into anisotropic porous media with controlled design. By customising the pore-scale morphology and heterogeneities with the adoption of anisotropic triangular pillars distributed with quenched disorder, we observe a substantially different invasion dynamics according to the direction of fluid injection relative to the medium orientation, that is depending if the triangular pillars have their apex ori…
Although capillary and permeability are the two most important physical properties controlling fluid distribution and flow in nature, the interconnectivity function between them was a pressing challenge. Because knowing permeability leads to determining capillary pressure. Geodynamics (e.g., subsurface water, CO2 sequestration) and organs (e.g., plants, blood vessels) depend on capillary pressure and permeability. The first determines how far the fluid can reach, while the second determines how fast the fluid can flow in porous media. They are also vital to designing synthetic materials and mi…
We present in detail a set of algorithms to carry out fluid displacements in a dynamic pore-network model of immiscible two-phase flow in porous media. The algorithms are general and applicable to regular and irregular pore networks in two and three dimensions with different boundary conditions. Implementing these sets of algorithms, we describe a dynamic pore-network model and reproduce some of the fundamental properties of both the transient and steady-state two-phase flow. During drainage displacements, we show that the model can reproduce the flow patterns corresponding to viscous fingerin…
In this paper we consider a multiscale phase-field model for capillarity-driven flows in porous media. The presented model constitutes a reduction of the conventional Navier-Stokes-Cahn-Hilliard phase-field model, valid in situations where interest is restricted to dynamical and equilibrium behavior in an aggregated sense, rather than a precise description of microscale flow phenomena. The model is based on averaging of the equation of motion, thereby yielding a significant reduction in the complexity of the underlying Navier-Stokes-Cahn-Hilliard equations, while retaining its macroscopic dyna…
We perform more than 6000 steady-state simulations with a dynamic pore network model, corresponding to a large span in viscosity ratios and capillary numbers. From these simulations, dimensionless quantities such as relative permeabilities, residual saturations, mobility ratios and fractional flows are computed. Relative permeabilities and residual saturations show many of the same qualitative features observed in other experimental and modeling studies. However, while other studies find that relative permeabilities converge to straight lines at high capillary numbers we find that this is not …
Capillary fingering is a displacement process that can occur when a non-wetting fluid displaces a wetting fluid from a homogeneous disordered porous medium. Here, we investigate how this process is influenced by a pore size gradient. Using microfluidic experiments and computational pore-network models, we show that the non-wetting fluid displacement behavior depends sensitively on the direction and the magnitude of the gradient. The fluid displacement depends on the competition between a pore size gradient and pore-scale disorder; indeed, a sufficiently large gradient can completely suppress c…
We present an experimental and numerical study of immiscible two-phase flow in 3-dimensional (3D) porous media to find the relationship between the volumetric flow rate ($Q$) and the total pressure difference ($ΔP$) in the steady state. We show that in the regime where capillary forces compete with the viscous forces, the distribution of capillary barriers at the interfaces effectively creates a yield threshold, making the fluids reminiscent of a Bingham viscoplastic fluid in the porous medium, introducing a threshold pressure $P_t$. In this regime, $Q$ depends quadratically on an excess press…
Wetting phenomena play a key role in flows through porous media. Relative permeability and capillary pressure-saturation functions show a high sensitivity to wettability, which has different definitions at the continuum- and pore-scale. At the continuum-scale, the state of wetting is defined as Amott-Harvey or USBM (United States Bureau of Mines) by capillary pressure drainage and imbibition cycles. At the pore-scale, the concept of contact angle is used, which until recently was not experimentally possible to determine within an opaque porous medium. Recent progress on measurements of pore-sc…
Detailed understanding of the coupling between fluid flow and solid deformation in porous media is crucial for the development biomedical devices and novel energy technologies relating to a wide range of geological and biological processes. Well established models based on poroelasticity theory exist for describing coupled fluid-solid mechanics. However, these models are not adapted to describe systems with multiple fluid phases or 'hybrid-scale' systems containing both solid-free regions and porous matrices. To address this problem, we present a novel computational fluid dynamics approach bas…
In the above paper the authors treat the natural convection boundary layer flow in a Darcy-Brinkman-Forchheimer porous medium. In the energy equation the radiation effect has been taken into account. A two-parameter perturbation method is used for the solution of the equations. The first order results are presented in tables and figures. This is an interesting work but there are some weak points which are presented below:
Wetting of surfaces with porous coating is relevant for a wide variety of technical applications, such as printing technologies and heat transfer enhancement. Imbibition and evaporation of liquids on surfaces covered with porous layers are responsible for significant improvement of cooling efficiency during drop impact cooling and flow boiling on such surfaces. Up to now, no reliable model exists which is able to predict the kinetics of imbibition coupled with evaporation on surfaces with porous coatings. In this work we consider one of possible mechanisms of imbibition on a substrate covered …
Porous materials are used in many fields, including energy industry, agriculture, medical industry, etc. The generation of digital porous media facilitates the fabrication of real porous media and the analysis of their properties. The past random digital porous media generation methods are unable to generate a porous medium with a specific permeability. A new method is proposed in the present study, which can generate the random packed isotropic porous media with specific porosity and permeability. Firstly, the process of generating the random packed isotropic porous media is detailed. Secondl…
