Dip-coating is a common technique used to cover a solid surface with a thin liquid film, the thickness of which was successfully predicted by the theory developed by Landau & Levich and Derjaguin in the 1940's. In this work, we present an extension of their theory to the case where the dipping bath contains two immiscible liquids, one lighter than the other, resulting in the entrainment of two thin films on the substrate. We report how the thicknesses of the coated films depend on the capillary number, on the ratios of the properties of the two liquids and on the relative thickness of the upper fluid layer in the bath. We also show that the liquid/liquid and liquid/gas interfaces evolve independently from each other as if only one liquid was coated, except for a very small region where their separation falls quickly to its asymptotic value and the shear stresses at the two interfaces peak. Interestingly, we find that the final coated thicknesses are determined by the values of these maximum shear stresses.
In this letter, we describe the capillary sorting of particles by size based on dip coating. A substrate withdrawn from a liquid bath entrains a coating whose thickness depends on the withdrawal speed and the liquid properties. If the coating material contains particles, they will only be entrained when the viscous force pulling them with the substrate overcomes the opposing capillary force at the deformable meniscus. This force threshold occurs at different liquid thicknesses for particles of different sizes. Here, we show that this difference can be used to separate small particles from a mi…
Dip-coating consists in withdrawing a substrate from a bath to coat it with a thin liquid layer. This process is well-understood for homogeneous fluids, but heterogeneities such as particles dispersed in the liquid lead to more complex situations. Indeed, particles introduce a new length scale, their size, in addition to the thickness of the coating film. Recent studies have shown that at first order, the thickness of the coating film for monodisperse particles can be captured by an effective capillary number based on the viscosity of the suspension, providing that the film is thicker than the…
The displacement of a suspension of particles by an immiscible fluid in a capillary tube or in a porous media is a canonical configuration that finds application in a large number of natural and industrial applications, including water purification, dispersion of colloids and microplastics, coating and functionalization of tubings. The influence of particles dispersed in the fluid on the interfacial dynamics and on the properties of the liquid film left behind remain poorly understood. Here, we study the deposition of a coating film on the walls of a capillary tube induced by the translation o…
Withdrawing a plate from a suspension leads to the entrainment of a coating layer of fluid and particles on the solid surface. In this article, we study the Landau-Levich problem in the case of a suspension of non-Brownian particles at moderate volume fraction $10\% < ϕ< 41\%$. We observe different regimes depending on the withdrawal velocity $U$, the volume fraction of the suspension $ϕ$, and the diameter of the particles $2\,a$. Our results exhibit three coating regimes. (i) At small enough capillary number $Ca$, no particles are entrained, and only a liquid film coats the plate. (ii) At lar…
We studied the dynamics of a liquid contact line receding on a hydrophobic soft gel (SBS-paraffin). In order to realize a well-defined geometry with an accurate control of velocity, a dip-coating setup was implemented. Provided that the elastic modulus is small enough, a significant deformation takes place near the contact line, which in turn drastically influences the wetting behaviour. Depending on the translation velocity of the substrate, the contact line exhibits different regimes of motions. Continuous motions are observed at high and low velocities, meanwhile two types of stick-slip mot…
An object withdrawn from a liquid bath is coated with a thin layer of liquid. Along with the liquid, impurities such as particles present in the bath can be transferred to the withdrawn substrate. Entrained particles locally modify the thickness of the film, hence altering the quality and properties of the coating. In this study, we show that it is possible to entrain the liquid alone and avoid contamination of the substrate, at sufficiently low withdrawal velocity in diluted suspensions. Using a model system consisting of a plate exiting a liquid bath, we observe that particles can remain tra…
When a solid substrate is withdrawn from a bath of simple, partially wetting, nonvolatile liquid, one typically distinguishes two regimes, namely, after withdrawal the substrate is macroscopically dry or homogeneously coated by a liquid film. In the latter case, the coating is called a Landau-Levich film. Its thickness depends on the angle and velocity of substrate withdrawal. We predict by means of a numerical and analytical investigation of a hydrodynamic thin-film model the existence of a third regime. It consists of the deposition of a regular pattern of liquid ridges oriented parallel to …
Shear-driven arrest of dip-coating film entrainment
Eindhoven University of Technology（埃因霍温理工大学）；Sorbonne Université, CNRS and IUF, UMR 7190, Institut Jean Le Rond d’Alembert（索邦大学，法国国家科学研究中心及法国高等研究学院，UMR 7190，让·勒朗·达朗贝尔研究所）
When a plate is withdrawn from a liquid bath, either a static meniscus forms in the transition region between the bath and the substrate or a liquid film of finite thickness (a Landau-Levich film) is transferred onto the moving substrate. If the substrate is inhomogeneous, e.g., has a prestructure consisting of stripes of different wettabilities, the meniscus can be deformed or show a complex dynamic behavior. Here we study the free surface shape and dynamics of a dragged meniscus occurring for striped prestructures with two orientations, parallel and perpendicular to the transfer direction. A…
We consider the deposition of a film of viscous liquid on a flat plate being withdrawn from a bath, experimentally and theoretically. For any plate speed $U$, there is a range of ``thick'' film solutions whose thickness scales like $U^{1/2}$ for small $U$. These solutions are realized for a partially wetting liquid, while for a perfectly wetting liquid the classical Landau-Levich-Derjaguin (LLD) film is observed, whose thickness scales like $U^{2/3}$. The thick film is distinguished from the LLD film by a dip in its spatial profile at the transition to the bath. We calculate the phase diagram …
We study numerically the hydrodynamics of dip coating from a suspension and report a mechanism for colloidal assembly and pattern formation on smooth and uniform substrates. Below a critical withdrawal speed of the substrate, capillary forces required to deform the meniscus prevent colloidal particles from entering the coating film. Capillary forces are overcome by hydrodynamic drag only after a minimum number of particles organize in a close-packed formation within the meniscus. Once within the film, the formed assembly moves at nearly the withdrawal speed and rapidly separates from the next …
The jet wiping process is a cost-effective coating technique that uses impinging gas jets to control the thickness of a liquid layer dragged along a moving strip. This process is fundamental in various coating industries (mainly in hot-dip galvanizing) and is characterized by an unstable interaction between the gas jet and the liquid film that results in wavy final coating films. To understand the dynamics of the wave formation, we extend classic laminar boundary layer models for falling films to the jet wiping problem, including the self-similar integral boundary layer (IBL) and the weighted …
Accurate and computationally accessible models of liquid film flows allow for optimizing coating processes such as hot-dip galvanization and vertical slot-die coating. This paper extends the classic three-dimensional integral boundary layer (IBL) model for falling liquid films (FF) to account for a moving substrate (MS). We analyze the stability of the liquid films on vertically moving substrates in a linear and a nonlinear setting. In the linear analysis, we derive the dispersion relation and the temporal growth rates of an infinitesimal disturbance using normal modes and linearized governing…
Recent experiments on coating flows and liquid drop impact both demonstrate that wetting failures caused by air entrainment can be suppressed by reducing the ambient gas pressure. Here, it is shown that non-equilibrium effects in the gas can account for this behaviour, with ambient pressure reductions increasing the gas' mean free path and hence the Knudsen number $Kn$. These effects first manifest themselves through Maxwell slip at the gas' boundaries so that for sufficiently small $Kn$ they can be incorporated into a continuum model for dynamic wetting flows. The resulting mathematical model…
Thin-film flows of viscoelastic fluids are encountered in various industrial and biological settings. The understanding of thin viscous film flows in Newtonian fluids is very well developed, which for a large part is due to the so-called thin-film equation. This equation, a single partial differential equation describing the height of the film, is a significant simplification of the Stokes equation effected by the lubrication approximation which exploits the thinness of the film. There is no such established equation for viscoelastic fluid flows. Here we derive the thin-film equation for a sec…
This chapter illustrates how to apply continuation techniques in the analysis of a particular class of nonlinear kinetic equations that describe the time evolution through transport equations for a single scalar field like a densities or interface profiles of various types. We first systematically introduce these equations as gradient dynamics combining mass-conserving and nonmass-conserving fluxes followed by a discussion of nonvariational amendmends and a brief introduction to their analysis by numerical continuation. The approach is first applied to a number of common examples of variationa…
