We study a simple model for photoinduced electron transfer reactions for the case of many donor-acceptor pairs that are collectively and homogeneously coupled to a photon mode of a cavity. We describe both coherent and dissipative collective effects resulting from this coupling within the framework of a quantum optics Lindblad master equation. We introduce a method to derive an effective rate equation for electron transfer, by adiabatically eliminating donor and acceptor states and the cavity mode. The resulting rate equation is valid both for weak and strong coupling to the cavity mode, and describes electronic transfer through both the cavity coupled bright states and the uncoupled dark states. We derive an analytic expression for the instantaneous electron transfer rate that depends non-trivially on the time-varying number of pairs in the ground state. We find that under proper resonance conditions, and in the presence of an incoherent drive, reaction rates can be enhanced by the cavity. This enhancement persists, and can even be largest, in the weak light-matter coupling regime. We discuss how the cavity effect is relevant for realistic experiments.
The possibility to induce predetermined coherent quantum dynamics by controlling only the dissipative environmental parameters (such as temperature and pressure) is studied using the combined optimal control and environment engineering frameworks. As an example, we consider the problem of transforming an optically excited donor state into free charge carriers via intermediate higher-lying bridge state(s), with a view to solar energy conversion. In this context, vibrational bath engineering allows to promote fast, directional charge transfer and to suppress recombinative losses.
We propose a new scheme for solid-state photonic quantum computation in which trapped photons in optical cavities are taken as a quantum bit. Quantum gates can be realized by coupling the cavities with quantum dots through waveguides. The proposed scheme allows programmable and deterministic gate operations and the system can be scaled up to many quantum bits.
We propose a scheme to unconditionally entangle the internal states of atoms trapped in separate high finesse optical cavities. The scheme uses the technique of quantum reservoir engineering in a cascaded cavity QED setting, and for ideal (lossless) coupling between the cavities generates an entangled pure state. Highly entangled states are also shown to be possible for realizable cavity QED parameters and with nonideal coupling.
We propose a scheme for conditional implementation of a quantum phase gate by using distant atoms trapped in different optical cavities. Instead of direct interaction between atoms, the present scheme makes use of quantum interference of polarized photons decaying from the optical cavities to conditionally create the desired quantum phase gate between two distant atoms. The proposed scheme only needs linear optical elements and a two-fold coincidence detection, and are insensitive to the quantum noise. The scheme can be directly used to prepare any quantum state of many distant atoms.
The generation of quantum entanglement between phonons in photoirradiated remote electron-phonon systems is numerically studied. Upon excitation by a visible/ultraviolet laser pulse, the entanglement of electrons is immediately generated and that of phonons follows via electron-phonon interactions, i.e., the entanglement generation of phonons is a two-step process. Therefore, it is important to design the temporal properties of incident optical pulses in order to control the entanglement of electrons and/or phonons. These features are revealed by the quantum mutual information and the composit…
We show the possibility of noiseless amplification of an optical image in cavities containing a parametric oscillator. We consider a confocal ring cavity with plane mirrors and compare with the case of planar cavity. In the latter case the system operates with severe spatial limitations, while in the confocal case, there is the possibility of preserving the signal-to-noise ratio while amplifying uniformely the entire image.
We demonstrate that quantum information processing can be implemented with ions trapped in a far detuned optical cavity. For sufficiently large detuning the system becomes insensitive to cavity decay. Following recent experimental progress, this scheme can be implemented with currently available technology.
We present a composite optical cavity made of standard laser mirrors; the cavity consists of a suitable combination of stable and unstable cavities. In spite of its very open nature the composite cavity shows ray chaos, which may be either soft or hard, depending on the cavity configuration. This opens a new, convenient route for experimental studies of the quantum aspects of a chaotic wave field.
We propose a scheme for entangling the optical and microwave output modes of the respective cavities by using a micro mechanical resonator. The micro-mechanical resonator on one side is capacitively coupled to the microwave cavity and on the other side is coupled to a high finesses optical cavity. We then show how this continuous variable entanglement can be profitably used to teleport the non-Gaussian number state |1> and the superposition (|0>+|1>)/\surd2 from the microwave cavity output mode onto an output of optical cavity mode with fidelity much larger than the no-cloning limit.
We propose to produce entanglement by measuring the transmission of an optical cavity. Conditioned on the detection of a reflected photon, pairs of atoms in the cavity are prepared in maximally entangled states. The success probability depends on the cavity parameters, but high quality entangled states may be produced with a high probability even for cavities of moderate quality.
The output fields of a pair of coherently coupled nonlinear optical cavities are found to exhibit strong optical entanglement. For sufficiently strong coupling the quantum correlations become asynchronous providing a resource for quantum information protocols such as all-optical quantum memories. A straightforward experimental implementation applicable to whispering gallery mode resonators such as microtoroids is proposed.
To take existing quantum optical experiments and devices into more practical regimes requires the construction of robust, solid-state implementations. In particular, to observe the strong-coupling regime of atom-photon interactions requires very small cavities and large quality factors. Here we show that the slot-waveguide geometry recently introduced for photonic applications is also promising for quantum optical applications in the visible regime. We study diamond- and GaP-based slot-waveguide cavities (SWCs) compatible with diamond colour centres e.g. nitrogen-vacancy (NV) defect, and show …
In the framework of cavity QED, we propose a practical scheme to purify dynamically a bipartite entangled state using short chains of atoms coupled to high-finesse optical cavities. In contrast to conventional entanglement purification protocols, we avoid CNOT gates, thus reducing complicated pulse sequences and superfluous qubit operations. Our interaction scheme works in a deterministic way, and together with entanglement distribution and swapping, opens a route towards efficient quantum repeaters for long-distance quantum communication.
We present a thorough analysis of single atom detection using optical cavities. The large set of parameters that influence the signal-to-noise ratio for cavity detection is considered, with an emphasis on detunings, probe power, cavity finesse and photon detection schemes. Real device operating restrictions for single photon counting modules and standard photodiodes are included in our discussion, with heterodyne detection emerging as the clearly favourable technique, particularly for detuned detection at high power.
We propose a method to prepare entangled states and implement quantum computation with atoms in optical cavities. The internal state of the atoms are entangled by a measurement of the phase of light transmitted through the cavity. By repeated measurements an entangled state is created with certainty, and this entanglement can be used to implement gates on qubits which are stored in different internal degrees of freedom of the atoms. This method, based on measurement induced dynamics, has a higher fidelity than schemes making use of controlled unitary dynamics.
Quantum networks provide unique possibilities for resolving open questions on entanglement and promise innovative applications ranging from secure communication to scalable computation. While two quantum nodes coupled by a single channel are adequate for basic quantum communication tasks between two parties, fully functional large-scale quantum networks require a web-like architecture with multiply connected nodes. Efficient interfaces between network nodes and channels can be implemented with optical cavities. Using two optical fibre cavities coupled to one atom, we here realise a quantum net…
We present evidence of cavity quantum electrodynamics from a sparse density of strongly quantum-confined Pb-chalcogenide nanocrystals (between 1 and 10) approaching single-dot levels on moderately high-Q mesoscopic silicon optical cavities. Operating at important near-infrared (1500-nm) wavelengths, large enhancements are observed from devices and strong modifications of the QD emission are achieved. Saturation spectroscopy of coupled QDs is observed at 77K, highlighting the modified nanocrystal dynamics for quantum information processing.
A system consisting of two single-mode cavities spatially separated and connected by an optical fiber and multiple two-level atoms trapped in the cavities is considered. If the atoms resonantly and collectively interact with the local cavity fields but there is no direct interaction between the atoms, we show that an ideal quantum state transfer and highly reliable quantum swap, entangling, and controlled-Z gates can be deterministically realized between the distant cavities. We find that the operation of state transfer and swap, entangling, and controlled-Z gates can be greatly speeded up as …
We analyze the physics of accelerated particle detectors (such as atoms) crossing optical cavities. In particular we focus on the detector response as well as on the energy signature that the detectors imprint in the cavities. In doing so, we examine to what extent the usual approximations made in quantum optics in cavities (such as the single-mode approximation, or the dimensional reduction of 3+1D cavities to simplified 1+1D setups) are acceptable when the atoms move in relativistic trajectories. We also study the dependence of these approximations on the state of the atoms and the relativis…
Fabry-Perot interferometers have stimulated numerous scientific and technical applications ranging from high resolution spectroscopy over metrology, optical filters to interfaces of light and matter at the quantum limit and more. End facet machining of optical fibers has enabled the miniaturization of optical Fabry-Perot cavities. Integration with fiber wave guide technology allows for small yet open devices with favorable scaling properties including mechanical stability and compact mode geometry. These Fiber Fabry-Perot Cavities (FFPCs) are stimulating extended applications in many fields in…
We present a detailed experimental characterization of the spectral and spatial structure of the confined optical modes for oxide-apertured micropillar cavities, showing good-quality Hermite-Gaussian profiles, easily mode-matched to external fields. We further derive a relation between the frequency splitting of the transverse modes and the expected Purcell factor. Finally, we describe a technique to retrieve the profile of the confining refractive index distribution from the spatial profiles of the modes.
Erbium dopants in crystals exhibit highly coherent optical transitions well suited for solid-state optical quantum memories operating in the telecom band. Here we demonstrate coupling of erbium dopant ions in yttrium orthosilicate to a photonic crystal cavity fabricated directly in the host crystal using focused ion beam milling. The coupling leads to reduction of the photoluminescence lifetime and enhancement of the optical depth in microns-long devices, which will enable on-chip quantum memories.
