The breathing honeycomb lattice hosts a topologically non-trivial bulk phase due to the crystalline-symmetry of the system. Pseudospin-dependent edge states which emerge at the interface between trivial and non-trivial regions can be used for directional propagation of energy. Using the plasmonic metasurface as an example system, we probe these states in the near and far-field using a semi-analytical model. We give the conditions under which directionality is observed and show that it is source position dependent. By probing with circularly-polarized magnetic dipoles out of the plane, we first characterize modes along the interface in terms of the enhancement of source emission due to the metasurface. We then excite from the far-field with non-zero orbital angular momentum beams. The position dependent directionality holds true for all classical wave systems with a breathing honeycomb lattice. Our results show that a metasurface in combination with a chiral two-dimensional material could be used to guide light effectively on the nanoscale.
The nonlinear process of second harmonic generation (SHG) in monolayer (1L) transition metal dichalcogenides (TMD), like $WS_2$, strongly depends on the polarization state of the excitation light. Combining plasmonic nanostructures with $1L-WS_2$ by transferring it onto a plasmonic nanoantenna array, a hybrid metasurface is realized impacting the polarization dependency of its SHG. Here, we investigate how plasmonic dipole resonances affect the process of SHG in plasmonic-TMD hybrid metasurfaces by nonlinear spectroscopy. We show, that the polarization dependency is affected by the lattice str…
We review the latest theoretical advances in the application of the framework of Transformation Optics for the analytical description of deeply sub-wavelength electromagnetic phenomena. First, we present a general description of the technique, together with its usual exploitation for metamaterial conception and optimization in different areas of wave physics. Next, we discuss in detail the design of plasmonic metasurfaces, including the description of singular geometries which allow for broadband absorption in ultrathin platforms. Finally, we discuss the quasi-analytical treatment of plasmon-e…
The coupled light-matter modes supported by plasmonic metasurfaces can be combined with topological principles to yield subwavelength topological valley states of light. We give a systematic presentation of the topological valley states available for lattices of metallic nanoparticles: All possible lattices with hexagonal symmetry are considered, as well as valley states emerging on a square lattice. Several unique effects which have yet to be explored in plasmonics are identified, such as robust guiding, filtering and splitting of modes, as well as dual-band effects. We demonstrate these by m…
We investigate experimentally Third Harmonic Generation (THG) from plasmonic metasurfaces consisting of two-dimensional rectangular lattices of centrosymmetric gold nano-bars. By varying the incidence angle and the lattice period, we show how Surface Lattice Resonances (SLRs) at the involved wavelengths are the major contributors in determining the magnitude of the nonlinear effects. A further boost on THG is observed when we excite together more than one SLR, either at the same or at different frequencies. When such multiple resonances take place, interesting phenomena are observed, such as m…
Nonlinear metasurfaces based on coupling a locally enhanced plasmonic response to intersubband transitions of n-doped multi-quantum-wells (MQWs) have recently provided second-order susceptibilities orders of magnitude larger than any other nonlinear flat structure measured so far. Here, we present a comprehensive theory to characterize the electromagnetic response of nonlinear processes occurring in ultrathin MQW-based plasmonic metasurfaces, providing a homogeneous model that takes phase-matching at the unit-cell level and the influence of saturation and losses into account. In addition, the …
The heat-shielding properties of random metasurface, composed of spherical or spheroidal nanoparticles with random displacements and/or random deformation, were theoretically investigated using the finite difference time domain method. The effective coverage was defined using the total area of nanoparticles in the metasurface, and the robustness of the near-infrared light reflection against randomness was investigated. When the effective coverage was high, the near-infrared light reflection was reduced by at least 20% in both nanoparticle arrangement and shape randomness compared to the hexago…
We present the experimental realization of ordered arrays of hyper-doped silicon nanodisks, which exhibit a localized surface plasmon resonance. The plasmon is widely tunable in a spectral window between 2 and 5 $μ$m by adjusting the free carrier concentration between 10$^{20}$ and 10$^{21}$ cm$^{-3}$. We show that strong infrared light absorption can be achieved with all-silicon plasmonic metasurfaces employing nano-structures with dimensions as low as 100\,nm in diameter and 23 nm in height. Our numerical simulations show an excellent agreement with the experimental data and provide physical…
We study a plasmonic metasurface that supports pseudospin dependent edge states confined at a subwavelength scale, considering full electrodynamic interactions including retardation and radiative effects. The spatial symmetry of the lattice of plasmonic nanoparticles gives rise to edge states with properties reminiscent of the quantum spin Hall effect in topological insulators. However, unlike the spin-momentum locking characteristic of topological insulators, these modes are not purely unidirectional and their propagation properties can be understood by analysing the spin angular momentum of …
Laser printing with a spatial light modulator (SLM) has several advantages over conventional raster-writing and dot-matrix display (DMD) writing: multiple pixel exposure, high power endurance and existing software for computer generated holograms (CGH). We present a technique for the design and manufacturing of plasmonic metasurfaces based on ultrafast laser printing with an SLM. As a proof of principle, we have used this technique to laser print a plasmonic metalens as well as high resolution plasmonic color decorations. The high throughput holographic resonant laser printing (HRLP) approach …
We discuss the possibility of realizing utlrabroadband omnidirectional absorbers and angularly selective coherent thermal emitters based on properly patterned plasmonic metastructures. Instead of relying on resonant concentration effects that inherently limit the bandwidth, we base our design on the combination of two inherently nonresonant effects: plasmonic Brewster funneling and adiabatic plasmonic focusing. With this approach, we demonstrate compact, broadband absorption and emission spanning terahertz, infrared and optical frequencies, ideal for various energy and defense applications.
Acoustic vibrations at the nanoscale (GHz-THz frequencies) and their interactions with electrons, photons and other excitations are the heart of an emerging field in physics: nanophononics. The design of ultrahigh frequency acoustic-phonon transducers, with tunable frequency, and easy to integrate in complex systems is still an open and challenging problem for the development of acoustic nanoscopies and phonon lasers. Here we show how an optimized plasmonic metasurface can act as a high-frequency phonon transducer. We report pump-probe experiments in metasurfaces composed of an array of gold n…
Chiral response is of tremendous importance to many fields, such as analytical chemistry, polarization manipulation and biological sensing. Here, a chiral metasurface based on rectangular holes is systematically investigated. The results show that the chirality is closely related to the size and the orientation of resonance unit. It is found that the period of the structure is always smaller than the wavelength at which chirality appears, which will provide a good basis for the design of chiral structures. More importantly, the CD is highly sensitive to the orientation of resonance unit. By ad…
A local model of the dielectric response of a metal predicts that singular surfaces, such as sharp-edged structures, have a continuous absorption spectrum and extreme concentration of energy at the singularity. Here we show that nonlocality drastically alters this picture: the spectrum is now discrete and energy concentration, though still substantial, is greatly reduced.
Geometrical singularities in plasmonic metasurfaces have recently been proposed for the enhancement of light-matter interactions, owing to their broadband light-harvesting properties and extreme plasmon confinement. However, the large plasmon momenta thus achieved lead to failure of local descriptions of the optical response of metals. Here we study a class of metasurfaces consisting of a periodic metal slab with a smooth modulation of its thickness. When the thinnest part shrinks, the two surfaces almost touch, forming a near-singular point. Using transformation optics, we show analytically h…
Optical interactions have an important impact on the optical response of nanostructures in complex environments. Accounting for interactions in large ensembles of structures requires computationally demanding numerical calculations. In particular if no periodicity can be exploited, full field simulations can become prohibitively expensive. Here we propose a method for the numerical description of aperiodic assemblies of plasmonic nanostructures. Our approach is based on dressed polarizabilities, which are conventionally very expensive to calculate, a problem which we alleviate using a deep con…
Metasurfaces is an emerging field that enables the manipulation of light by an ultra-thin structure composed of sub-wavelength antennae and fulfills an important requirement for miniaturized optical elements. Finding a new design for a metasurface or optimizing an existing design for a desired functionality is a computationally expensive and time consuming process as it is based on an iterative process of trial and error. We propose a deep learning (DL) architecture dubbed bidirectional autoencoder for nanophotonic metasurface design via a template search methodology. In contrast with the earl…
Plasmon resonances play a pivotal role in enhancing light-matter interactions in nanophotonics, but their low-quality factors have hindered applications demanding high spectral selectivity. Even though symmetry-protected bound states in the continuum with high-quality factors have been realized in dielectric metasurfaces, impinging light is not efficiently coupled to the resonant metasurfaces and is lost in the form of reflection due to low intrinsic losses. Here, we demonstrate a novel design and 3D laser nanoprinting of plasmonic nanofin metasurfaces, which support symmetry-protected bound s…
A comprehensive analysis of hybrid TM-TE polarized surface electromagnetic waves supported by different few-layer anisotropic metasurfaces is presented. A generalized 4$\times$4 T-matrix formalism for arbitrary anisotropic 2D layers is developed, from which the general relations for the surface waves dispersions and scattering coefficients are deduced. Using this formalism and the effective conductivity approach, the dispersions and iso-frequency contours (IFCs) topology of the surface waves in various hybrid uniaxial metasurfaces are studied. The existence of hyperbolic plasmon-exciton polari…
Nanostructures of conventional metals offer manipulation of light at the nanoscale but are limited to static behavior due to their fixed material properties. To develop the next frontier of dynamic nanooptics and metasurfaces, we utilize the redox-tunable optical properties of conducting polymers, which were recently shown to be capable of sustaining plasmons in their most conducting oxidized state. Using nanodisks of poly(3,4-ethylenedioxythiophene:sulfate) (PEDOT:Sulf) as a model system, we present the first electrically tunable conducting polymer nanooptical antennas. In addition to repeate…
Room-temperature tuning and probing of Fermi polarons in atomically thin semiconductors on a plasmonic metasurface
Nanyang Technological University（南洋理工大学）；Universidad Autónoma de Madrid（马德里自治大学）；Condensed Matter Physics Center (IFIMAC), Universidad Autónoma de Madrid（马德里自治大学凝聚态物理中心（IFIMAC））；Jilin University（吉林大学）；Zhejiang University（浙江大学）
The material and exact shape of a nanostructure determine its optical response, which is especially strong for plasmonic metals. Unfortunately, only a very few plasmonic metals are available, which limits the spectral range where these strong optical effects can be utilized. Alloying different plasmonic metals can overcome this limitation, at the expense of using a high temperature alloying process, which adversely destroys the nanostructure shape. Here, we develop a low temperature alloying process at only 300°C and fabricate Au-Ag nanostructures with a broad diversity of shapes, aspect ratio…
Plasmonic antennas are key elements to control the luminescence of quantum emitters. However, the antenna's influence is often hidden by quenching losses. Here, the luminescence of a quantum dot coupled to a gold dimer antenna is investigated. Detailed analysis of the multiply excited states quantifies the antenna's influence on the excitation intensity and the luminescence quantum yield separately.
This paper makes evidence for direct dark mode excitation mechanism in a metasurface structure. The dark mode excitation mechanism is entirely determined by structures' symmetry and does not depend on near-field coupling between elements. In our examples, we consider single element based metasurface composed of two V antennas connected in an anti-symmetric arrangement. Both experimental and modeling results show an efficient excitation of magnetic dipolar mode in such structures. The direct dark mode excitation mechanism provides a design that is more robust with respect to technology imperfec…
Surface plasmons dominate the optical response of metal surfaces, and their nature is controlled by surface geometry. Here we study metasurfaces containing singularities in the form of sharp edges and characterized by three quantum numbers despite the two-dimensional nature of the surface. We explore the nature of the plasmonic excitations, their ability to generate large concentrations of optical energy, and the transition from the discrete excitation spectrum of a non-singular surface to the continuous spectrum of a singular metasurface.
The identification of plasmons in systems below $ \sim $10 nm in size is a tremendous challenge. Any sharp distinction of the excitation character (non-plasmonic vs plasmonic) becomes blurred in this range of sizes, where quantum effects become important. Here we define a {\em plasmonicicty index} that quantifies the plasmonic character of selected optical excitations in small nanostructures, starting from first principles calculations, based on (TD)DFT. This novel approach allows us to overcome the aforementioned problems, providing a direct and quantitative classification of the plasmonic ch…
We report strong amplification of photo-magnetic spin precession in Co-doped YIG employing a surface plasmon excitation in a metal-dielectric magneto-plasmonic crystal. Plasmonic enhancement is accompanied by the localization of the excitation within the 300~nm-thick layer inside the transparent dielectric garnet. Experimental results are nicely reproduced by numerical simulations of the photo-magnetic excitation. Our findings demonstrate the magneto-plasmonic concept of subwavelength localization and amplification of the photo-magnetic excitation in dielectric YIG:Co and open up a path to all…
We demonstrate how the controlled positioning of a plasmonic nanoparticle modifies the photoluminescence of a single epitaxial GaAs quantum dot. The antenna particle leads to an increase of the luminescence intensity by about a factor of eight. Spectrally and temporally resolved photoluminescence measurements prove an increase of the quantum dot's excitation rate. The combination of stable epitaxial quantum emitters and plasmonic nanostructures promises to be highly beneficial for nanoscience and quantum optics.
