We study the low-frequency properties of the bulk photovoltaic effect in topological semimetals. The bulk photovoltaic effect is a nonlinear optical effect that generates DC photocurrents under uniform irradiation, allowed by noncentrosymmetry. It is a promising mechanism for a terahertz photodetection based on topological semimetals. Here, we systematically investigate the low-frequency behavior of the second-order optical conductivity in point-node semimetals. Through symmetry and power-counting analysis, we show that Dirac and Weyl points with tilted cones show the leading low-frequency divergence. In particular, we find new divergent behaviors of the conductivity of Dirac and Weyl points under circularly polarized light, where the conductivity scales as $ω^{-2}$ and $ω^{-1}$ near the gap-closing point in two and three dimensions, respectively. We provide a further perspective on the low-frequency bulk photovoltaic effect by revealing the complete quantum geometric meaning of the second-order optical conductivity tensor. The bulk photovoltaic effect has two origins, which are the transition of electron position and the transition of electron velocity during the optical excitation, and the resulting photocurrents are respectively called the shift current and the injection current. Based on an analysis of two-band models, we show that the injection current is controlled by the quantum metric and Berry curvature, whereas the shift current is governed by the Christoffel symbols near the gap-closing points in semimetals. Finally, for further demonstrations of our theory beyond simple two-band models, we perform first-principles calculations on magnetic Dirac semimetal MnGeO$_3$and Weyl semimetal PrGeAl. Our work brings out new insights into the structure of nonlinear optical responses as well as for the design of semimetal-based terahertz photodetectors.
We theoretically study the circularly polarized light-induced Floquet state in line-node semimetals with time-reversal symmetry and inversion symmetry. It is found that the Floquet state can show the photovoltaic anomalous Hall effect when an applied circularly polarized light gaps out the line node in the bulk and leave Weyl point nodes. The Hall conductivity is sensitive to the location of Fermi level: When the Fermi level locates at the node, the Hall conductivity depends on the radius of line node and is nearly independent of the intensity of light. Away from the line node, the Hall conduc…
Broadband, efficient and fast conversion of light to electricity is crucial for sensing and clean energy. Here we reveal the largest observed bulk photo-voltaic effect (BPVE), an intrinsic mechanism predicted to be ultrafast and exceed the Shockley-Quiesser limit. This discovery results from combining recent developments in the connection of BPVE to topology, Weyl semimetals and focused-ion beam fabrication. Our room temperature observation of the first BPVE in the mid-IR, is enabled by microscopic devices of the Weyl semimetal TaAs. Detailed symmetry analysis enables unambiguous separation of…
The photovoltaic effect in a Weyl semimetal due to the adiabatic quantum phase is studied. We particularly focus on the case in which an external ac electric field is applied to the semimetal. In this setup, we show that a photocurrent is induced by the ac electric field. By considering a generalized Weyl Hamiltonian with nonlinear terms, it is shown that the photocurrent is induced by circularly, rather than linearly, polarized light. This photovoltaic current can be understood as an emergent electromagnetic induction in the momentum space; the Weyl node is a magnetic monopole in the momentum…
Weyl semimetals (WSM) have been discovered in time-reversal symmetric materials, featuring monopoles of Berry's curvature in momentum space. WSM have been distinguished between Type-I and II where the velocity tilting of the cone in the later ensures a finite area Fermi surface. To date it has not been clear whether the two types results in any qualitatively new phenomena. Here we focus on the shift-current response ($σ_{shift}(ω)$), a second order optical effect generating photocurrents. Surprisingly we find that up to an order unity constant, $σ_{shift}(ω)\sim \frac{e^3}{h^2}\frac{1}ω$ in Ty…
The rectified non-linear response of a clean undoped semiconductor to an AC electric field includes a well known intrinsic contribution -- the shift current. We show that when Kramers degeneracy is broken, a distinct second order rectified response appears that is due to Bloch state anomalous velocities in a system with an oscillating Fermi surface. This effect, which we refer to as the resonant photovoltaic effect (RPE), produces a resonant galvanic current peak at the interband absorption threshold in doped semiconductors or semimetals with approximate particle-hole symmetry. We evaluate the…
We theoretically predict a generation of a current in Weyl semimetals by applying circularly polarized light. The electric field of the light can drive an effective magnetic field of order of ten Tesla. For lower frequency light, a non-equilibrium spin distribution is formed near the Fermi surface. Due to the spin-momentum locking, a giant electric current proportional to the effective magnetic field is induced. On the other hand, higher frequency light realizes a quasi-static Floquet state with no induced electric current. We discuss relevant materials and estimate order of magnitude of the i…
Vortex-enhanced photovoltaic current in disordered topological materials
University of Missouri（密苏里大学）；The Ohio State University（俄亥俄州立大学）；Lawrence Berkeley National Laboratory（劳伦斯伯克利国家实验室）；University of California Santa Cruz（加州大学圣克鲁兹分校）
This paper presents a study of dc photocurrents in biased insulators to the third order in the electric field. We find three photocurrents which are characterized by physical divergences of the third-order free-electron polarization susceptibility. In the absence of momentum relaxation and saturation effects, these dc photocurrents grow as $t^n$ $(n=2,1,0)$ with illumination time. The photocurrents are dubbed \textit{jerk}, third-order injection, and third-order shift current, respectively, and are generalizations of the second-order injection and shift currents of the bulk photovoltaic effect…
We theoretically study the magnetoconductivity of the Weyl semimetal having a surface boundary under $E$ || $B$ geometry and demonstrate that the topological surface state plays an essential role in the magnetotransport. In the long-range disorder limit where the scattering between the two Weyl nodes vanishes, the conductivity diverges in the bulk model (i.e., periodic boundary condition) as usually expected, since the direct inter-node relaxation is absent. In the presence of the surface, however, the inter-node relaxation always takes place through the mediation by the surface states, and th…
We investigate a physical divergence of the third order polarization susceptibility representing a photoinduced current in biased crystalline insulators. This current grows quadratically with illumination time in the absence of momentum relaxation and saturation; we refer to it as the \textit{jerk current}. Two contributions to the current are identified. The first is a hydrodynamic acceleration of optically injected carriers by the static electric field, and the second is the change in the carrier injection rate in the presence of the static electric field. The jerk current can have a compone…
Quantum phase transitions of three-dimensional (3D) Weyl semimetals (WSMs) subject to uncorrelated on-site disorder are investigated through quantum conductance calculations and finite-size scaling of localization length. Contrary to previous claims that a direct transition from a WSM to a diffusive metal (DM) occurs, an intermediate phase of Chern insulator (CI) between the two distinct metallic phases should exist due to internode scattering that is comparable to intranode scattering. The critical exponent of localization length is $ν\simeq 1.3$ for both the WSM-CI and CI-DM transitions, in …
We show that Weyl Fermi arcs are generically accompanied by a divergence of the surface Berry curvature scaling as $1/k^2$, where $k$ is the distance to a hot-line in the surface Brillouin zone that connects the projection of Weyl nodes with opposite chirality but which is distinct from the Fermi arc itself. Such surface Berry curvature appears whenever the bulk Weyl dispersion has a velocity tilt toward the surface of interest. This divergence is reflected in a variety of Berry curvature mediated effects that are readily accessible experimentally, and in particular leads to a surface Berry cu…
The electron-phonon interaction (EPI) is instrumental in a wide variety of phenomena in solid-state physics, such as electrical resistivity in metals, carrier mobility, optical transition and polaron effects in semiconductors, lifetime of hot carriers, transition temperature in BCS superconductors, and even spin relaxation in diamond nitrogen-vacancy centers for quantum information processing. However, due to the weak EPI strength, most phenomena have focused on electronic properties rather than on phonon properties. One prominent exception is the Kohn anomaly, where phonon softening can emerg…
We study the unique physical properties of topological nodal-loop semimetals protected by the coexistence of time-reversal and inversion symmetries with negligible spin-orbit coupling. We argue that strong correlation effects occur at the surface of such systems for relatively small Hubbard interaction $U$, due to the narrow bandwidth of the "drumhead" surface states. In the Hartree-Fock approximation, at small $U$ we obtain a surface ferromagnetic phase through a continuous quantum phase transition characterized by the surface-mode divergence of the spin susceptibility, while the bulk states …
Electrons moving in a Bloch band are known to acquire an anomalous Hall velocity proportional to the Berry curvature of the band which is responsible for the intrinsic linear Hall effect in materials with broken time-reversal symmetry. Here, we demonstrate that there is also an anomalous correction to the electron acceleration which is proportional to the Berry curvature dipole and is responsible for the Nonlinear Hall effect recently discovered in materials with broken inversion symmetry. This allows us to uncover a deeper meaning of the Berry curvature dipole as a nonlinear version of the Dr…
In this work, we describe the phenomenon of Weyl-point teleportation. Weyl points usually move continuously in the configuration parameter space of a quantum system when the control parameters are varied continuously. However, there are special transition points in the control space where the continuous motion of the Weyl points is disrupted. In such transition points, an extended nodal structure (nodal line or nodal surface) emerges, serving as a wormhole for the Weyl points, allowing their teleportation in the configuration space. A characteristic side effect of the teleportation is that the…
We study a model for a quantum critical point in two spatial dimensions between a semimetallic phase, characterized by a stable quadratic Fermi node, and an ordered phase, in which the spectrum develops a band gap. The quantum critical behavior can be computed exactly, and we explicitly derive the scaling laws of various observables. While the order-parameter correlation function at criticality satisfies the usual power law with anomalous exponent $η_ϕ= 2$, the correlation length and the expectation value of the order parameter exhibit essential singularities upon approaching the quantum criti…
We show that the position-momentum duality offers a transparent interpretation of the band geometry at the topological band crossings. Under this duality, the band geometry with Berry connection is dual to the free-electron motion under gauge field. This identifies the trace of quantum metric as the dual energy in momentum space. The band crossings with Berry defects thus induce the dual energy quantization in the trace of quantum metric. For the $\mathbb Z$ nodal-point and nodal-surface semimetals in three dimensions, the dual Landau level quantization occurs owing to the Berry charges. Meanw…
Nonlinear light-matter interaction, as the core of ultrafast optics, bulk photovoltaics, nonlinear optical sensing and imaging, and efficient generation of entangled photons, has been traditionally studied by first-principles theoretical methods with the sum-over-states approach. However, this indirect method often suffers from the divergence at band degeneracy and optical zeros as well as convergence issues and high computation costs when summing over the states. Here, using shift vector and shift current conductivity tensor as an example, we present a gauge-invariant generalized approach for…
