The physical evolution of Young Stellar Objects (YSOs) is accompanied by an enrichment of the molecular complexity, mainly triggered by the heating and energetic processing of the astrophysical ices. In this paper, a study of how the ice column density varies across the protostellar evolution has been performed. Tabulated data of H$_2$O, CO$_2$, CH$_3$OH, HCOOH observed by ground- and space-based telescopes toward 27 early-stage YSOs were taken from the literature. The observational data shows that ice column density and spectral index ($α$), used to classify the evolutionary stage, are well correlated. A 2D continuum radiative transfer simulation containing bare and grains covered by ices at different levels of cosmic-ray processing were used to calculate the Spectral Energy Distributions (SEDs) in different angle inclinations between face-on and edge-on configuration. The H$_2$O:CO$_2$ ice mixture was used to address the H$_2$O and CO$_2$ column density variation whereas the CH$_3$OH and HCOOH are a byproduct of the virgin ice after the energetic processing. The simulated spectra were used to calculate the ice column densities of YSOs in an evolutionary sequence. As a result, the models show that the ice column density variation of HCOOH with $α$ can be justified by the envelope dissipation and ice energetic processing. On the other hand, the ice column densities are mostly overestimated in the cases of H$_2$O, CO$_2$ and CH$_3$OH, even though the physical and cosmic-ray processing effects are taken into account.
We present the study of the effects of high energy cosmic rays (CRs) over the astrophysical ices, observed toward the embedded class I protostar Elias 29, by using computational modeling and laboratory data. Its spectrum was observed with {\it Infrared Space Observatory - ISO}, covering 2.3 - 190 $μ$m. The modeling employed the three-dimensional Monte Carlo radiative transfer code RADMC-3D (Dullemond et al. 2012) and laboratory data of bombarded ice grains by CRs analogs, and unprocessed ices (not bombarded). We are assuming that Elias 29 has a self-irradiated disk with inclination $i =$ 60$^{…
The survival of astrophysical ices in the star-forming regions depends on the suitability of temperature, density and radiation conditions. In this paper, the role of Interstellar Radiation Field (ISRF) on ices in Elias 29 is addressed. This object is the most luminous protostar in $ρ$ Oph E molecular cloud, and is surrounded by many Young Stellar Objects distant only a few arcminutes. In addition, other two brightness BV stars (S1 and HD 147889) enhance the external irradiation in Elias 29. This study was carried out by using the Monte Carlo radiative transfer code RADMC-3D assuming an intern…
In dense and cold regions of the interstellar medium (ISM), molecules may be adsorbed onto dust grains to form the ice mantles. Once formed, they can be processed by ionizing radiation coming from stellar or interstellar medium leading to formation of several new molecules in the ice. Among the different kind of ionizing radiation, cosmic rays play an important role in the solid-phase chemistry because of the large amount of energy deposited in the ices. The physicochemical changes induced by the energetic processing of astrophysical ices are recorded in a intrinsic parameter of the matter cal…
Context: Broadband optical constants of astrophysical ice analogues in the infrared (IR) and terahertz (THz) ranges are required for modeling the dust continuum emission and radiative transfer in dense and cold regions, where thick icy mantles are formed on the surface of dust grains. Aims: In this paper, the THz time-domain spectroscopy (TDS) and the Fourier-transform IR spectroscopy (FTIR) are combined to study optical constants of CO and CO$_2$ ices in the broad THz-IR spectral range. Methods: The measured ices are grown at cryogenic temperatures by gas deposition on a cold Si window. A met…
Mapping of interstellar ices with JWST in protostellar envelopes: Spatial variations of $^{13}$CO$_2$, $^{12}$CO$_2$, CO, OCN$^-$ and H$_2$O ice
Leiden University（莱顿大学）；Max-Planck-Institut für Extraterrestrische Physik（马克斯·普朗克地外物理研究所）；University of Hawai’i at Manoa（夏威夷大学马诺阿分校）；University of Cambridge（剑桥大学）；Center for Astrophysics, Harvard & Smithsonian（哈佛与史密森尼天体物理中心）；Max Planck Institute for Astronomy（马克斯·普朗克天文学研究所）；INAF-Osservatorio Astronomico di Capodimonte（意大利国家天体物理研究所卡波迪蒙特天文台）；The University of Toledo（托莱多大学）
In this study, we employed broadband X-rays ($6-2000$ eV) to irradiate the frozen acetone CH$_3$COCH$_3$, at the temperature of 12 K, with different photon fluences up to $2.7\times 10^{18}$ photons cm$^{-2}$. Here, we consider acetone as a representative complex organic molecule (COM) present on interstellar ice grains. The experiments were conduced at the Brazilian synchrotron facility (LNLS/CNPEN) employing infrared spectroscopy (FTIR) to monitor chemical changes induced by radiation in the ice sample. We determined the effective destruction cross-section of the acetone molecule and the eff…
Context. "Snow lines", marking regions where abundant volatiles freeze out onto the surface of dust grains, play an important role for planet growth and bulk composition in protoplanetary disks. They can already be observed in the envelopes of the much younger, low-mass Class 0 protostars that are still in their early phase of heavy accretion. Aims. We aim at using the information on the sublimation regions of different kinds of ices to understand the chemistry of the envelope, its temperature and density structure, and the history of the accretion process. Methods. As part of the CALYPSO IRAM…
High-resolution mid-IR spectroscopy of SVS 13-A with EXES/SOFIA: The surprisingly high CH$_3$OH/H$_2$O ratio in the planet-forming zone of a solar mass protostar
Space Science Institute（空间科学研究所）；ESO（欧洲南方天文台）；INAF, Osservatorio Astrofisico di Arcetri（意大利国家天体物理研究所阿切特里天文台）；Univ. Grenoble Alpes, CNRS, IPAG（格勒诺布尔阿尔卑斯大学、法国国家科学研究中心、行星与地球物理研究所）；Space Science and Astrobiology Division, NASA Ames Research Center（美国宇航局艾姆斯研究中心空间科学与天体生物学部门）；Bay Area Environmental Research Institute（湾区环境研究所）；Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）；Universitat Autònoma de Barcelona（巴塞罗那自治大学）；University of Turin（都灵大学）
Low-mass protostars are the extrasolar analogues of the natal Solar System. Sophisticated physicochemical models are used to simulate the formation of two protoplanetary discs from the initial prestellar phase, one dominated by viscous spreading and the other by pure infall. The results show that the volatile prestellar fingerprint is modified by the chemistry en route into the disc. This holds relatively independent of initial abundances and chemical parameters: physical conditions are more important. The amount of CO2 increases via the grain-surface reaction of OH with CO, which is enhanced …
Optical constants of Ih, Ic, and amorphous H$_2$O ices in the THz and IR ranges
Prokhorov General Physics Institute of the Russian Academy of Sciences（俄罗斯科学院普尔科沃普通物理研究所）；Max-Planck-Institut für Extraterrestrische Physik（马克斯·普朗克地外物理研究所）；Federal Institute of Education, Science and Technology of Rio de Janeiro (IFRJ)（里约热内卢联邦教育、科学和技术学院）
High quality vibrational spectra of solid-phase molecules in ice mixtures and for temperatures of astrophysical relevance are needed to interpret infrared observations toward protostars and background stars. Over the last 25 years, the Laboratory for Astrophysics at Leiden Observatory has provided more than 1100 spectra of diverse ice samples. Timely with the recent launch of the James Webb Space Telescope, we have fully upgraded the Leiden Ice Database for Astrochemistry (LIDA) adding recently measured spectra. The goal of this manuscript is to describe what options exist to get access to and…
Non-thermal desorption from icy grains containing H$_2$CO has been invoked to explain the observed H$_2$CO gas phase abundances in ProtoPlanetary Disks (PPDs) and Photon Dominated Regions (PDRs). Photodesorption is thought to play a key role, however no absolute measurement of the photodesorption from H$_2$CO ices were performed up to now, so that a default value is used in the current astrophysical models. As photodesorption yields differ from one molecule to the other, it is crucial to experimentally investigate photodesorption from H$_2$CO ices. We measured absolute wavelength-resolved phot…
Up to 90% of the chemical reactions during star formation occurs on ice surfaces, probably including the formation of complex organics. Only the most abundant ice species are however observed directly by infrared spectroscopy. This study aims to develop an indirect observational method of ices based on non-thermal ice desorption in the colder part of protostellar envelopes. For that purpose the IRAM 30m telescope was employed to observe two molecules that can be detected both in the gas and the ice, CH3 OH and HNCO, toward 4 low mass embedded protostars. Their respective gas-phase column densi…
We study the evaporation and condensation of CO and CO_2 during the embedded stages of low-mass star formation by using numerical simulations. We focus on the effect of luminosity bursts, similar in magnitude to FUors and EXors, on the gas-phase abundance of CO and CO_2 in the protostellar disk and infalling envelope. The evolution of a young protostar and its environment is followed based on hydrodynamical models using the thin-disk approximation, coupled with a stellar evolution code and phase transformations of CO and CO_2. The accretion and associated luminosity bursts in our model are cau…
Aims. Intermediate Mass (IM) stars are an important component of our Galaxy, as they significantly contribute to the interstellar FUV field and, consequently, play an important role in the energy balance of the ISM. Despite their importance, very little is known about their formation process and only a few studies have been devoted to characterize the first phases in the evolution of intermediate mass protostars. Here we consider in great detail the case of the brightest and closest known young IM protostar: FIR4 in the OMC2 component of the Orion molecular cloud complex. Methods. We analyzed …
Korea Astronomy and Space Science Institute (KASI)（韩国天文与空间科学研究所）；Johns Hopkins University（约翰斯·霍普金斯大学）；Johns Hopkins University, Applied Physics Laboratory（约翰斯·霍普金斯大学应用物理实验室）；Infrared Processing Analysis Center, California Institute of Technology（加州理工学院红外处理与分析中心）；Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）；Seoul National University（首尔大学）
Backlighting young stellar objects in the Central Molecular Zone: an ensemble-averaged abundance structure of methanol ices
Ewha Womans University（梨花女子大学）；University of Hawaii（夏威夷大学）；Korea Astronomy and Space Science Institute（韩国天文与空间科学研究所）；University of Science and Technology, Korea (UST)（韩国科学技术院）
Isocyanic acid (HNCO), the most stable of the simplest molecules containing the four main elements essential for organic chemistry, has been observed in several astrophysical environments such as molecular clouds, star-forming regions, external galaxies and comets. In this work, we model HNCO spectral line profiles toward the low-mass solar type protostar IRAS 16293$-2$422 observed with the ALMA interferometer, the IRAM, JCMT and APEX single-dish radio telescopes, and the HIFI instrument on board the Herschel Space Observatory. In star-forming environments, the HNCO emission is not always in L…
Thermal annealing of interstellar ices takes place in several stages of star formation. Knowledge of this process comes from a combination of astronomical observations and laboratory simulations under astrophysically relevant conditions. For the first time we present the results of temperature programmed desorption (TPD) experiments with pre-cometary ice analogs composed of up to five molecular components: H2 O, CO, CO2, CH3 OH, and NH3 . The experiments were performed with an ultra-high vacuum chamber. A gas line with a novel design allows the controlled preparation of mixtures with up to fiv…
CORINOS V: Radiative transfer effects in protostellar ice observations
University of California, Berkeley（加州大学伯克利分校）；The University of Texas at Austin（德克萨斯大学奥斯汀分校）；RIKEN Cluster for Pioneering Research（理化学研究所前沿研究集群）；Jet Propulsion Laboratory, California Institute of Technology（加州理工学院喷气推进实验室）；University of Virginia（弗吉尼亚大学）；Leiden Observatory, Leiden University（莱顿大学莱顿天文台）；Max Planck Institut für Extraterrestrische Physik (MPE)（马克斯·普朗克地外物理研究所）；Seoul National University（首尔国立大学）
When studying the evolutionary stages of protostars that form in clusters, the role of any intracluster medium cannot be neglected. High foreground extinction can lead to situations where young stellar objects (YSOs) appear to be in earlier evolutionary stages than they actually are, particularly when using simple criteria like spectral indices. To address this issue, we have assembled detailed SED characterizations of a sample of 56 Spitzer-identified candidate YSOs in the clusters NGC 2264 and IC 348. For these, we use spectra obtained with the Infrared Spectrograph onboard the Spitzer Space…
EPISODE IV: Ice Inventory in the Envelope of EC 53
Korea Astronomy and Space Science Institute（韩国天文与空间科学研究所）；Seoul National University（首尔大学）；Research Institute of Basic Sciences, Seoul National University（首尔大学基础科学研究院）；RIKEN Pioneering Research Institute（理化学研究所先导研究院）；University of Tokyo（东京大学）；Peking University（北京大学）
Context. Icy dust grains play an important role in the formation of complex inter- and circumstellar molecules. Observational studies show that polycyclic aromatic hydrocarbons (PAHs) are abundantly present in the ISM in the gas phase. It is likely that these non-volatile species freeze out onto dust grains as well and participate in the astrochemical solid-state network, but experimental PAH ice studies are largely lacking. Methods. Near UV/VIS spectroscopy is used to track the in situ VUV driven photochemistry of pyrene containing ices at temperatures ranging from 10 to 125 K. Results. The m…
Functionalization of Benzene Ices by Atomic Oxygen
Harvard-Smithsonian Center for Astrophysics（哈佛-史密森天体物理中心）；Harvard University（哈佛大学）；University of Bern（伯尔尼大学）；The Hebrew University of Jerusalem（耶路撒冷希伯来大学）；UC Berkeley（加州大学伯克利分校）
JWST Observations of Young protoStars (JOYS+): Detection of icy complex organic molecules and ions. I. CH$_4$, SO$_2$, HCOO$^-$, OCN$^-$, H$_2$CO, HCOOH, CH$_3$CH$_2$OH, CH$_3$CHO, CH$_3$OCHO, CH$_3$COOH
In cold core of dark molecular clouds, where the UV radiation from external sources is strongly attenuated, cosmic rays can induce chemical reactions on the surface of ice-covered grains promoting the ejection of the processed material to the gas phase. We report the positive and negative secondary ion emission from pure CH3CN, C2H3CN and i-C3H7CN ices due to the bombardment of heavy ions (252Cf fission fragments), simulating the incidence of cosmic rays onto icy surfaces. The secondary ions emitted from each sample were analysed by time-of-flight mass spectrometry (TOF-MS), using Plasma Desor…
Broadband infrared spectroscopy of methanol isotopologues in pure, H2O-rich, and CO-rich ice analogues
Max-Planck-Institut für extraterrestrische Physik（马克斯·普朗克地外物理学研究所）；University of Kent（肯特大学）；HUN-REN Institute for Nuclear Research (Atomki)（匈牙利研究与教育网络核物理研究所）；INAF - Osservatorio Astrofisico di Catania（意大利国家天体物理研究所卡塔尼亚天文台）
The role of MHD turbulence in astrophysical environments is still highly debated. An important question that permeates this debate is the transport of magnetic flux. This is particularly important, for instance, in the context of star formation. When clouds collapse gravitationally to form stars, there must be some magnetic flux transport. otherwise the new born stars would have magnetic fields several orders of magnitude larger than the observed ones. Also, the magnetic flux that is dragged in the late stages of the formation of a star can remove all the rotational support from the accretion …
