We derive geometrical bounds on the irreversibility in both quantum and classical Markovian open systems that satisfy the detailed balance condition. Using information geometry, we prove that irreversible entropy production is bounded from below by a modified Wasserstein distance between the initial and final states, thus strengthening the Clausius inequality in the reversible-Markov case. The modified metric can be regarded as a discrete-state generalization of the Wasserstein metric, which has been used to bound dissipation in continuous-state Langevin systems. Notably, the derived bounds can be interpreted as the quantum and classical speed limits, implying that the associated entropy production constrains the minimum time of transforming a system state. We illustrate the results on several systems and show that a tighter bound than the Carnot bound for the efficiency of quantum heat engines can be obtained.
The relation between the thermodynamic entropy production and non-Markovian evolutions is matter of current research. Here, we study the behavior of the stochastic entropy production in open quantum systems undergoing unital non-Markovian dynamics. In particular, for the family of Pauli channels we show that in some specific time intervals both the average entropy production and the variance can decrease, provided that the quantum dynamics fails to be P-divisible. Although the dynamics of the system is overall irreversible, our result may be interpreted as a transient tendency towards reversib…
We address the emergence of entropy production in the non-equilibrium process of an open quantum system from the viewpoint of the environment. By making use of a dilation-based approach akin to Stinespring theorem, we derive an expression for the entropy production that comprises two fundamental contributions. The first is linked to the rate of creation of correlations between system and environment whereas the second highlights the possibility for the environment to modify its state in light of its coupling to the system. Both terms are shown to be associated with irreversible currents within…
We consider a simple model of a classical harmonic oscillator coupled to a field. In standard approaches Langevin-type equations for {\it bare} particles are derived from Hamiltonian dynamics. These equations contain memory terms and are time-reversal invariant. In contrast the phenomenological Langevin equations have no memory terms (they are Markovian equations) and give a time evolution split in two branches (semigroups), each of which breaks time symmetry. A standard approach to bridge dynamics with phenomenology is to consider the Markovian approximation of the former. In this paper we pr…
Entropy production plays a fundamental role in nonequilibrium thermodynamics to quantify the irreversibility of open systems. Its positivity can be ensured for a wide class of setups, but the entropy production rate can become negative sometimes. This is often taken as an indicator of non-Markovian dynamics. We make this link precise by showing under which conditions a negative entropy production rate implies non-Markovian dynamics and when it does not. This is established within a unified language for two setups: (i) the dynamics resulting from a coarse-grained description of a system in cont…
We derive an exact Markovian kinetic equation for an oscillator linearly coupled to a heat bath, describing quantum Brownian motion. Our work is based on the subdynamics formulation developed by Prigogine and collaborators. The space of distribution functions is decomposed into independent subspaces that remain invariant under Liouville dynamics. For integrable systems in Poincaré's sense the invariant subspaces follow the dynamics of uncoupled, renormalized particles. In contrast for non-integrable systems, the invariant subspaces follow a dynamics with broken-time symmetry, involving general…
Continuous feedback control of Langevin processes may be non-Markovian due to a time lag between the measurement and the control action. We show that this requires to modify the basic relation between dissipation and time-reversal and to include a contribution arising from the non-causal character of the reverse process. We then propose a new definition of the quantity measuring the irreversibility of a path in a nonequilibrium stationary state, which can be also regarded as the trajectory-dependent total entropy production. This leads to an extension of the second law which takes a simple for…
We derive a geometrical expression of the excess entropy production for quasi-static transitions between nonequilibrium steady states of Markovian jump processes, which can be exactly applied to nonlinear and nonequilibrium situations. The obtained expression is geometrical; the excess entropy production depends only on a trajectory in the parameter space, analogous to the Berry phase in quantum mechanics. Our results imply that vector potentials are needed to construct thermodynamics of nonequilibrium steady states.
Conditional fluctuation theorems and entropy production for monitored quantum systems under imperfect detection
Institute for Cross-Disciplinary Physics and Complex Systems IFISC (UIB-CSIC)（交叉物理与复杂系统研究所）；Departamento de Física Aplicada, Universidad de Alicante（阿利坎特大学应用物理系）
We show that memory, feedback, and activity are all describable by the same unifying concept, that is non-reciprocal (NR) coupling. We demonstrate that characteristic thermodynamic features of these intrinsically nonequilibrium systems are reproduced by low-dimensional Markovian networks with NR coupling, which we establish as minimal models for such complex systems. NR coupling alone implies a violation of the fluctuation-dissipation relation, which is inevitably connected to entropy production, i.e., irreversibility. Hiding the NR coupled degrees of freedom renders non-Markovian, one-variabl…
Stochastic Thermodynamics for Autoregressive Generative Models: A Non-Markovian Perspective
The University of Tokyo（东京大学）；Quantum-Phase Electronics Center (QPEC), The University of Tokyo（量子相位电子中心（QPEC），东京大学）；Inamori Research Institute for Science (InaRIS)（稻盛科学研究所（InaRIS)）
We investigate the total stochastic entropy production of a two-level bosonic open quantum system under protocols of time dependent coupling to a harmonic environment. These processes are intended to represent the measurement of a system observable, and consequent selection of an eigenstate, whilst the system is also subjected to thermalising environmental noise. The entropy production depends on the evolution of the system variables and their probability density function, and is expressed through system and environmental contributions. The continuous stochastic dynamics of the open system is …
For open systems described by the quantum Markovian master equation, we study a possible extension of the Clausius equality to quasistatic operations between nonequilibrium steady states (NESSs). We investigate the excess heat divided by temperature (i.e., excess entropy production) which is transferred into the system during the operations. We derive a geometrical expression for the excess entropy production, which is analogous to the Berry phase in unitary evolution. Our result implies that in general one cannot define a scalar potential whose difference coincides with the excess entropy pro…
The total entropy production and its three constituent components are described both as fluctuating trajectory-dependent quantities and as averaged contributions in the context of the continuous Markovian dynamics, described by stochastic differential equations with multiplicative noise, of systems with both odd and even coordinates with respect to time reversal, such as dynamics in full phase space. Two of these constituent quantities obey integral fluctuation theorems and are thus rigorously positive in the mean by Jensen's inequality. The third, however, is not and furthermore cannot be uni…
Correlations in quantum systems exhibit a rich phenomenology under the effect of various sources of noise. We investigate theoretically and experimentally the dynamics of quantum correlations and their classical counterparts in two nuclear magnetic resonance setups, as measured by geometric quantifiers based on trace-norm. We consider two-qubit systems prepared in Bell diagonal states, and perform the experiments in decohering environments resulting from Bell diagonal-preserving Markovian local noise. We then report the first observation of environment-induced double sudden transitions in the …
Autonomous engines operating at the nano-scale can be prone to deleterious fluctuations in the heat and particle currents which increase, for fixed power output, the more reversible the operation regime is. This fundamental trade-off between current fluctuations and entropy production forms the basis of the recently formulated thermodynamic uncertainty relations (TURs). However, these relations have so far only been derived for classical Markovian systems and can be violated in the quantum regime. In this paper we show that the geometry of quantum non-equilibrium steady-states alone, already d…
