对X.“广义玻尔兹曼分布是唯一的吉布斯-香农熵等于热力学熵的分布”一文的评论。Gao、黄毛菊E. Gallicchio和A.E. Roitberg [J. Chem. Phys. 151,034113(2019)]
Comment on "The generalized Boltzmann distribution is the only distribution in which the Gibbs-Shannon entropy equals the thermodynamic entropy" by X. Gao, E. Gallicchio and A.E. Roitberg [J. Chem. Phys. 151, 034113 (2019)]
摘要:
本文的标题导致了一个不正确的结论,因为我们表明,平衡结果的文件是一个特殊的限制的一般结果的非平衡系统的内部平衡已经在文献中。我们还指出了作者所采取的方法的一些局限性。
英文摘要:
The title of the paper leads to an incorrect conclusion as we show that the equilibrium result of the paper is a special limit of a general result for nonequilibrium systems in internal equilibrium already available in the literature. We also point out some of the limitations of the approach taken by the authors.
机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。