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arXiv 2004.03625cond-mat.supr-con
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Fe1-xVxSe超导性能对过渡金属替代和杂质相的鲁棒性

Robustness of superconducting properties to transition metal substitution and impurity phases in Fe1-xVxSe

Franziska K. K. Kirschner, Daniel N. Woodruff, Matthew J. Bristow, Franz Lang, Peter J. Baker, Simon J. Clarke, Stephen J. Blundell

摘要:

我们已经进行了横向和零场μ子自旋旋转/弛豫实验,以及磁力测量,样品的Fe 1-xVxSe和它们的Li+NH3插入Li 0.6(NH 2)0.2(NH3)0.8 Fe 1-x Vx Se。我们研究了低钒取代制度:x = 0.005,0.01和0.02。插层反应显著地提高了所有x的临界温度(Tc)和超流刚度。非插层样品的Tc均为8.5 K,而插层样品的Tc均大于40 K。钒取代对Tc的影响可以忽略不计,但似乎抑制了非插层样品的超流刚度,并微弱地增强了插层材料的超流刚度。插层样品的最佳取代度为x = 0.01,Tc = 41 K,λ ab(0)= 0.18 μm。的nonintercalated样品可以建模与一个单一的d-波超导能隙或与各向异性的间隙功能的基础上最近的准粒子成像实验,而嵌入显示多间隙节点的行为,可以使用s + d-或d + d-波模型拟合。磁性,可能来自铁杂质,在嵌入反应后出现,并与超导性共存和竞争。然而,似乎超导性对杂质相具有显著的鲁棒性,提供了稳定改善过渡金属取代的FeSe的超导性质的途径。

英文摘要:

We have performed transverse- and zero-field muon spin rotation/relaxation experiments, as well as magnetometry measurements, on samples of Fe1-xVxSe and their Li+NH3 intercalates Li0.6(NH2)0.2(NH3)0.8 Fe1-x Vx Se. We examine the low vanadium substitution regime: x = 0.005, 0.01, and 0.02. The intercalation reaction significantly increases the critical temperature (Tc) and the superfluid stiffness for all x. The nonintercalated samples all exhibit Tc = 8.5 K while the intercalated samples all show an enhanced Tc > 40 K. Vanadium substitution has a negligible effect on Tc, but seems to suppress the superfluid stiffness for the nonintercalated samples and weakly enhance it for the intercalated materials. The optimal substitution level for the intercalated samples is found to be x = 0.01, with Tc = 41 K and λ_{ab}(0) = 0.18 μm. The nonintercalated samples can be modeled with either a single d-wave superconducting gap or with an anisotropic gap function based on recent quasiparticle imaging experiments, whereas the intercalates display multigap nodal behavior which can be fitted using s + d- or d + d-wave models. Magnetism, likely from iron impurities, appears after the intercalation reaction and coexists and competes with the superconductivity. However, it appears that the superconductivity is remarkably robust to the impurity phase, providing an avenue to stably improve the superconducting properties of transition metal substituted FeSe.

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