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arXiv 2003.02504cond-mat.mtrl-sci
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Keto-enol tautomerization drives the self-assembly of Leucoquinizarin on Au(111)

Roberto Costantini, Luciano Colazzo, Laura Batini, Matus Stredansky, Mohammed S. G. Mohammed, Simona Achilli, Luca Floreano, Guido Fratesi, Dimas G. de Oteyza, Albano Cossaro

英文摘要:

The self-assembly of Leucoquinizarin molecule on Au(111) surface is shown to be characterized by the molecules mostly in their keto-enolic tautomeric form, with evidences of their temporary switching to other tautomeric forms. This reveals a metastable chemistry of the assembled molecules, to be considered for their possible employment in the formation of more complex hetero-organic interfaces

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