Active fluids, which are driven at the microscale by non-conservative forces, are known to exhibit novel transport phenomena due to the breaking of time reversal symmetry. Recently, Epstein and Mandadapu [arXiv:1907.10041] obtained Green-Kubo relations for the full set of viscous coefficients governing isotropic chiral active fluids, including the so-called odd viscosity, invoking Onsager's regression hypothesis for the decay of fluctuations in active non-equilibrium steady states. In this Communication, we test these Green-Kubo relations using molecular dynamics simulations of a canonical model system consisting of actively torqued dumbbells. We find the resulting odd and shear viscosity values from the Green-Kubo relations to be in good agreement with values measured independently through non-equilibrium molecular dynamics (NEMD) flow simulations. This provides a test of the Green-Kubo relations, and lends support to the application of the Onsager regression hypothesis in relation to viscous behaviors of active matter systems.
Non-equilibrium Molecular Dynamics (NEMD) calculations of the bulk viscosity of the triple point Lennard-Jones fluid are performed with the aim of investigating the origin of the observed disagreement between Green-Kubo estimates and previous NEMD data. We show that a careful application of the Doll's perturbation field, the dynamical NEMD method, the instantaneous form of the perturbation and the "subtraction technique" provides a NEMD estimate of the bulk viscosity at zero field in full agreement with the value obtained by the Green-Kubo formula. As previously reported for the shear viscosit…
In this article, we compare the results of non-equilibrium (NEMD) and equilibrium (EMD) molecular dynamics methods to compute the thermal conductance at the interface between solids. We propose to probe the thermal conductance using equilibrium simulations measuring the decay of the thermally induced energy fluctuations of each solid. We also show that NEMD and EMD give generally speaking inconsistent results for the thermal conductance: Green Kubo simulations probe the Landauer conductance between two solids which assumes phonons on both sides of the interface to be at equilibrium. On the oth…
The bulk viscosity of two-component fermions with a zero-range interaction is revisited both in two and three dimensions. We first point out that the "standard" Kubo formula employed in recent studies has flaws to give rise to an unphysical divergent bulk viscosity even in a limit where it is supposed to vanish. The corrected Kubo formula as well as the sum rule is then carefully rederived so as to confirm that the bulk viscosity indeed vanishes in the free, unitarity, and dimer limits. We also discuss that the recently found discrepancy between the Kubo formalism and the kinetic theory for th…
We derive from first principles the Kubo formulas for the stress-stress response function at zero wavevector that can be used to define the full complex frequency-dependent viscosity tensor, both with and without a uniform magnetic field. The formulas in the existing literature are frequently incomplete, incorrect, or lack a derivation; in particular, Hall viscosity is overlooked. Our approach begins from the response to a uniform external strain field, which is an active time-dependent coordinate transformation in d space dimensions. These transformations form the group GL(d,R) of invertible …
Shear viscosity of the classical $Φ^4$ theory is measured using classical microcanonical simulation. To calculate the Kubo formula, we measure the energy-momentum tensor correlation function, and apply the Green-Kubo relation. Being a classical theory, the results depend on the cutoff which should be chosen in the range of the temperature. Comparison with experimentally accessible systems is also performed.
For a quantum system in a steady state with a constant current of heat or particles driven by a temperature or chemical potential difference between two reservoirs attached to the system, the fluctuation theorem for the current was previously shown to lead to the Green-Kubo formula for the linear response coefficient for the current expressed in terms of the symmetrized correlation function of the current density operator. In this article, we show that for a quantum system in a steady state with a constant rate of work done on the system, the fluctuation theorem for a quantity induced in the s…
By combining confocal microscopy and Stress Assessment from Local Structural Anisotropy (SALSA), we directly measure stresses in 3D quiescent colloidal liquids. Our non-invasive and non-perturbative method allows us to measure forces $\lesssim$ 50 fN with a small and tunable probing volume, enabling us to resolve the stress fluctuations arising from particle thermal motions. We use the Green-Kubo relation to relate these measured stress fluctuations to the bulk Brownian viscosity at different volume fractions and comparing against simulations and conventional rheometry measurements. We demonst…
We study the rheological signatures of departure from equilibrium in two-dimensional viscous fluids with and without internal spin. Under the assumption of isotropy, we provide the most general linear constitutive relations for stress and couple stress in terms of the velocity and spin fields. Invoking Onsager's regression hypothesis for fluctuations about steady states, we derive the Green-Kubo formulae relating the transport coefficients to time correlation functions of the fluctuating stress. In doing so, we verify the claim that one of the non-equilibrium transport coefficients, the odd-vi…
We study the friction coefficient of a macroscopic sphere in a viscous fluid at low Reynolds number. First, Kirkwood's formula for the friction coefficient is reviewed on the basis of the Hamiltonian description of particle systems. According to this formula, the friction coefficient is expressed in terms of the stress correlation on the surface of the macroscopic sphere. Then, with the aid of large deviation theory, we relate the surface stress correlation to the stress correlation in the bulk of the fluid, where the latter is characterized by the viscosity in the Green-Kubo formula. By combi…
Diffusive transport is characterized by a diffusivity tensor which may, in general, contain both a symmetric and an antisymmetric component. Although the latter is often neglected, we derive Green-Kubo relations showing it to be a general characteristic of random motion breaking time-reversal and parity symmetries, as encountered in chiral active matter. In analogy with the odd viscosity appearing in chiral active fluids, we term this component the odd diffusivity. We show how odd diffusivity emerges in a chiral random walk model, and demonstrate the applicability of the Green-Kubo relations t…
We propose a new method, the Helfand-moment method, to compute the shear viscosity by equilibrium molecular dynamics in periodic systems. In this method, the shear viscosity is written as an Einstein-like relation in terms of the variance of the so-called Helfand moment. This quantity, is modified in order to satisfy systems with periodic boundary conditions usually considered in molecular dynamics. We calculate the shear viscosity in the Lennard-Jones fluid near the triple point thanks to this new technique. We show that the results of the Helfand-moment method are in excellent agreement with…
The shear viscosity coefficient and the corresponding relaxation time for causal dissipative hydrodynamics are calculated based on the microscopic formula proposed in [T. Koide and T. Kodama, Phys. Rev. \textbf{E 78}, 051107 (2008)]. Here, the exact formula is transformed into a more compact form and applied it to evaluate these transport coefficients in the chiral perturbation theory and perturbative QCD. It is shown that in the leading order calculation, the causal shear viscosity coefficient $η$ reduces to that of the ordinary Green-Kubo-Nakano formula, and the relaxation time $τ_π$ is rela…
Einstein equations projected on to a black hole horizon gives rise to Navier-Stokes equations. Horizon-fluids typically possess unusual features like negative bulk viscosity and it is not clear whether a statistical mechanical description exists for such fluids. In this work, we provide an explicit derivation of the Bulk viscosity of the horizon-fluid based on the theory of fluctuations a la Kubo. The main advantage of our approach is that our analysis remains for the most part independent of the details of the underlying microscopic theory and hence the conclusions reached here are model inde…
We investigate the shear viscosity of massless classical scalar fields in the $ϕ^4$ theory on a lattice by using the Green-Kubo formula. Based on the scaling property of the classical field, the shear viscosity is represented using a scaling function. Equilibrium expectation value of the time-correlation function of the energy-momentum tensor is evaluated as the ensemble average of the classical field configurations, whose time evolution is obtained by solving the classical equation of motion starting from the initial condition in thermal equilibrium. It is found that there are two distinct da…
Second-order phase transitions are characterized by a divergence of the spatial correlation length of the order parameter fluctuations. For confined systems, this is known to lead to remarkable equilibrium physical phenomena, including finite-size effects and critical Casimir forces. We explore here some non-equilibrium aspects of these effects in the stationary state resulting from the action of external forces: by analyzing a model of a correlated fluid under shear, spatially confined by two parallel plates, we study the resulting viscosity within the setting of (Gaussian) Landau-Ginzburg th…
Inspired by recent experiments on graphene, we examine the non-dissipative viscoelastic response of anisotropic two-dimensional quantum systems. We pay particular attention to electron fluids with point group symmetries, and those with discrete translational symmetry. We start by extending the Kubo formalism for viscosity to systems with internal degrees of freedom and discrete translational symmetry, highlighting the importance of properly considering the role of internal angular momentum. We analyze the Hall components of the viscoelastic response tensor in systems with discrete point group …
The Green-Kubo-Nakano formula should be modified in relativistic hydrodynamics because of the problem of acausality and the breaking of sum rules. In this work, we propose a formula to calculate the transport coefficients of causal hydrodynamics based on the projection operator method. As concrete examples, we derive the expressions for the diffusion coefficient, the shear viscosity coefficient, and corresponding relaxation times.
Using the second law of local thermodynamics and the first-order Palatini formalism, we formulate relativistic spin hydrodynamics for quantum field theories with Dirac fermions, such as QED and QCD, in a torsionful curved background. We work in a regime where spin density, which is assumed to relax much slower than other non-hydrodynamic modes, is treated as an independent degree of freedom in an extended hydrodynamic description. Spin hydrodynamics in our approach contains only three non-hydrodynamic modes corresponding to a spin vector, whose relaxation time is controlled by a new transport …
In this paper, we examine the viscoelastic properties of integer quantum Hall (IQH) states in a tilted magnetic field. In particular, we explore to what extent the tilted-field system behaves like a two-dimensional electron gas with anisotropic mass in the presence of strain deformations. We first review the Kubo formalism for viscosity in an external magnetic field, paying particular attention to the role of rotational symmetry and contact terms. Next, we compute the conductivity, stress, and viscosity tensors for IQH states in the presence of a tilted field and vertical confining potential. …
We discuss the roles of viscosity in relativistic fluid dynamics from the point of view of memory effects. Depending on the type of quantity to which the memory effect is applied, different terms appear in higher order corrections. We show that when the memory effect applies on the extensive quantities, the hydrodynamic equations of motion become non-singular. We further discuss the question of memory effect in the derivation of transport coefficients from a microscopic theory. We generalize the application of the Green-Kubo-Nakano (GKN) to calculate transport coefficients in the framework of …
