The gap structure of a novel uranium-based superconductor UTe$_2$, situated in the vicinity of ferromagnetic quantum criticality, has been investigated via specific-heat $C(T,H,Ω)$ measurements in various field orientations. Its angular $Ω(ϕ,θ)$ variation shows a characteristic shoulder anomaly with a local minimum in $H \parallel a$ at moderate fields rotated within the $ab$ and $ac$ planes. Based on the theoretical calculations, these features can be attributed to the presence of point nodes in the superconducting gap along the $a$ direction. Under the field orientation along the easy-magnetization $a$ axis, an unusual temperature dependence of the upper critical field at low fields together with a convex downward curvature in $C(H)$ were observed. These anomalous behaviors can be explained on the basis of a nonunitary triplet state model with equal-spin pairing whose $T_{\rm c}$ is tuned by the magnetization along the $a$ axis. From these results, the gap symmetry of UTe$_2$ is most likely described by a vector order parameter of $d(k)=(b + ic)(k_b + ik_c)$.
Motivated by the recent discovery of superconductivity in UTe$_2$, we analyze the stability and nodal structure of various triplet superconducting order parameters. Using a combination of symmetry group-theoretical analysis, phenomenological Landau free energy and weak-coupling BCS theory, we show that chiral nonunitary superconducting order can be stabilized on the border of ferromagnetism in UTe$_2$, even in the absence of long-range magnetic order. We further perform first principles density functional theory (DFT) calculations of the so-called "small" Fermi surface, excluding the contribut…
A stationary Josephson effect in a weak-link between misorientated nonunitary triplet superconductors is investigated theoretically. The non-self-consistent quasiclassical Eilenberger equation for this system has been solved analytically. As an application of this analytical calculation, the current-phase diagrams are plotted for the junction between two nonunitary bipolar $f-$wave superconducting banks. A spontaneous current parallel to the interface between superconductors has been observed. Also, the effect of misorientation between crystals on the Josephson and spontaneous currents is stud…
Nonunitary triplet superconductivity in the Z2 topological metal SrPd2As2
University of Petroleum and Energy Studies（石油能源大学）；Indian Institute of Technology, Kanpur（坎普尔印度理工学院）；Ariel University（阿里埃勒大学）；Rutherford Appleton Laboratory（卢瑟福阿普顿实验室）；University of Johannesburg（约翰内斯堡大学）；Jawaharlal Nehru Centre for Advanced Scientific Research（贾瓦哈拉尔·尼赫鲁高级科学研究中心）；Ramakrishna Mission Vivekananda Educational and Research Institute（罗摩克里希纳使命维韦卡南达教育与研究机构）
Distinguishing nodal and nonunitary superconductivity in quasiparticle interference of an Ising superconductor with Rashba spin-orbit coupling: an example of NbSe$_2$
The space-group approach to the wavefunction of a Cooper pair is extended to Shubnikov groups of type III and applied to newly discovered nearly ferromagnetic superconductor UTe2. A nonunitary triplet SOP (superconducting order parameter), manifested experimentally, was obtained for Shubnikov group m'm'm . The nodal structure of triplet nonunitary SOP is investigated and it was shown that in the case of Shubnikov III symmetry nodal structure of ESP (equal spin pairing) state is in some cases unstable, i.e. changes when a complex phase winding is added. The irreducible corepresentations of a Co…
Hund's coupling in multiorbital systems allows for the possibility of even-parity orbital-antisymmetric spin-triplet pairing, which can be stabilized by spin-orbit coupling (SOC). While this pairing expressed in the orbital basis is uniform and spin-triplet, it appears in the band basis as a pseudospin-singlet, with the momentum dependence determined by the SOC and the underlying triplet character remaining in the form of interband pairing active away from the Fermi energy. Here, we examine the role of momentum-dependent SOC in generating nontrivial pairing symmetries, as well as the hidden tr…
It is developed a microscopic description of superconductivity in ferromagnetic materials with triplet pairing triggered by the exchange of magnetic fluctuations. Instead widely used paramagnon model we work with phenomenological spectrum of fluctuations in the orthorhombic ferromagnet with strong magnetic anisotropy. Depending of the field orientation parallel or perpendicular to the direction of spontaneous magnetization the effective amplitude of pairing interaction proves to be decreasing or increasing function of magnetic field that allows to explain the drastic difference in magnitudes o…
Odd-frequency Cooper pairs are gathering attention for the convenience of investigating the edge state of topological superconductors including Majorana fermions. Although a spinless p-wave superconductor has only one Majorana fermion in a topological phase, the system with magnetic fields can reach the topological phases with multiple Majorana fermions. To distinguish these multiple Majorana fermion phases, we correlate the energy spectrum with the odd-frequency pair amplitude as increasing the system size. The system size dependence tells us three pieces of information: the parity of the num…
We propose a microscopic mechanism for triplet pairing due to spin-orbit-assisted electron interaction with optical phonons in a crystal with a complex unit cell. Using two examples of electrons with symmetric Fermi surfaces in crystals with either a cubic or a layered square lattice, we show that spin-orbit-assisted electron-phonon coupling can, indeed, generate triplet pairing and that, in each case, it predetermines the tensor structure of a p-wave order parameter.
We show within the dynamical mean field theory that local multiplet interactions such as Hund's rule coupling produce local pairing superconductivity in the strongly correlated regime. Spin-triplet superconductivity driven by the Hund's rule coupling emerges from the pairing mediated by local fluctuations in pair exchange. In contrast to the conventional spin-triplet theories, the local orbital degrees of freedom has the anti-symmetric part of the exchange symmetry, leaving the spatial part as fully gapped and symmetric s-wave.
We show that the newly discovered BiS$_2$-based superconductors may have a dominant triplet pairing component, in addition to a subdominant singlet component arising from the spin-orbital coupling. The pairing respects time-reversal symmetry. The dominant triplet gap causes gap sign changes between the spin-split Fermi pockets. Within a pocket, the gap function respects $d^*_{x^2-y^2}$-wave symmetry, where the star indicates joint spin-lattice rotations. Below the Lifshitz filling level the gap is nodelss and the superconducting state is weak topological. Above the Lifshitz points the gap beco…
Recent experiments in quantum critical heavy fermion metals have pushed to the fore the question about whether antiferromagnetic fluctuations can promote both spin-singlet and spin-triplet superconductivity. Here we address the issue through non-perturbative calculations in antiferromagnetically correlated Kondo systems. We identify Kondo-destruction quantum critical points in both the SU(2) symmetric and Ising-anisotropic cluster Bose-Fermi Anderson models. The spin-singlet pairing correlations are significantly enhanced near the quantum critical point in the SU(2) case; however, with adequat…
We show that an additional triplet component of the order parameter is generated in the vortex phase of the d-wave superconductor. Spatial variations of the triplet component are analyzed for a strong spin-orbit coupling. Corrections to the London equation and an unusual temperature dependence of the upper critical field, are obtained in the case of the weak spin-orbit coupling.
We present a microscopic theory of fluctuation-mediated pairing mechanism in organic superconductors ${(TMTSF)}_{2}X$, where the experimentally observed coexistence of $2k_{F}$ charge fluctuation and $2k_{F}$ spin fluctuation is naturally taken into account. We have studied, within the random phase approximation, the extended Hubbard model at quarter-filling on a quasi-one-dimensional lattice, where we consider the off-site repulsive interaction up to third next nearest neighbors along with the on-site repulsion. The results show that spin-triplet $f$-wave-like pairing can be realized in this …
Searching for triplet superconductivity has been pursued intensively in a broad field of material science and quantum information for decades. Nevertheless, these novel states remain rare. Within a simplified effective three-orbital model, we reveal a spin triplet pairing in doped MoS$_2$ by employing both the finite temperature determinant quantum Monte Carlo approach and the ground state constrained-phase quantum Monte Carlo method. In a wide filling region of $\avg{n}=0.60-0.80$ around charge neutrality $\avg{n}=2/3$, the $f$-wave pairing dominates over other symmetries. The pairing suscept…
Nonunitary superconductivity has attracted renewed interest as a novel gapless phase of matter. In this study, we investigate the superconducting gap structure of nonunitary odd-parity chiral pairing states in a superconductor involving strong spin-orbit interactions. By applying a group theoretical classification of chiral states in terms of discrete rotation symmetry, we categorized all possible point-nodal gap structures in nonunitary chiral states into four types in terms of the topological number of nodes and node positions relative to the rotation axis. In addition to conventional Dirac …
Recent experiments on the organic compound κ-(ET)_2Cu_2(CN)_3 have provided a promising example of a two dimensional spin liquid state. This phase is described by a two-dimensional spinon Fermi sea coupled to a U(1) gauge field. We study Kohn-Luttinger-like pairing instabilities of the spinon Fermi surface due to singular interaction processes with twice-the-Fermi-momentum transfer. We find that under certain circumstances the pairing instability occurs in odd-orbital-angular-momentum/spin-triplet channels. Implications to experiments are discussed.
We investigate the twisted bilayer graphene by a two-orbital Hubbard model on the honeycomb lattice. The model is studied near 1/4 band filling by using the singular-mode functional renormalization group theory. Spin-triplet $f$-wave pairing is found from weak to moderate coupling limit of the local interactions, and is associated with the Hund's rule coupling and incommensurate spin fluctuations at moderate momenta.
Using a renormalization group approach, we determine the phase diagram of an extended quasi-one-dimensional electron gas model that includes interchain hopping, nesting deviations and both intrachain and interchain repulsive interactions. We find a close proximity of spin-density- and charge-density-wave phases, singlet d-wave and triplet f-wave superconducting phases. There is a striking correspondence between our results and recent puzzling experimental findings in the Bechgaard salts, including the coexistence of spin-density-wave and charge-density-wave phases and the possibility of a trip…
In order to probe the effect of charge fluctuations on triplet pairing, we study the pairing symmetry in the one-band Hubbard model having the off-site Coulomb repulsion ($V$) on top of the on-site repulsion as a model for the $γ$ band of Sr$_2$RuO$_4$, a strong candidate for triplet pairing superconductor. The result, obtained with the dynamical cluster approximation combined with the quantum Monte-Carlo method, and confirmed from the fluctuation exchange approximation, shows that while $d_{x^2-y^2}$-pairing dominates over $p$ in the absence of $V$, introduction of $V$ makes $p_{x+y}$ and $d_…
We propose a two-dimensional exciton model showing the possibility of two-exciton pairing in cuprates, both in singlet and in triplet states. The former is assumed to be responsible for the superconductivity and the latter for the unusual normal state properties. The ground state is found to be a projection of the Bose condensation of N/2 mobile bosons with a ηprojection operator which is a generalization of the Gutzwiller projection operator. The phase diagram of the model shows insulator-superconductivity and superconductivity-metal transitions with doping.
Spin-orbit coupling (SOC) plays a crucial role in determining the spin structure of an odd parity psedospin-triplet Cooper pairing state. Here, we present a thorough study of how SOC lifts the degeneracy among different p-wave pseudospin-triplet pairing states in a widely used microscopic model for $\mathrm{Sr_2 Ru O_4}$, combining a Ginzburg-Landau (GL) free energy expansion, a symmetry analysis of the model, and numerical weak-coupling renormalization group (RG) and random phase approximation (RPA) calculations. These analyses are then used to critically re-examine previous numerical results…
In the present paper, we propose the parity even,orbital singlet and spin triplet pairing state as the ground state of the newly discovered super-conductor $LaO_{1-x}F_xFeAs$.The pairing mechanism involves both the special shape of the electron fermi surface and the strong ferromagnetic fluctuation induced by Hund's rule coupling.The special behavior of the Bogoliubov quasi-particle spectrum may leads to "Fermi arc" like anisotropy super-conducting gap, which can be detected by angle resolved photo emission(ARPES).The impurity effects are also discussed.
Within a multicomponent BCS-like framework we study the coexistence and competition of various CDW and SC order parameters in the presence of a strong ferromagnetic background. We find that the competition of unconventional CDW, also called orbital antiferromagnet, with SC at finite momentum (${\bf Q}$-triplet pairing) shows unique characteristics like an extreme sensitivity on the deviations from nesting. We argue that pressure in UGe$_2$ creates deviations from the nesting and report a phase diagram in qualitative agreement with the observed behavior of UGe$_2$.
We study spin-half fermions in a one-dimensional extended Hubbard chain at low filling. We identify three triplet and one singlet pairing channels in the system, which are independently tunable as a function of nearest-neighbor charge and spin interactions. In a large-size system with translational invariance, we derive gap equations for the corresponding pairing gaps and obtain a Bogoliubov-de Gennes Hamiltonian with its non-trivial topology determined by the interplay of these gaps. In an open-end system with a fixed number of particles, we compute the exact many-body ground state and identi…
We study the dynamical spin susceptibility, $χ({\bf q}, ω)$, in the normal and superconducting state of Sr$_2$RuO$_4$. In the normal state, we find a peak in the vicinity of ${\bf Q}_i\simeq (0.72π,0.72π)$ in agreement with recent inelastic neutron scattering (INS) experiments. We predict that for spin triplet pairing in the superconducting state a {\it resonance peak} appears in the out-of-plane component of $χ$, but is absent in the in-plane component. In contrast, no resonance peak is expected for spin singlet pairing.
We investigate superconducting pairing driven by electron-electron interactions in a theoretical model for monolayer MoS$_2$ with the temperature-flow functional renormalization group(fRG). At low doping, the dominant instability is toward odd-parity pairing with $f$-wave Mo-nearest-neighbor structure. We compute the fRG phase diagram versus electron doping below the van Hove filling of the conduction band. In the superconducting regime, the critical temperature grows with doping, comparable to the experiments. Near van Hove filling the system favors a ferromagnetic state. We demonstrate that …
We show that when spin and orbital angular momenta are entangled by spin-orbit coupling, this transforms a topological spin-triplet superfluid/superconductor state, such as $^{3}$He-B, into a topological $s^{\pm}$ state, with non-trivial gapless edge states. Similar to $^{3}$He-B, the $s^{\pm}$ state also minimizes on-site Coulomb repulsion for weak to moderate interactions. A topological phase transition into a $d$-wave state occurs for sufficiently strong spin-orbit coupling.
We study the possible superconducting pairing symmetry mediated by spin and charge fluctuations on the honeycomb lattice using the extended Hubbard model and the random-phase-approximation method. From $2\%$ to $20\%$ doping levels, a spin-singlet $d_{x^{2}-y^{2}}+id_{xy}$-wave is shown to be the leading superconducting pairing symmetry when only the on-site Coulomb interaction $U$ is considered, with the gap function being a mixture of the nearest-neighbor and next-nearest-neighbor pairings. When the offset of the energy level between the two sublattices exceeds a critical value, the most fav…
Muon spin rotation and relaxation experiments on the centrosymmetric intermetallic superconductor LaNiGa$_2$ are reported. The appearance of spontaneous magnetic fields coincides with the onset of superconductivity, implying that the superconducting state breaks time reversal symmetry, similarly to non-centrosymmetric LaNiC$_2$. Only four triplet states are compatible with this observation, all of which are non-unitary triplets. This suggests that LaNiGa$_2$ is the centrosymmetric analogue of LaNiC$_2$. We argue that these materials are representatives of a new family of paramagnetic non-unita…
Using an RPA approximation, we have calculated the strengths of the singlet and triplet pairing interactions which arise from the exchange of spin and orbital fluctuations for a 2-orbital model of the Fe-pnictide superconductors. When the system is doped with F, the electron pockets become dominant and we find that the strongest pairing occurs in the singlet d-wave pairing and the triplet p-wave pairing channels, which compete closely. The pairing structure in the singlet d-wave channel corresponds to a superposition of near neighbor intra-orbital singlets with a minus sign phase difference be…
We present precise measurements of the upper critical field (Hc2) in the recently discovered cobalt oxide superconductor. We have found that the critical field has an unusual temperature dependence; namely, there is an abrupt change of the slope of Hc2(T) in a weak field regime. In order to explain this result we have derived and solved Gor'kov equations on a triangular lattice. Our experimental results may be interpreted in terms of the field-induced transition from singlet to triplet superconductivity.
We study pairing symmetry of noncentrosymmetric superconductors based on the extended Hubbard model on square lattice near half-filling, using the random phase approximation. We show that d+f-wave pairing is favored and the triplet f-wave state is enhanced by Rashba type spin-orbit coupling originating from the broken inversion symmetry. The enhanced triplet superconductivity stems from the increase of the effective interaction for the triplet pairing and the reduction of the spin susceptibility caused by the Rashba type spin-orbit coupling which lead to the increase of the triplet component a…
Triplet pairing, orbital selectivity and correlations in Iron-based superconductors
University of Cincinnati（辛辛那提大学）；Max-Planck-Institut für Festkörperforschung（马克斯·普朗克固体研究所）；Rutgers University（罗格斯大学）；Royal Holloway, University of London（伦敦大学皇家霍洛威学院）
The antiferromagnetic Fulde-Ferrell-Larkin-Ovchinnikov (AFM-FFLO) state of coexisting d-wave FFLO superconductivity and incommensurate AFM order is studied on the basis of Bogoliubov-de Gennes (BdG) equations. We show that the incommensurate AFM order is stabilized in the FFLO state by the appearance of the Andreev bound state localized around the zeros of the FFLO order parameter. The AFM-FFLO state is further enhanced by the induced π-triplet superconductivity (pair density wave). The AFM order occurs in the FFLO state even when it is neither stable in the normal state nor in the BCS state. …
The microscopic origin of triplet superconductivity in Sr$_2$RuO$_4$ is discussed, paying attention to the role of Coulomb interaction, $U_{pp}$, at the O site. It is shown on the $d$-$p$ model that $U_{pp}$ induces a ferromagnetic exchange interaction between "d-electrons" (molecular orbital with $d_{xy}$-symmetry) at adjacent Ru sites, leading to short-range ferromagnetic correlations and promoting Cooper pairing with ($\sin p_x\pm\ii\sin p_y$)-symmetry on the $γ$-band. The reason why such ferromagnetic correlations work effectively may be traced back to the fact that the level of 4d-electro…
We demonstrate the stability of a spin-triplet paired s-wave (with an admixture of extended s-wave) state for the case of purely repulsive interactions in a degenerate two-band Hubbard model. We further show that near half-filling the considered kind of superconductivity can coexist with antiferromagnetism. The calculations have been carried out with the use of the so-called statistically consistent Gutzwiller approximation for the case of a square lattice. The absence of a stable paired state when analyzed in the Hartree-Fock-BCS approximation allows us to claim that the electron correlations…
Different models for doping of two-orbital chains with mobile $S=1/2$ fermions and strong, ferromagnetic (FM) Hund's rule couplings stabilizing the S=1 spins are investigated by density matrix renormalization group (DMRG) methods. The competition between antiferromagnetic (AF) and FM order leads to a rich phase diagram with a narrow FM region for weak AF couplings and strongly enhanced triplet pairing correlations. Without a level difference between the orbitals, the spin gap persists upon doping, whereas gapless spin excitations are generated by interactions among itinerant polarons in the pr…
Effects of short-range correlations on the Coulomb screening, the phonons, and the pairing interactions are examined in electron-phonon systems. First, we derive a model Hamiltonian of Coulomb interactions which includes both the long-range part v_q and the short-range part U. It is found from the expression of the dielectric function that the strong on-site correlations weaken the Coulomb screening. Secondly, we examine the screened phonons and the interaction mediated by phonons. In a consistent picture, we derive an expression of the effective interaction which includes (1) the screened Cou…
In quantum materials, the electronic interaction and the electron-phonon coupling are, in general, two essential ingredients, the combined impact of which may drive exotic phases. Recently, an anomalously strong electron-electron attraction, mediated by phonons, has been unveiled in one-dimensional copper-oxide chain Ba$_{2-x}$Sr$_x$CuO$_{3+δ}$. Yet, it is unclear how this strong near-neighbor attraction $V$ influences the superconductivity pairing in the compound. Here we perform accurate many-body calculations to study the extended Hubbard model with on-site Coulomb repulsion $U>0$ and attra…
We study the effect of the magnetic field (Zeeman splitting) on the triplet pairing. We show generally that the enhancement of spin triplet pairing mediated by coexisting $2k_F$ spin and $2k_F$ charge fluctuations can be much larger than in the case of triplet pairing mediated by ferromagnetic spin fluctuations. We propose that this may be related to the recent experiment for (TMTSF)$_2$ClO$_4$, in which a possibility of singlet to triplet pairing transition has been suggested.
Nuclear magnetic resonance (NMR) measurements on the $^{195}$Pt nucleus in an aligned powder of the moderately heavy-fermion material U2PtC2 are consistent with spin-triplet pairing in its superconducting state. Across the superconducting transition temperature and to much lower temperatures, the NMR Knight shift is temperature independent for field both parallel and perpendicular to the tetragonal c-axis, expected for triplet equal-spin pairing superconductivity. The NMR spin-lattice relaxation rate 1/T$_1$, in the normal state, exhibits characteristics of ferromagnetic fluctuations, compatib…
Motivated by the possible non-spin-singlet superconductivity in the magic-angle twisted trilayer graphene experiment, we investigate the triplet-pairing superconductivity arising from a correlation-induced spin-fermion model on a honeycomb lattice. We find that the $f$-wave pairing is favored due to the valley-sublattice structure, and the superconducting state is time-reversal symmetric, fully gapped, and non-topological. With a small in-plane magnetic field, the superconducting state becomes partially polarized, and the transition temperature can be slightly enhanced. Our results apply quali…
In noncentrosymmetric superconductors (NCSs), the conversion of a charge current into spin magnetization - the so called magnetoelectric effect - is the direct indicator of the unconventional, mixed-parity order parameter. This paper proposes a scheme to detect the magnetoelectric effect by anomalous, equal-spin Andreev tunneling in NCS/ferromagnet contacts. The proposal relies on the ability to generate spin-polarized triplet pairing by passing an electric current through an NCS. Such an induced triplet pairing bears a similarity to the paradigmatic nonunitary pairing in triplet superfluids w…
A prime category of superconducting materials in which to look for spin-triplet pairing and topological superconductivity are superconductors without inversion symmetry. It is predicted that the breaking of parity symmetry gives rise to an admixture of spin-singlet / spin-triplet pairing states; a triplet pairing component, being substantial, seems all but guaranteed. However, the experimental confirmation of pair mixing in any particular material remains elusive. In this work, we perform phase-sensitive experiment to examine the pairing state of noncentrosymmetric superconductor $α-$BiPd. The…
Quasi-low-dimensional type II superconductors in parallel magnetic fields are studied when singlet pairing interactions and relatively weak triplet pairing interactions coexist. Singlet and triplet components of order parameter are mixed at high fields, and at the same time an inhomogeneous superconducting state called a Fulde-Ferrell-Larkin-Ovchinnikov state occurs. As a result, the triplet pairing interactions enhance the upper critical field of superconductivity remarkably even at temperatures far above the transition temperature of parallel spin pairing. It is found that the enhancement is…
We have investigated the proximity effect in superconductor/ferromagnet junctions in a systematic manner to discuss the relationship between the zero-energy peak (ZEP) of the local density of states (LDOS) and spin-triplet odd-frequency pairing. By exactly solving the nonlinear Usadel equations, we have found that the ZEP is realized in a wide range of geometrical and material parameters in the case of the noncollinear magnetization. This strongly suggests the robustness of the ZEP induced by spin-triplet odd-frequency pairing in such systems. We also found that the crossover from singlet pair…
The superconducting state in uranium compounds UGe2, URhGe and UCoGe is formed at temperatures far below the Curie temperature pointing on nonconventional nature of superconductivity in these materials - namely the superconductivity with triplet pairing. The emergence of superconductivity is accompanied by the slight magnetization expulsion typical for the type-II superconductors. Following classic Abrikosov paper I develop the theory of type-II superconductivity in application to two-band ferromagnetic metal with equal spin triplet pairing.
