Disparate exciton-phonon couplings for zone center and boundary phonons in solid-state graphite

High-energy excitonic effects in graphite and graphene

We present ab initio many-body calculations of the optical absorption in bulk graphite, graphene and bilayer of graphene. Electron-hole interaction is included solving the Bethe-Salpeter equation on top of a GW quasiparticle electronic structure. For all three systems, we observe strong excitonic effects at high energy, well beyond the continuum of π-> π* transitions. In graphite, these affect the onset of σ-> σ* transitions. In graphene, we predict an excitonic resonance at 8.3 eV arising from a background continuum of dipole forbidden transitions. In the graphene bilayer, the resonance is sh…

石墨中振动修饰核心激子的超快动力学：飞秒RIXS视角

Ultrafast dynamics of vibronically dressed core-excitons in graphite: a femtosecond RIXS perspective

本研究实现首批时间分辨共振非弹性X射线散射（tr-RIXS），用飞秒X射线脉冲研究石墨中振动修饰核心激子的超快动力学，揭示其与光学声子模式的瞬态耦合，确立tr-RIXS为阐明电子-晶格相互作用的变革性工具。

Tunable excitonic insulator in quantum limit graphite

Half a century ago, Mott noted that tuning the carrier density of a semimetal towards zero produces an insulating state in which electrons and holes form bound pairs. It was later argued that such pairing persists even if a semiconducting gap opens in the underlying band structure, giving rise to what has become known as the strong coupling limit of an `excitonic insulator.' While these `weak' and `strong' coupling extremes were subsequently proposed to be manifestations of the same excitonic state of electronic matter, the predicted continuity of such a phase across a band gap opening has not…

Observation of magneto-phonon resonance of Dirac fermions in graphite

Coherent coupling of Dirac fermion magneto-excitons with an optical phonon is observed in graphite as marked magnetic-field dependent splittings and anti-crossing behavior of the two coupled modes. The sharp magneto-phonon resonance occurs in regions of the graphite sample with properties of superior single-layer graphene having enhanced lifetimes of Dirac fermions. The greatly reduced carrier broadening to values below the graphene electron-phonon coupling constant explains the appearance of sharp resonances that reveal a fundamental interaction of Dirac fermions.

Direct imaging of the band profile in single layer ${\small MoS_2}$ on graphite: quasiparticle energy gap, metallic edge states and edge band bending

Using Scanning Tunneling Microscopy and Spectroscopy, we probe the electronic structures of single layer ${\small MoS_2}$ on graphite. We show that the quasiparticle energy gap of single layer ${\small MoS_2}$ is 2.15 $\pm$ 0.07 eV at 77 K. Combining with temperature dependent photoluminescence studies, we deduce an exciton binding energy of 0.22 $\pm$ 0.1 eV, a value that is much lower than current theoretical predictions. Consistent with theoretical predictions we directly observed metallic edge states of single layer ${\small MoS_2}$. In the bulk region of ${\small MoS_2}$, the Fermi level …

Splitting of interlayer shear modes and photon energy dependent anisotropic Raman response in $N$-layer ReSe$_2$ and ReS$_2$

We investigate the interlayer phonon modes in $N$-layer rhenium diselenide (ReSe$_2$) and rhenium disulfide (ReS$_2$) by means of ultralow-frequency micro-Raman spectroscopy. These transition metal dichalcogenides exhibit a stable distorted octahedral (1T') phase with significant in-plane anisotropy, leading to sizable splitting of the (in-plane) layer shear modes. The fan-diagrams associated with the measured frequencies of the interlayer shear modes and the (out-of-plane) interlayer breathing modes are perfectly described by a finite linear chain model and allow the determination of the inte…