sp2纳米碳的自旋化学
Spin chemistry of sp2 nanocarbons
摘要：
建议在该文件中的sp2纳米碳的稳定自由基的自旋离域拓扑化学的观点的考虑。其特征在于在总的和原子的有效未配对电子的数量以及后者在碳原子上的分布和描述的选择性确定的障碍不同的反应表现出拓扑本质的分子间相互作用，sp2纳米碳揭示了一个奇特的拓扑动力学，奠定了基础，其自由基性质的稳定性。
英文摘要：
Suggested in the paper is the consideration of stable radicals of sp2 nanocarbons from the standpoint of spin-delocalized topochemistry. Characterized in terms of the total and atomically-partitioned number of effectively unpaired electrons as well as of the distribution of the latter over carbon atoms and described by selectively determined barriers of different reactions exhibiting topological essence of intermolecular interaction, sp2 nanocarbons reveal a peculiar topokinetics that lays the foundation of the stability of their radical properties.
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