Almost all planetary atmospheres are affected by disequilibrium chemical processes. In this paper we introduce our recently developed Chemical Kinetic Model (\texttt{ChemKM}). We show that the results of our HD189733b model are in good agreement with previously published results, except at $μ$bar regime, where molecular diffusion and photochemistry are the dominant processes. We thus recommend careful consideration of these processes when abundances at the top of the atmosphere are desired. We also propose a new metric for a quantitative measure of quenching levels. By applying this metric, we find that quenching pressure decreases with the effective temperature of planets, but it also varies significantly with other atmospheric parameters such as [Fe/H], log(g), and C/O. In addition, we find that the "Methane Valley", a region between 800 and 1500K where above a certain C/O threshold value a greater chance of CH$_4$ detection is expected, still exists after including the vertical mixing. The first robust CH$_4$ detection on an irradiated planet (HD102195b) places this object within this region; supporting our prediction. We also investigate the detectability of disequilibrium spectral fingerprints by JWST, and suggest focusing on the targets with T$_{eff}$ between 1000 and 1800K, orbiting around M-dwarfs, having low surface gravity but high metallicity and a C/O ratio value around unity. Finally, constructing Spitzer color-maps suggests that the main two color-populations are largely insensitive to the vertical mixing. Therefore any deviation of observational points from these populations are likely due to the presence of clouds and not disequilibrium processes. However, some cold planets (T$_{eff}<$900K) with very low C/O ratios ($<$0.25) show significant deviations; making these planets interesting cases for further investigation.
Quantifying the differences in transmission and emission spectra for hot irradiated gaseous exoplanet atmospheres: A comparison of 1D and 3D modeling using JWST
A carbon-to-oxygen ratio (C/O) of around unity is believed to act as a natural separator of water- and methane-dominated spectra when characterizing exoplanet atmospheres. In this paper we quantify the C/O ratios at which this separation occurs by calculating a large self-consistent grid of cloud-free atmospheric models in chemical equilibrium, using the latest version of petitCODE. Our study covers a broad range of parameter space: 400 K$<$T$_{eff}<$2600 K, 2.0$<$log(g)$<$5.0, -1.0$<$[Fe/H]$<$2.0, 0.25$<$C/O$<$1.25, and stellar types from M to F. We make the synthetic transmission and emissio…
Small planets ($\sim$1--3.9 $\Rearth$) constitute more than half of the inventory of the 4000-plus exoplanets discovered so far. Smaller planets are sufficiently dense to be rocky, but those with radii larger than $\sim$1.6 $\Rearth$ are thought to display in many cases hydrogen/helium gaseous envelopes up to $\sim$30\% of the planetary mass. These low-mass planets are highly irradiated and the question of their origin, evolution, and possible links remains open. Here we show that close-in ocean planets affected by greenhouse effect display hydrospheres in supercritical state, which generate i…
Cold brown dwarfs are excellent analogs of widely separated, gas giant exoplanets, and provide insight into the potential atmospheric chemistry and physics we may encounter in objects discovered by future direct imaging surveys. We present a low resolution R $\sim$ 300 $M$-band spectroscopic sequence of seven brown dwarfs with effective temperatures between 750 K and 250 K along with Jupiter. These spectra reveal disequilibrium abundances of carbon monoxide (CO) produced by atmospheric quenching. We use the eddy diffusion coefficient (K$_{zz}$) to estimate the strength of vertical mixing in ea…
One of the most significant advances by NASA's ${\mathit Kepler}$ Mission was the discovery of an abundant new population of highly irradiated planets with sizes between the Earth and Neptune. Subsequent analysis showed that at ~1.5 Earth radii there is a transition from a population of predominantly rocky super-Earths to non-rocky sub-Neptunes, which must have substantial volatile envelopes. Determining the origin of these highly irradiated rocky planets will be critical to our understanding of low-mass planet formation and the frequency of potentially habitable Earth-like planets. These shor…
We present an open-source and validated chemical kinetics code for studying hot exoplanetary atmospheres, which we name VULCAN. It is constructed for gaseous chemistry from 500 to 2500 K using a reduced C-H-O chemical network with about 300 reactions. It uses eddy diffusion to mimic atmospheric dynamics and excludes photochemistry. We have provided a full description of the rate coefficients and thermodynamic data used. We validate VULCAN by reproducing chemical equilibrium and by comparing its output versus the disequilibrium-chemistry calculations of Moses et al. and Rimmer & Helling. It rep…
Observations suggest an abundance of water and paucity of methane in the majority of observed exoplanetary atmospheres. We isolate the effect of atmospheric processes to investigate possible causes. Previously, we studied the effect of effective temperature, surface gravity, metallicity, carbon-to-oxygen ratio, and stellar type assuming cloud-free thermochemical equilibrium and disequilibrium chemistry. However, under these assumptions, methane remains a persisting spectral feature in the transmission spectra of exoplanets over a certain parameter space, the Methane Valley. In this work we inv…
Spitzer Space Telescope infrared observations indicate that several transiting extrasolar giant planets have thermal inversions in their upper atmospheres. Above a relative minimum, the temperature appears to increase with altitude. Such an inversion probably requires a species at high altitude that absorbs a significant amount of incident optical/UV radiation. Some authors have suggested that the strong optical absorbers titanium oxide (TiO) and vanadium oxide (VO) could provide the needed additional opacity. However, if regions of the atmosphere are cold enough for Ti and V to be sequestered…
Aerosols appear to be ubiquitous in close-in gas giant atmospheres, and disequilibrium chemistry likely impacts the emergent spectra of these planets. Lofted aerosols and disequilibrium chemistry are caused by vigorous vertical transport in these heavily irradiated atmospheres. Here we numerically and analytically investigate how vertical transport should change over the parameter space of spin-synchronized gas giants. In order to understand how tracer transport depends on planetary parameters, we develop an analytic theory to predict vertical velocities and mixing rates ($K_\mathrm{zz}$) and …
The hot Jupiter WASP-12b is a heavily irradiated exoplanet in a short period orbit around a G0-star with twice the metallicity of the Sun. A recent thermochemical equilibrium analysis based on Spitzer and ground-based infrared observations suggests that the presence of $\ch4$ in its atmosphere and the lack of $\h2o$ features can only be explained if the carbon-to-oxygen ratio in the planet's atmosphere is much greater than the solar ratio ($\ctoo = 0.54$). Here, we use a 1-D photochemical model to study the effect of disequilibrium chemistry on the observed abundances of $\h2o, \com, \co2$ and…
Photochemistry is expected to change the chemical composition of the upper atmospheres of irradiated exoplanets through the dissociation of species, such as methane and ammonia, and the association of others, such as hydrogen cyanide. Although primarily the high altitude day side should be affected by photochemistry, it is still unclear how dynamical processes transport photochemical species throughout the atmosphere, and how these chemical disequilibrium effects scale with different parameters. In this work we investigate the influence of photochemistry in a two-dimensional context, by synthe…
GJ436b is a unique member of the transiting extrasolar planet population being one of the smallest and least irradiated and possessing an eccentric orbit. Because of its size, mass and density, GJ436b could plausibly have an atmospheric metallicity similar to Neptune (20-60 times solar abundances), which makes it an ideal target to study the effects of atmospheric metallicity on dynamics and radiative transfer in an extrasolar planetary atmosphere. We present three-dimensional atmospheric circulation models that include realistic non-gray radiative transfer for 1, 3, 10, 30, and 50 times solar…
Context. Planets are thought to eventually form from the mostly gaseous (~99% of the mass) disks around young stars. The density structure and chemical composition of protoplanetary disks are affected by the incident radiation field at optical, FUV, and X-ray wavelengths, as well as by the dust properties. Aims. The effect of FUV and X-rays on the disk structure and the gas chemical composition are investigated. This work forms the basis of a second paper, which discusses the impact on diagnostic lines of, e.g., C+, O, H2O, and Ne+ observed with facilities such as Spitzer and Herschel. Methods…
Dynamically Coupled Three-dimensional Cloud-Chemistry in Rapidly Rotating Irradiated Atmospheres: an Application to the Compact White Dwarf-Brown Dwarf system ZTFJ0038+2030
Tsung-Dao Lee Institute, Shanghai Jiao Tong University（李政道研究所，上海交通大学）；School of Physics and Astronomy, Shanghai Jiao Tong University（物理与天文学院，上海交通大学）；State Key Laboratory of Dark Matter Physics, Shanghai Jiao Tong University（暗物质物理全国重点实验室，上海交通大学）；Department of Astronomy, University of Virginia（天文学系，弗吉尼亚大学）；School of Physics and Astronomy, University of Leicester（物理与天文学院，莱斯特大学）；School of Physics and Astronomy, University of Birmingham（物理与天文学院，伯明翰大学）；Center for Space and Habitability, University of Bern（太空与宜居性中心，伯尔尼大学）；Space Telescope Science Institute（太空望远镜科学研究所）；Université de la Côte d’Azur, Observatoire de la Côte d’Azur, CNRS, Laboratoire Lagrange（蔚蓝海岸大学，蔚蓝海岸天文台，法国国家科学研究中心，拉格朗日实验室）
We introduce a new thermochemical kinetics and photochemical model. We use high-temperature bidirectional reaction rates for important H, C, O and N reactions (most importantly for CH$_4$ to CO interconversion), allowing us to attain thermochemical equilibrium, deep in an atmosphere, purely kinetically. This allows ab initio chemical modeling of an entire atmosphere, from deep-atmosphere thermochemical equilibrium to the photochemically dominated regime. We use our model to explore the atmospheric chemistry of cooler ($T_{eff} < 10^3$ K) extrasolar giant planets. In particular, we choose to mo…
We report our spectroscopic investigation of the transiting ice giant GJ 3470b's atmospheric transmission, and the first results of extrasolar planet observations from the new Keck/MOSFIRE spectrograph. We measure a planet/star radius ratio of Rp/Rs = 0.0789 +/- 0.0020 in a bandpass from 2.09-2.36 micron and in six narrower bands across this wavelength range. When combined with existing broadband photometry, these measurements rule out cloud-free atmospheres in chemical equilibrium assuming either solar abundances (5.4 sigma confidence) or a moderate level of metal enrichment (50x solar abunda…
In this work we investigate the impact of calculating non-equilibrium chemical abundances consistently with the temperature structure for the atmospheres of highly-irradiated, close-in gas giant exoplanets. Chemical kinetics models have been widely used in the literature to investigate the chemical compositions of hot Jupiter atmospheres which are expected to be driven away from chemical equilibrium via processes such as vertical mixing and photochemistry. All of these models have so far used pressure--temperature (P-T) profiles as fixed model input. This results in a decoupling of the chemist…
The atmospheres of synchronously rotating exoplanets are intrinsically three-dimensional, and fast vertical and horizontal winds are expected to mix the atmosphere, driving the chemical composition out of equilibrium. Due to the longer computation times associated with multi-dimensional forward models, horizontal mixing has only been investigated for a few case studies. In this paper, we aim to generalize the impact of horizontal and vertical mixing on the chemistry of exoplanet atmospheres over a large parameter space. We do this by applying a sequence of post-processed forward models for a l…
Detections of molecules in the atmosphere of gas giant exoplanets allow us to investigate the physico-chemical properties of the atmospheres. Their inferred chemical composition is used as tracer of planet formation and evolution mechanisms. Currently, an increasing number of detections is showing a possible rich chemistry of the hotter gaseous planets, but whether this extends to cooler giants is still unknown. We observed four transits of WASP-80 b, a warm transiting giant planet orbiting a late-K dwarf star with the near-infrared GIANO-B spectrograph installed at the Telescopio Nazionale Ga…
State of the art spectral retrieval models of exoplanet atmospheres assume constant chemical profiles with altitude. This assumption is justified by the information content of current datasets which do not allow, in most cases, for the molecular abundances as a function of pressure to be constrained. In the context of the next generation of telescopes, a more accurate description of chemical profiles may become crucial to interpret observations and gain new insights into atmospheric physics. We explore here the possibility of retrieving pressure-dependent chemical profiles from transit spectra…
The anomalously large radii of highly-irradiated gaseous exoplanets has long been a mystery. One mechanism suggested as a solution for hot Jupiters is the heating of the deep atmosphere via the vertical advection of potential temperature resulting in an increased internal entropy. Here we intend to explore if this mechanism can also explain the observed brown dwarf radii trend: a general increase in radius with irradiation, with an exception for highly-irradiated brown dwarfs orbiting white dwarfs. We use a 3D GCM, DYNAMICO, to run a series of long-timescale models of the atmospheres of Kepler…
The hot Jupiter HD 209458b is particularly amenable to detailed study as it is among the brightest transiting exoplanet systems currently known (V-mag = 7.65; K-mag = 6.308) and has a large planet-to-star contrast ratio. HD 209458b is predicted to be in synchronous rotation about its host star with a hot spot that is shifted eastward of the substellar point by superrotating equatorial winds. Here we present the first full-orbit observations of HD 209458b, in which its 4.5 $μ$m emission was recorded with $Spitzer$/IRAC. Our study revises the previous 4.5 $μ$m measurement of HD 209458b's seconda…
This dissertation as a whole aims to provide means to better understand hot-Jupiter planets through observing, performing thermochemical calculations, and modeling their atmospheres. We used Spitzer multi-wavelength secondary-eclipse observations and targets with high signal-to-noise ratios, as their deep eclipses allow us to detect signatures of spectral features and assess planetary atmospheric structure and composition with greater certainty. Chapter 1 gives a short introduction. Chapter 2 presents the Spitzer secondary-eclipse analysis and atmospheric characterization of WASP-14b. WASP-14b…
Infrared radiation emitted from a planet contains information about the chemical composition and vertical temperature profile of its atmosphere. If upper layers are cooler than lower layers, molecular gases will produce absorption features in the planetary thermal spectrum. Conversely, if there is a stratosphere - where temperature increases with altitude - these molecular features will be observed in emission. It has been suggested that stratospheres could form in highly irradiated exoplanets, but the extent to which this occurs is unresolved both theoretically and observationally. A previous…
The first mass-estimate of an exoplanet around a Sun-like star, 51 Peg b and the first radius measurement of an exoplanet, HD209458b pointed to the challenges of understanding the atmosphere, interior, and evolution of exoplanets including the possibility of mass loss of planets on close-orbits that are exposed to strong irradiation. These discoveries raised the question of heating and inflation mechanisms, and of the nature of these objects in terms of composition compared to the known planets in the Solar system. The field of exoplanet interior modeling was born. Here, we outline and discuss…
A Physically Driven Parameterisation of Multidimensional Atmospheres: Application to the JWST Phase Curve of WASP-121b
CAS Key Laboratory of Planetary Sciences, Purple Mountain Observatory, Chinese Academy of Sciences（中国科学院行星科学重点实验室，紫金山天文台）；University of Science and Technology of China（中国科学技术大学）；Tsung-Dao Lee Institute & School of Physics and Astronomy, Shanghai Jiao Tong University（上海交大李政道研究所与物理与天文学院）；University of Oxford（牛津大学）；University of California, Santa Cruz（加州大学圣克鲁兹分校）；University of Newcastle（纽卡斯尔大学）；Max-Planck-Institut für Astronomie（马克斯·普朗克天文学研究所）；Instituto de Astrofísica de Canarias（加那利群岛天体物理研究所）；Universidad de La Laguna（拉各纳大学）；University of Hawai‘i（夏威夷大学）
In order to characterize giant exoplanets and better understand their origin, knowledge of how the planet's composition depends on its mass and stellar environment is required. In this work, we simulate the thermal evolution of gaseous planets and explore how various common model assumptions such as different equations of state, opacities, and heavy-element distributions affect the inferred radius and metallicity. We examine how the theoretical uncertainties translate into uncertainties in the inferred planetary radius and bulk metallicity. While we confirm the mass-metallicity trend previousl…
Recently, properties of exoplanet atmospheres have been constrained via multi-wavelength transit observation, which measures an apparent decrease in stellar brightness during planetary transit in front of its host star (called transit depth). Sets of transit depths so far measured at different wavelengths (called transmission spectra) are somewhat diverse: Some show steep spectral slope features in the visible, some contain featureless spectra in the near-infrared, some show distinct features from radiative absorption by gaseous species. These facts infer the existence of haze in the atmospher…
Making use of the publicly available 1D photoionization hydrodynamics code ATES we set out to investigate the combined effects of planetary gravitational potential energy ($ϕ_p\equiv GM_p/R_p$) and stellar X-ray and Extreme Ultraviolet (XUV) irradiation ($F_{\rm XUV}$) on the evaporation efficiency ($η$) of moderately-to-highly irradiated gaseous planets, from sub-Neptunes through hot Jupiters. We show that the (known) existence of a threshold potential above which energy-limited escape (i.e., $η\simeq 1$) is unattainable can be inferred analytically. For $\log ϕ_p\gtrsim \log ϕ_p^{\rm thr}\ap…
Super-Earths belong to a class of planet not found in the Solar System, but which appear common in the Galaxy. Given that some super-Earths are rocky, while others retain substantial atmospheres, their study can provide clues as to the formation of both rocky planets and gaseous planets, and - in particular - they can help to constrain the role of photo-evaporation in sculpting the exoplanet population. GJ 9827 is a system already known to host 3 super-Earths with orbital periods of 1.2, 3.6 and 6.2 days. Here we use new HARPS-N radial velocity measurements, together with previously published …
Planetary atmospheric escape and disk formation around WDJ0914+1914
Instituto de Astronomía Teórica y Experimental (CONICET-UNC)（理论与实验天体物理研究所）；Instituto de Astrofísica de La Plata, CCT La Plata-CONICET-UNLP（拉普拉塔天体物理研究所）；Departamento de Física, Universidad Técnica Federico Santa María（圣马利亚技术大学物理系）；Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México（墨西哥国立自治大学核科学研究所）；Department of Physics, University of Warwick（华威大学物理系）
Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets a…
