Flexible mechanical metamaterials possess repeating structural motifs that imbue them with novel, exciting properties including programmability, anomalous elastic moduli and nonlinear and robust response. We address such structures via micromorphic continuum elasticity, which allows highly nonuniform deformations (missed in conventional elasticity) within unit cells that nevertheless vary smoothly between cells. We show that the bulk microstructure gives rise to boundary elastic terms. Discrete lattice theories have shown that critically coordinated structures possess a topological invariant which determines the placement of low-energy modes on edges of such a system. We show that in continuum systems a new topological invariant emerges which relates the difference in the number of such modes between two opposing edges. Guided by the continuum limit of the lattice structures, we identify macroscopic experimental observables for these topological properties that may be observed independently on a new length scale above that of the microstructure.
We examine how the distribution of contour lengths and the high-stretch stiffening of individual chain segments affect the macroscopic shear modulus of flexible polymer gels, using a 2D numerical model, in which polymer segments form a triangular network and disorder is introduced by varying their contour lengths. We show that in the relevant parameter range: (i) the non-affine contribution to the shear modulus is negligible, i.e. the Born approximation is satisfactory; (ii) the shear modulus is dominated by the contribution originating from equilibrium chain tensions. Moreover, mechanical equ…
Force versus extension curves measure entropic elasticity of single polymer chain in force spectroscopy experiments. A Worm-like Chain model is used to describe force extension experiments with an intrinsic chain parameter called persistence length, which is a measure of local bending flexibility. For flexible polymers, there is a discrepancy in estimates of persistence length in various force regimes. For instance, Atomic Force Microscopy (AFM) based pulling experiments report anomaly low values which are also inconsistent with magnetic tweezers experiments. To understand this, we investigate…
Active materials are those in which individual, uncoordinated local stresses drive the material out of equilibrium on a global scale. Examples of such assemblies can be seen across scales from schools of fish to the cellular cytoskeleton and underpin many important biological processes. Synthetic experiments that recapitulate the essential features of such active systems have been the object of study for decades as their simple rules allow us to elucidate the physical underpinnings of collective motion. One system of particular interest has been active nematic liquid crystals (LCs). Because of…
Self-organisation into spatially modulated structures has different nature from phase transition into uniform states. Skyrmions and half-skyrmions (merons) are representatives of such structures and are utilised in designing magnetoelectric, optical, and mechanoresponsive materials by controlling topological phases. However, skyrmions and half-skyrmions in molecular solids are rarely studied, though there is a universality in theoretical descriptions between magnetic and molecular systems with chiral interactions. Here we develop a simple physical system for controlling topological phases in a…
Numerical and experimental framework for bending elasticity of highly flexible slender structures
School of Integrated Design Engineering, Graduate School of Science and Technology, Keio University（庆应义塾大学理工学研究科综合设计工程学院）；Graduate School of Engineering Science, Osaka University（大阪大学工学研究科）；Department of Mechanical Engineering, Faculty of Science and Technology, Keio University（庆应义塾大学理工学部机械工学科）
Crystallography typically studies collections of point particles whose interaction forces are the gradient of a potential. Lifting this assumption generically gives rise in the continuum limit to a form of elasticity with additional moduli known as odd elasticity. We show that such odd elastic moduli modify the strain induced by topological defects and their interactions, even reversing the stability of, otherwise, bound dislocation pairs. Beyond continuum theory, isolated dislocations can self propel via microscopic work cycles active at their cores that compete with conventional Peach-Koehle…
We analyze the phase behavior of lyotropic nematic liquid crystals in the self-organizing flow, viz. so called active nematics (AN). Their elastic properties are mutually caused by evolution of topological defects (for instance, disclinations and boojums) and the flow regime. Such changes in elasticity of AN comparing with conventional inactive ones set the new working characteristics of these materials, have an influence on their switchable and tunable properties. In this work, we study the uniaxial droplet AN phases with topological defects in their collective flow, we apply the gauge string…
We establish non-Hermitian topological mechanics in one dimensional (1D) and two dimensional (2D) lattices consisting of mass points connected by meta-beams that lead to odd elasticity. Extended from the "non-Hermitian skin effect" in 1D systems, we demonstrate this effect in 2D lattices in which bulk elastic waves exponentially localize in both lattice directions. We clarify a proper definition of Berry phase in non-Hermitian systems, with which we characterize the lattice topology and show the emergence of topological modes on lattice boundaries. The eigenfrequencies of topological modes are…
In this article, we unravel an intimate relationship between two seemingly unrelated concepts: elasticity, that defines the local relations between stress and strain of deformable bodies, and topology that classifies their global shape. Focusing on Moebius strips, we establish that the elastic response of surfaces with non-orientable topology is: non-additive, non-reciprocal and contingent on stress-history. Investigating the elastic instabilities of non-orientable ribbons, we then challenge the very concept of bulk-boundary-correspondence of topological phases. We establish a quantitative con…
The topologically polarized isostatic lattices discovered by Kane and Lubensky (2014, Nat. Phys. 10, 39-45) challenged the standard effective medium theories used in the modeling of many truss-based materials and metamaterials. As a matter of fact, these exhibit Parity (P) asymmetric distributions of zero modes that induce a P-asymmetric elastic behavior, both of which cannot be reproduced within Cauchy elasticity. Here, we propose a new effective medium theory baptized "microtwist elasticity" capable of rendering polarization effects on a macroscopic scale. The theory is valid for trusses on …
Elasticity typically refers to a material's ability to store energy, while viscosity refers to a material's tendency to dissipate it. In this review, we discuss fluids and solids for which this is not the case. These materials display additional linear response coefficients known as odd viscosity and odd elasticity. We first introduce odd elasticity and odd viscosity from a continuum perspective, with an emphasis on their rich phenomenology, including transverse responses, modified dislocation dynamics, and topological waves. We then provide an overview of systems that display odd viscosity an…
A micrometer-scale elastic shell immersed in a nematic liquid crystal may be deformed by the host if the cost of deformation is comparable to the cost of elastic deformation of the nematic. Moreover, such inclusions interact and form chains due to quadrupolar distortions induced in the host. A continuum theory model using finite elements is developed for this system, using mesh regularization and dynamic refinement to ensure quality of the numerical representation even for large deformations. From this model, we determine the influence of the shell elasticity, nematic elasticity and anchoring …
Deformations of conventional solids are described via elasticity, a classical field theory whose form is constrained by translational and rotational symmetries. However, flexible metamaterials often contain an additional approximate symmetry due to the presence of a designer soft strain pathway. Here we show that low energy deformations of designer dilational metamaterials will be governed by a novel field theory, conformal elasticity, in which the nonuniform, nonlinear deformations observed under generic loads correspond with the well-studied conformal maps. We validate this approach using ex…
The motion of flexible fibers through structured fluidic environments is ubiquitous in nature and industrial applications. Most often, their dynamics results from the complex interplay between internal elastic stresses, contact forces and hydrodynamic interactions with the walls and obstacles. By means of numerical simulations, experiments and analytical predictions, we investigate the dynamics of flexible fibers settling in a viscous fluid embedded with obstacles of arbitrary shapes. We identify and characterize two types of events: trapping and gliding, for which we detail the mechanisms at …
Much of our understanding of vibrational excitations and elasticity is based upon analysis of frames consisting of sites connected by bonds occupied by central-force springs, the stability of which depends on the average number of neighbors per site $z$. When $z<z_c \approx 2d$, where $d$ is the spatial dimension, frames are unstable with respect to internal deformations. This pedagogical review focuses on properties of frames with $z$ at or near $z_c$, which model systems like randomly packed spheres near jamming and network glasses. Using an index theorem, $N_0 - N_S = dN - N_B$ relating the…
Despite their considerable practical and biological applications, the link between molecular properties, assembly conditions and self-organized structure in confined polymer solutions remains elusive. Here, we explore the lyotropic nematic ordering of semi-flexible chains in spherical confinement for multiple contour lengths across a wide regime of concentrations. We uncover an original crossover from two distinct quadrupolar states, both characterized by regular tetrahedral patterns of surface topological defects, to either longitudinal, latitudinal or spontaneously-twisted bipolar structures…
Colloidal rods immersed in a thermotropic liquid-crystalline solvent are at the basis of so-called hybrid liquid crystals which are characterized by tunable nematic fluidity with symmetries ranging from conventional uniaxial nematic or anti-nematic to orthorhombic [Mundoor et al., Science 360, 768 (2018)]. We provide a theoretical analysis of the elastic moduli of such systems by considering interactions between the individual rods with the embedding solvent through surface-anchoring forces, as well as steric and electrostatic interactions between the rods themselves. For uniaxial systems the …
We consider models for elastic liquids, such as solutions of flexible polymers. They introduce a relaxation time $λ$ into the system, over which stresses relax. We study the kinematics of the problem, and clarify the relationship between Lagrangian and Eulerian descriptions, thereby showing which polymer models correspond to a nonlinear elastic deformation in the limit $λ\rightarrow\infty$. This allows us to split the change in elastic energy into reversible and dissipative parts, and thus to write an equation for the total energy, the sum of kinetic and elastic energies. As an illustration, w…
In this article, we introduce a framework to investigate the growth of nano-crystallites in a polymer matrix numerically. This framework combines the Flory theory of entropic elasticity with phase-field approaches commonly used to model crystal growth. We investigate in particular the growth kinetics of a crystallite in the presence of topological constraints such as entanglements or cross-links, and show that depending on the coupling between the topological constraints and the growth kinetics various structures can be observed: branched structures looking like spherulites or stable nano-crys…
Using a combination of the replica-exchange Monte Carlo algorithm and the multicanonical method, we investigate the influence of bending stiffness on the conformational phases of a bead-stick homopolymer model and present the pseudo-phase diagram for the complete range of semi-flexible polymers, from flexible to stiff. Although a simple model, we observe a rich variety of conformational phases, reminiscent of conformations observed for synthetic polymers or biopolymers. Changing the internal bending stiffness, the model exhibits different pseudo phases like bent, hairpin or toroidal. In partic…
Materials made from active, living, or robotic components can display emergent properties arising from local sensing and computation. Here, we realize a freestanding active metabeam with piezoelectric elements and electronic feed-forward control that gives rise to an odd micropolar elasticity absent in energy-conserving media. The non-reciprocal odd modulus enables bending and shearing cycles that convert electrical energy into mechanical work, and vice versa. The sign of this elastic modulus is linked to a non-Hermitian topological index that determines the localization of vibrational modes t…
Achieving control and tunability of lyotropic materials has been a long-standing goal of liquid crystal research. Here we show that the elasticity of a liquid crystal system consisting of a dense suspension of semiflexible biopolymers can be manipulated over a relatively wide range of elastic moduli. Specifically, thin films of actin filaments are assembled at an oil-water interface. At sufficiently high concentrations, one observes the formation of a nematic phase riddled with $\pm1/2$ topological defects, characteristic of a two-dimensional nematic system. As the average filament length incr…
It has become clear in recent years that the simple uniform wormlike chain model needs to be modified in order to account for more complex behavior which has been observed experimentally in some important biopolymers. For example, the large flexibility of short ds-DNA has been attributed to kink or hinge defects. In this paper, we calculate analytically, within the weak bending approximation, the force-extension relation of a wormlike chain with a permanent hinge defect along its contour. The defect is characterized by its bending energy (which can be zero, in the completely flexible case) and…
We study here the microscopic deformations of elastic lamellae constituting a superhydrophobic substrate under different wetting conditions of a sessile droplet using electrowetting. The deformation profiles of the lamellae are experimentally evaluated using confocal microscopy. These experimental results are then explained using a variational principle formalism within the framework of linear elasticity. We show that the local deformation profile of a lamella is mainly controlled by the net horizontal component of the capillary forces acting on its top due to the pinned droplet contact line. …
The injection of a long flexible rod into a two-dimensional domain yields a complex pattern commonly studied through elasticity theory, packing analysis, and fractal geometries. "Loop" is a one-vertex entity that is naturally formed in this system. The role of the elastic features of each loop in 2D packing has not yet been discussed. In this work, we point out how the shape of a given loop in the complex structure allows estimating local deformations and forces. First, we build sets of symmetric free loops and performed compression experiments. Then, tight packing configurations are analyzed …
We report extensive numerical simulations of different models of 2D polymer rings with internal elasticity. We monitor the dynamical behavior of the rings as a function of the packing fraction, to address the effects of particle deformation on the collective response of the system. In particular, we compare three different models: (i) a recently investigated model [Gnan \& Zaccarelli, Nat. Phys. 15, 683 (2019)], where an inner hertzian field providing the internal elasticity acts on the monomers of the ring, (ii) the same model where the effect of such a field on the center of mass is balanced…
The temperature dependence of DNA flexibility is studied in the presence of stretching and unzipping forces. Two classes of models are considered. In one case the origin of elasticity is entropic due to the polymeric correlations, and in the other the double-stranded DNA is taken to have an intrinsic rigidity for bending. In both cases single strands are completely flexible. The change in the elastic constant for the flexible case due to thermally generated bubbles is obtained exactly. For the case of intrinsic rigidity, the elastic constant is found to be proportional to the square root of th…
The packing problem of long thin filaments that are injected into confined spaces is of fundamental interest for physicists and biologists alike. How linear threads pack and coil is well known only for the ideal case of rigid containers, though. Here, we force long elastic rods into flexible spatial confinement borne by an elastic shell to examine under which conditions recently acquired knowledge on wire packing in rigid spheres breaks down. We find that unlike in rigid cavities, friction plays a key role by giving rise to the emergence of two distinct packing patterns. At low friction, the w…
Disordered filamentous networks with compliant crosslinks exhibit a low linear elastic shear modulus at small strains, but stiffen dramatically at high strains. Experiments have shown that the elastic modulus can increase by up to three orders of magnitude while the networks withstand relatively large stresses without rupturing. Here, we perform an analytical and numerical study on model networks in three dimensions. Our model consists of a collection of randomly oriented rigid filaments connected by flexible crosslinks that are modeled as wormlike chains. Due to zero probability of filament i…
