The Cassini Composite Infrared Spectrometer (CIRS) observed thermal emission in the far- and mid-infrared (from 10 cm$^{-1}$ to 1500 cm$^{-1}$), enabling spatiotemporal studies of ethane on Titan across the span of the Cassini mission from 2004 through 2017. Many previous measurements of ethane on Titan have relied on modeling the molecule's mid-infrared $ν_{12}$ band, centered on 822 cm$^{-1}$. Other bands of ethane at shorter and longer wavelengths were seen, but have not been modeled to measure ethane abundance. Spectral line lists of the far-infrared $ν_{4}$ torsional band at 289 cm$^{-1}$ and the mid-infrared $ν_{8}$ band centered ay 1468 cm$^{-1}$ have recently been studied in the laboratory. We model CIRS observations of each of these bands (along with the $ν_{12}$ band) separately and compare retrieved mixing ratios from each spectral region. Nadir observations of of the $ν_{4}$ band probe the low stratosphere below 100 km. Our equatorial measurements at 289 cm$^{-1}$ show an abundance of (1.0$\pm$0.4) $\times$10$^{-5}$ at 88 km, from 2007 to 2017. This mixing ratio is consistent with measurements at higher altitudes, in contrast to the depletion that many photochemical models predict. Measurements from the $ν_{12}$ and $ν_{8}$ bands are comparable to each other, with the $ν_{12}$ band probing an altitude range that extends deeper in the atmosphere. We suggest future studies of planetary atmospheres may observe the $ν_{8}$ band, enabling shorter wavelength studies of ethane. There may also be an advantage to observing both the ethane $ν_{8}$ band and nearby methane $ν_{4}$ band in the same spectral window.
At wavelengths between 0.15 and 0.19 $μ$m, the far-ultraviolet spectrum of Jupiter is dominated by the scattered solar spectrum, attenuated by molecular absorptions primarily by acetylene and ethane, and to a lesser extent ammonia and phosphine. We describe the development of our radiative transfer code that enables the retrieval of abundances of these molecular species from ultraviolet reflectance spectra. As a proof-of-concept we present an analysis of Cassini Ultraviolet Imaging Spectrograph (UVIS) observations of the disk of Jupiter during the 2000/2001 flyby. The ultraviolet-retrieved ace…
Acetylene (C$_2$H$_2$) and ethane (C$_2$H$_6$) are both produced in the stratosphere of Jupiter via photolysis of methane (CH$_4$). Despite this common source, the latitudinal distribution of the two species is radically different, with acetylene decreasing in abundance towards the pole, and ethane increasing towards the pole. We present six years of NASA IRTF TEXES mid-infrared observations of the zonally-averaged emission of methane, acetylene and ethane. We confirm that the latitudinal distributions of ethane and acetylene are decoupled, and that this is a persistent feature over multiple y…
The complex organic chemistry harbored by the atmosphere of Titan has been investigated in depth by Cassini observations. Among them, a series of solar occultations performed by the VIMS instrument throughout the 13 years of Cassini revealed a strong absorption centered at 3.4 $μ$m. Several molecules present in Titan's atmosphere create spectral features in that wavelength region, but their individual contributions are difficult to disentangle. In this work, we quantify the contribution of the various molecular species to the 3.4 $μ$m band using a radiative transfer model. Ethane and propane a…
Of the C$_{3}$H$_{x}$ hydrocarbons, propane (C${_3}$H$_{8}$) and propyne (methylacetylene, CH$_{3}$C$_{2}$H) were first detected in Titan's atmosphere during the Voyager 1 flyby in 1980. Propene (propylene, C$_{3}$H$_{6}$) was first detected in 2013 with data from the Composite InfraRed Spectrometer (CIRS) instrument on Cassini. We present the first measured abundance profiles of propene on Titan from radiative transfer modeling, and compare our measurements to predictions derived from several photochemical models. Near the equator, propene is observed to have a peak abundance of 10 ppbv at a …
We report on spectroscopic observations of Saturn's stratosphere in July 2011 with the Texas Echelon Cross Echelle Spectrograph (TEXES) mounted on the NASA InfraRed Telescope Facility (IRTF). The observations, targeting several lines of the CH$_4$ $ν_4$ band and the H$_2$ S(1) quadrupolar line, were designed to determine how Saturn's stratospheric thermal structure was disturbed by the 2010 Great White Spot. A study of Cassini Composite Infrared Spectrometer (CIRS) spectra had already shown the presence of a large stratospheric disturbance centered at a pressure of 2~hPa, nicknamed the beacon …
The Cassini mission offered us the opportunity to monitor the seasonal evolution of Titan's atmosphere from 2004 to 2017, i.e. half a Titan year. The lower part of the stratosphere (pressures greater than 10 mbar) is a region of particular interest as there are few available temperature measurements, and because its thermal response to the seasonal and meridional insolation variations undergone by Titan remains poorly known. In this study, we measure temperatures in Titan's lower stratosphere between 6 mbar and 25 mbar using Cassini/CIRS spectra covering the whole duration of the mission (from…
The Cassini/Composite InfraRed Spectrometer (CIRS) instrument has been observing the middle atmosphere of Titan over almost half a Saturnian year. We used the CIRS dataset processed through the up-to-date calibration pipeline to characterize seasonal changes of temperature and abundance profiles in the middle atmosphere of Titan, from mid-northern winter to early northern summer all around the satellite. We used limb spectra from 590 to 1500 cm$^{-1}$ at 0.5-cm$^{-1}$ spectral resolution, which allows us to probe different altitudes. We averaged the limb spectra recorded during each flyby on a…
We aim at constraining the diffusive and advective transport processes in Jupiter's stratosphere. The IR spectrum recorded by Cassini/CIRS during the Jupiter flyby contains the fingerprints of several atmospheric compounds and allows probing its atmospheric composition. C2H2 and C2H6, the main compounds produced by methane photochemistry, were retrieved as a function of latitude at certain pressure levels. CIRS observations suggest a different meridional distribution for these two species, difficult to reconcile with their photochemical histories, which are thought to be coupled to the methane…
Submillimeter emission lines of carbon monoxide (CO) in Titan's atmosphere provide excellent probes of atmospheric temperature due to the molecule's long chemical lifetime and stable, well constrained volume mixing ratio. Here we present the analysis of 4 datasets obtained with the Atacama Large Millimeter/Submillimeter Array (ALMA) from 2012 to 2015 that contain strong CO rotational transitions. Utilizing ALMA's high spatial resolution in the 2012, 2014, and 2015 observations, we extract spectra from 3 separate regions on Titan's disk using datasets with beam sizes of ~0.3''. Temperature prof…
We study the seasonal evolution of Titan's lower stratosphere (around 15~mbar) in order to better understand the atmospheric dynamics and chemistry in this part of the atmosphere. We analysed Cassini/CIRS far-IR observations from 2006 to 2016 in order to measure the seasonal variations of three photochemical by-products: $\mathrm{C_4H_2}$, $\mathrm{C_3H_4}$, and $\mathrm{C_2N_2}$. We show that the abundances of these three gases have evolved significantly at northern and southern high latitudes since 2006. We measure a sudden and steep increase of the volume mixing ratios of $\mathrm{C_4H_2}$,…
Benzene ice contributes to an emission feature detected by the Cassini Composite InfraRed Spectrometer (CIRS) near 682 cm^{-1} in Titan's late southern fall polar stratosphere. It is as well one of the dominant components of the CIRS-observed High Altitude South Polar (HASP) ice cloud observed in Titan's mid stratosphere during late southern fall. Titan's stratosphere exhibits significant seasonal changes with temperatures that spatially vary with seasons. A quantitative analysis of the chemical composition of infrared emission spectra of Titan's stratospheric ice clouds relies on consistent a…
NASA's Spitzer Infrared Spectrometer (IRS) acquired mid-infrared (5-37 microns) disc-averaged spectra of Uranus very near to its equinox in December 2007. A mean spectrum was constructed from observations of multiple central meridian longitudes, spaced equally around the planet, which has provided the opportunity for the most comprehensive globally-averaged characterisation of Uranus' temperature and composition ever obtained (Orton et al., 2014 a [arXiv:1407.2120], b [arXiv:1407.2118]). In this work we analyse the disc-averaged spectra at four separate central meridian longitudes to reveal si…
We report the detection of a spectral signature observed at 682 cm$^{-1}$ by the Cassini Composite Infrared Spectrometer (CIRS) in nadir and limb geometry observations of Titan's southern stratospheric polar region in the middle of southern fall, while stratospheric temperatures are the coldest since the beginning of the Cassini mission. The 682 cm$^{-1}$ signature, which is only observed below an altitude of 300-km, is at least partly attributed to the benzene (C$_6$H$_6$) ice $ν_{4}$ C-H bending mode. While we first observed it in CIRS nadir spectra of the southern polar region in early 2013…
We present an analysis of all currently available ground-based imaging of Neptune in the mid-infrared. Dating between 2003 and 2020, the images reveal changes in Neptune's mid-infrared ($\sim 8-25μ$m) emission over time in the years surrounding Neptune's 2005 southern summer solstice. Images sensitive to stratospheric ethane ($\sim12μ$m), methane ($\sim8μ$m), and CH$_3$D ($\sim9μ$m) display significant sub-seasonal temporal variation on regional and global scales. Comparison with H$_2$ S(1) hydrogen-quadrupole ($\sim17.035μ$m) spectra suggests these changes are primarily related to stratospher…
The aim of this study is to measure the vertical distribution of HCN on Titan's stratosphere using ground-based submm observations acquired quasi-simultaneously with the Herschel ones. This allows us to perform a consistency check between space and ground-based observations and to build a reference mean HCN vertical profile in Titan's stratosphere. Using APEX and IRAM 30-m, we obtained the spectral emission of HCN (4-3) and (3-2) lines. We applied a line-by-line radiative transfer code to calculate the synthetic spectra of HCN, and a retrieval algorithm based on optimal estimation to retrieve …
Global maps of Jupiter's atmospheric temperatures, gaseous composition and aerosol opacity are derived from a programme of 5-20 $μ$m mid-infrared spectroscopic observations using the Texas Echelon Cross Echelle Spectrograph (TEXES) on NASA's Infrared Telescope Facility (IRTF). Image cubes from December 2014 in eight spectral channels, with spectral resolutions of $R\sim2000-12000$ and spatial resolutions of $2-4^\circ$ latitude, are inverted to generate 3D maps of tropospheric and stratospheric temperatures, 2D maps of upper tropospheric aerosols, phosphine and ammonia, and 2D maps of stratosp…
Experimental Measurements of Benzene Ice Critical Saturation Ratios on Titan Tholins and Impact on the Microphysical Modeling of Titan's South Polar Benzene Cloud
NASA Ames Research Center（美国国家航空航天局艾姆斯研究中心）；Bay Area Environmental Research Institute（湾区环境研究所）；Centre de Recherche sur les Ions, les Matériaux et la Photonique Université Caen Normandie, ENSICAEN, CNRS, CEA, Normandie Univ, CIMAP UMR6252（诺曼底大学离子、材料与光子研究中心）；Southwest Research Institute（西南研究院）；LIRA, Observatoire de Paris, Université PSL, CNRS, Sorbonne Université, Université Paris Cité（巴黎天文台）
