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arXiv 1907.02243cond-mat.supr-con
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NbSeTe --一种新的层状过渡金属二硫属化合物超导体

NbSeTe -A New Layered Transition Metal Dichalcogenide Superconductor

Dong Yan, Shu Wang, Yishi Lin, Guohua Wang, Yijie Zeng, Mebrouka Boubeche, Yuan He, Jie Ma, Yihua Wang, Dao-Xin Yao, Huixia Luo

摘要:

过渡金属二硫属化合物(TMDC)由于层间耦合较弱,通常呈现层状多型结构。2 H-NbSe 2是TMDC系列中研究最广泛的一种,因为它具有很高的超导转变温度(Tc = 7.3K)和低于33 K时出现的电荷密度波(CDW)阶数。CDW与超导电性的共存提出了一个有趣的公开问题,费米表面嵌套和库珀配对之间的关系。过去的研究主要集中在通过3d过渡金属掺杂2 H-NbSe 2而不显著改变其晶体结构。本文以Te取代2 H-NbSe_2中的Se,设计了一种新的1 T多型层状TMDC NbSeTe,它采用三角结构,空间群为P-3 m_1。采用气相输运法,以I2为输运剂,成功地生长出了大尺寸、高质量的1 T-NbSeTe单晶。与温度相关的电阻率和比热数据揭示了1.3 K下的体Tc,这是首次在纯1 T-NbSeTe相中观察到超导电性。这种化合物扩大了超导TMDC的家族,并提供了一个机会来研究三角结构中CDW和超导性之间的相互作用。

英文摘要:

Transition metal dichalcogenides (TMDCs) usually exhibit layered polytypic structures due to the weak interlayer coupling. 2H-NbSe2 is one of the most widely studied in the pristine TMDC family due to its high superconducting transition temperature (Tc = 7.3K) and the occurrence of a charge-density wave (CDW) order below 33 K. The coexistence of CDW with superconductivity poses an intriguing open question about the relationship between Fermi surface nesting and Cooper pairing. Past studies of this issue have mostly been focused on doping 2H-NbSe2 by 3d transition metals without significantly changing its crystal structure. Here we replaced the Se by Te in 2H-NbSe2 in order to design a new 1T polytype layered TMDC NbSeTe, which adopts a trigonal structure with space group P-3m1. We successfully grew large size and high-quality single crystals of 1T-NbSeTe via the vapor transport method using I2 as the transport agent. Temperature-dependent resistivity and specific heat data revealed a bulk Tc at 1.3 K, which is the first observation of superconductivity in pure 1T-NbSeTe phase. This compound enlarged the family of superconducting TMDCs and provides an opportunity to study the interplay between CDW and superconductivity in the trigonal structure.

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