Transition metal dichalcogenides (TMDCs) usually exhibit layered polytypic structures due to the weak interlayer coupling. 2H-NbSe2 is one of the most widely studied in the pristine TMDC family due to its high superconducting transition temperature (Tc = 7.3K) and the occurrence of a charge-density wave (CDW) order below 33 K. The coexistence of CDW with superconductivity poses an intriguing open question about the relationship between Fermi surface nesting and Cooper pairing. Past studies of this issue have mostly been focused on doping 2H-NbSe2 by 3d transition metals without significantly changing its crystal structure. Here we replaced the Se by Te in 2H-NbSe2 in order to design a new 1T polytype layered TMDC NbSeTe, which adopts a trigonal structure with space group P-3m1. We successfully grew large size and high-quality single crystals of 1T-NbSeTe via the vapor transport method using I2 as the transport agent. Temperature-dependent resistivity and specific heat data revealed a bulk Tc at 1.3 K, which is the first observation of superconductivity in pure 1T-NbSeTe phase. This compound enlarged the family of superconducting TMDCs and provides an opportunity to study the interplay between CDW and superconductivity in the trigonal structure.
Pressure-induced Structural Phase Transition, Metallization, and Superconductivity in layered metalloid dichalcogenide 1T-SiTe$_2$
National Laboratory of Solid State Microstructures and Department of Physics, Collaborative Innovation Center of Advanced Microstructures, Nanjing University(南京大学固体微结构物理国家重点实验室和物理学院,先进微结构协同创新中心)
Misfit layer superconductors, tuneable bulk heterostructures with strong 2D effects
P.J. Šafárik University(P.J. 萨法里克大学);Institute of Experimental Physics, Slovak Academy of Sciences(斯洛伐克科学院实验物理研究所);University of Trento(特伦托大学);Sorbonne Université, CNRS, Institute des Nanoscience de Paris(索邦大学,法国国家科学研究中心,巴黎纳米科学研究所)
Pressure-induced reentrant superconductivity in a misfit layered compound $\mathrm{(SnS)_{1.15}(TaS_2)}$
Qufu Normal University(曲阜师范大学);Center for High Pressure Science and Technology Advanced Research(高压科学和技术先进研究中心);Xinyang Normal University(信阳师范大学);Jining University(济宁学院);Indian Institute of Technology Roorkee(印度理工学院鲁尔基分校);Academia Sinica(中央研究院);Zhejiang University of Technology(浙江工业大学)